石油化工

1）石油及其产品的加氢精制和加氢裂化工艺条件优化及新型催化剂设计
2）废弃油脂短流程加氢制航空煤油
3）深地化石能源原位加氢降粘提高采收率
4）废塑料氢解制高值化学品
5）液态储氢材料的储放氢
6）二氧化碳加氢制高值化学品

Hydrodesulfurization;Dibenzothiophene;Formic Acid;4,6-dimethyldibenzothiophene;Hydrogen Spillover;Oxygen Vacancy;Methanol;Naphthalene;H 2 Production;Density Functional Theory

以第一/通讯作者身份发表SCI论文60篇，代表性的30篇论文如下：
1)        Y. T. Zou, C. K. Xiao, X. Yang, Y. Z. Wang, X. Y. Kong, Z. T. Liu, C. Y. Wang, A. J. Duan, C. M. Xu, X. L. Wang*, “Flower-like hierarchical TS-1/Al2O3 composite supported NiMo catalysts for efficient hydrodesulfurization of dibenzothiophenes” Journal of Catalysis 2024, 435, 115576.
2)        Y. T. Zou, C. K. Xiao, D. Z. Li, A. C. Wang, D. W. Gao, H. Shang, C. Y. Wang, A. J. Duan, C. M. Xu, X. L. Wang*, “Dendritic micro-mesoporous composites via nano-assembly strategy towards high-efficiency catalysts for hydrodesulfurization of dibenzothiophenes.” Journal of Catalysis 2023, 427, 115092.
3)        S. Li, C. H. Zhou*, J. S. Hu*, A. J. Duan, C. M. Xu, X. L. Wang*, PdIr nanoparticles on NH2-functionalized dendritic mesoporous silica nanospheres for efficient dehydrogenation of formic acid. Journal of Catalysis, 2023, 426, 153-161.
4)        M. H. Alabsi, X. Z. Chen, X. L. Wang*, M. L. Zhang, A. Ramirez, A. J. Duan, C. M. Xu, L. Cavallo, K. -W. Huang*, “Highly dispersed Pd nanoparticles supported on dendritic mesoporous CeZrZnOx for efficient CO2 hydrogenation to methanol.” Journal of Catalysis 2022, 413, 751-761.
5)        L. Qi, P. Zheng, Z. Zhao, A. J. Duan, C. M. Xu, X. L. Wang*, “Insights into the intrinsic kinetics for efficient hydrodesulfurization of 4,6-dimethyldibenzothiophene over mesoporous CoMoS2/ZSM-5.” Journal of Catalysis 2022, 408, 279-293.
6)        X. L. Wang, C. K. Xiao, P. Zheng, Z. Zhao, M. H. Alabsi, Y. Shi, D. W. Gao, A. J. Duan*, K. -W. Huang*, C. M. Xu*, “Dendritic micro–mesoporous composites with center-radial pores assembled by TS-1 nanocrystals to enhance hydrodesulfurization activity of dibenzothiophene and 4, 6-dimethyldibenzothiophene.” Journal of Catalysis 2020, 384, 136-146.
7)        X. L. Wang, J. L. Mei, Z. Zhao, P. Zheng, Z. T. Chen, D. W. Gao, J. Y. Fu, J. Y. Fan, A. J. Duan*, C. M. Xu*, “Self-Assembly of Hierarchically Porous ZSM-5/SBA-16 with Different Morphologies and Its High Isomerization Performance for Hydrodesulfurization of Dibenzothiophene and 4,6-Dimethyldibenzothiophene.” ACS Catalysis 2018, 8, 1891-1902
8)        X. L. Wang, Z. Zhao, P. Zheng, Z. T. Chen, A. J. Duan*, C. M. Xu*, J. Q. Jiao, H. L. Zhang, Z. K. Cao, B. H. Ge, “Synthesis of NiMo catalysts supported on mesoporous Al2O3 with different crystal forms and the superior catalytic performance for hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene.” Journal of Catalysis 2016, 344, 680-691.
9)        K. Yu, W. M. Kong, Z. Zhao*, A. J. Duan, L. Kong*, X. L. Wang*, “Hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene over NiMo supported on yolk-shell silica catalysts with adjustable shell thickness and yolk size.” Journal of Catalysis 2022, 410, 128-143.
