新能源

能源产业,环境生态

一、MOF材料在低温SCR脱硝反应中的应用
确定了含不饱和金属位的MOF材料的优异的低温脱硝活性，初步探索活化及反应机理。选择了具有配位不饱和金属位的M-MOF-74作为低温SCR反应的催化剂进行探索性研究。研究了M-MOF-74中的配位不饱和金属位作为催化活性中心的特殊性质，考察了MOF催化材料对低温SCR过程的影响。获得国家自然科学基金一项。
二、MOF材料在醋酸体系中痕量碘脱除的应用，
研究了碘分子在不同结构的MOF材料的吸附作用规律，为工业上碘分离材料的设计提供科学依据。基于碘的毒性以及其较强的挥

1. Jiang, Haoxi; Wang, Qianyun; Wang, Huiqin; Chen, Yifei*; Zhang, Minhua*. MOF-74 as an Efficient Catalyst for the Low-Temperature Selective Catalytic Reduction of NOx with NH3, ACS Applied Materials & Interfaces, 2016, 8(40): 26817~26826.
2. Minhua Zhang, Rui Yao, Haoxi Jiang, Yifei Chen*. Insights into the mechanism of acetic acid hydrogenation to ethanol on Cu(111) surface. Applied Surface Science, 2017, 412: 342-349
3. Minhua Zhang, Wenyi Wang, Yifei Chen*. Insight of DFT and ab initio atomistic thermodynamics on the surface stability and morphology of In2O3, Applied Surface Science, 2018, 434, 1344-1352
4. Yifei Chen#, Ziwei Zhai#, Jiatao Liu, Jia Zhang, Zhongfeng Geng*, Huisheng Lyu. The synergistic effects of Cu clusters and In2O3 on ethanol synthesis from acetic acid hydrogenation, Physical Chemistry Chemical Physics, 2019, 21(43): 23906-23915 (2019 hot paper)
5. Minhua Zhang, Song Yin, Yifei Chen*, A DFT study for CO2 hydrogenation on W(111) and Ni-doped W(111) surfaces, Physical Chemistry Chemical Physics, 2020,22 17106-17116 (2020 hot paper)
6. Yifei Chen, Yang Gao, Lingtao Wang, Hao Gong*, The mechanism of MOF as a heterogeneous catalyst for propene hydroformylation: a DFT study, Reaction Chemistry & Engineering, 2022, 7, 1156
7. Yiduo Wang, Cheng Liu, He Dong, Yifei Chen*, Insight into the mechanism of the key step for the production of 1,4-butanediol on Ni(111) surface: A DFT study, Molecular Catalysis, 2022, 524: 112335
8. Xiuqin Dong, Chen Xin, Lingtao Wang, Hao Gong, Yifei Chen*, The role of metal nodes on Rh coordinated MOFs for Hydroformylation of n-butene, Applied Catalysis A, General, 2022, 118848
9. Minhua Zhang, Lin Liu, Qinghua Li, Hao Gong, Yifei Chen*, Theoretical Design of MOFs and PSA Process for Efficient Separation of CF4/NF3, Industrial & Engineering Chemistry Research, 2023, 62, 7103−7113
10. Yifei Chen，Yongru You, Chen Xin, Xiuqin Dong, Hao Gong*, Rational design of ligand-immobilized Rh/IRMOFs catalysts for 1-butene hydroformylation with high regioselectivity, Journal of Environmental Chemical Engineering, 2024, 12，114163
11. 龚奇菡， 陈毅飞， 崔佳，姜浩锡，吕雉，董秀芹，耿中峰，张上，李兆飞，马安，一种高稳定性的金属有机骨架材料、其制备方法及应用，中国CN202010248149.7