10)    Chunhui Zhou, Song Li, Hao Chai, Quan Liu, Jinsong Hu*, Zhentao Liu, Ke Yu, Fei Fan, Wenwu Zhou, Aijun Duan, Chunming Xu, Xilong Wang*, “Immobilizing Pd nanoparticles on amine-functionalized yolk-shell mesoporous silica nanospheres for efficient H2 production from formic acid dehydrogenation.” Applied Catalysis B: Environment and Energy 2024, 346, 123750.
11)    Daowei Gao, Shuai Wang, Yipin Lv, Changxu Wang, Jianyu Ren, Peng Zheng*, Lianghao Song, Aijun Duan, Xilong Wang*, Guozhu Chen*, and Chunming Xu, “Unraveling Hydrogenation Kinetic Behavior of Transition Metal Oxides via Decoupling Dihydrogen Dissociation and Substrate Activation.” ACS Catalysis 2024, 14, 1939-1950.
12)    J. Lei, Z. Li*, C. P. Wang, H. Y. Yao*, X. L. Wang*, J. S. Hu*, “Nanocage confined nitrogen-rich MOF-derived Co/CoN heterostructure for overall water splitting.” Chemical Engineering Science 2024, 293, 120068.
13)   X. L. Wang*, M. H. Alabsi, X. Z. Chen, A. J. Duan, C. M. Xu, K. -W. Huang*, “CO2 hydrogenation to methanol over PdZn catalysts on bimetallic modified dendritic mesoporous silica nanospheres.” Chemical Engineering Journal 2023, 476, 146596.
14)   Zhentao Liu, Enhua Wang, Jinlin Mei, Aocheng Wang, Yutong Zou, Chunya Wang*, Hui Shang, Yanjun Gong, Aijun Duan, Chunming Xu, Xilong Wang*, “Hierarchical porous Pt/Hβ catalyst with controllable acidity for efficient hydrogenation of naphthalene.” Chemical Engineering Journal 2024, 481, 148763.
15)   Dongze Li, Chengkun Xiao, Yutong Zou, Liang Qiao, Chunhui Zhou*, Aijun Duan, Chunya Wang*, Chunming Xu, Xilong Wang*, “Novel titanium silicon micro-mesoporous composites via nano-assembly strategy for efficient hydrodesulfurization of dibenzothiophene” Chemical Engineering Journal 2024, 494, 152938.
16)    C. K. Xiao, S. T. Song, Y. T. Zou, E. H. Wang, A. C. Wang, Y. D. Song, J. Liu, A. J. yeyeDuan*, P. Zheng*, X. L. Wang*. "Facile synthesis of few-layer MoS2 nanosheets with different morphologies supported on Al-TUD-1 for efficient hydrodesulfurization of dibenzothiophene and 4, 6-dimethyldibenzothiophene." Chemical Engineering Journal 2021, 425, 131416.
17)   X. L. Wang, C. K. Xiao, M. H. Alabsi, P. Zheng, Z. K. Cao, J. Li Mei, Y. Shi, A. J. Duan*, D. W. Gao*, K. -W. Huang*, C. M. Xu*, "Pt-confinement catalyst with Dendritic hierarchical pores on Excellent Sulfur-resistance for Hydrodesulfurization of Dibenzothiophene and 4, 6-Dimethyldibenzothiophene." Green Energy & Environment 2022, 7, 324-333.
18)   X. L. Wang*, M. H. Alabsi, P. Zheng*, J. L. Mei, A. Ramirez, A. J. Duan, C. M. Xu, K. -W. Huang*, “PdCu supported on dendritic mesoporous CexZr1-xO2 as superior catalysts to boost CO2 hydrogenation to methanol.” Journal of Colloid and Interface Science 2022, 611, 739-751.
19)   Chunhui Zhou, Rongmei Zhang, Jinsong Hu*, Changguang Yao*, Zhentao Liu, Aijun Duan, X. L. Wang*, “Ultrasmall Pd nanoparticles supported on a metal–organic framework DUT-67-PZDC for enhanced formic acid dehydrogenation.” Journal of Colloid and Interface Science 2024, 673, 997-1006.
20)    C. K. Xiao, Y. T. Zou, Z. T. Liu, D. Z. Li, X. Y. Kong, D. W. Gao, C. Y. Wang*, A. J. Duan, C. M. Xu, X. L. Wang*, “Monodisperse dendritic micro-mesoporous composite self-assembled with tiny TS-1 seeds as efficient catalysts for hydrodesulfurization of dibenzothiophenes.” Fuel 2024, 361, 130644.
21)    A. C. Wang, K. Yu, D. W. Gao, Z. K. Cao, H. Shang, C. Y. Wang*, A. J. Duan, C. M. Xu, X. L. Wang*, “Hierarchically porous ZSM-5/SBA-15 composite: Tuning pore structure and acidity for hydrodesulfurization of dibenzothiophene.” Fuel 2024, 362, 130826.
22)    Hao Chai, Chunhui Zhou*, Song Li, Rongmei Zhang, Junjie Yuan, Jinsong Hu*, Zhentao Liu, Aijun Duan, Chunming Xu, Xilong Wang*, “Anchoring Pd nanoparticles on MOF-303-derived N-doped carbon for enhanced H2 production from formic acid dehydrogenation.” Fuel 2024, 371, 131908.
23)    E. H. Wang, D. Hu, C. K. Xiao, S. T. Song, Y. T. Zou, S. Y. Fu, K. B. Chi, J. Liu, A. J. Duan*, X. L. Wang*, “Highly dispersed Pt on core–shell micro-mesoporous composites assembled by mordenite nanocrystals for selective hydrogenation of polycyclic aromatics.” Fuel 2023, 331, 125852.
24)    Chunhui Zhou, Song Li, Hao Chai, Jinsong Hu*, Zhentao Liu, Ke Yu, Chunya Wang*, Aijun Duan, Chunming Xu, Xilong Wang*, “Ultrafine PdCo nanoparticles on amine-functionalized CeZrSBA-15 with short channels for efficient H2 production from formic acid dehydrogenation.” Fuel 2024, 365, 131170.
25)   M. H. Alabsi, X. L. Wang*, P. Zheng, J. L. Mei, A. Ramirez, A. J. Duan, C. M. Xu, K. -W. Huang*, “Screening and design of active metals on dendritic mesoporous Ce0.3Zr0.7O2 for efficient CO2 hydrogenation to methanol.” Fuel 2022, 317, 123471.
26)    C. K. Xiao, Y. T. Zou, D. Z. Li, E. H. Wang, A. C. Wang, D. W. Gao, A. J. Duan, P. Zheng*, X. L. Wang*, “Optimization of dendritic TS-1/Silica micro–mesoporous composites for efficient hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene.” Petroleum Science 2023, 20, 2521-2530.
27)    J. L. Mei, Y. Shi, C. K. Xiao, A. C. Wang, A. J. Duan*, X. L. Wang*. “Hierarchically porous Beta/SBA-16 with different silica-alumina ratios and the hydrodesulfurization performances of DBT and 4,6-DMDBT” Petroleum Science 2022, 19, 375-386.
28)    X. L. Wang, J. L. Mei, Z. Zhao, Z. T. Chen, P. Zheng, J. Y. Fu, H. D. Li, J. Y. Fan, A. J. Duan*, C. M. Xu*, “Controllable Synthesis of Spherical Al-SBA-16 Mesoporous Materials with Different Crystal Sizes and Its High Isomerization Performance for Hydrodesulfurization of Dibenzothiophene and 4,6-Dimethyldibenzothiophene.” Industrial & Engineering Chemistry Research 2018, 57, 2498-2507.
29)    X. L. Wang, J. L. Mei, Z. Zhao, P. Zheng, Z. T. Chen, J. M. Li, J. Y. Fan, A. J. Duan*, C. M. Xu*, “Restrictive Diffusion in the Hydrodesulfurization over Ni-MoS2/Al2O3 with different crystal forms.” Industrial & Engineering Chemistry Research 2017, 56, 10018-10027.
30)    S. T. Song, T. S. Li, Y. N. Ju, Y. Li, Z. W. Lv, P. Zheng, A. J. Duan*, P. Wu*, X. L. Wang*, “Lanthanum/Gallium-Modified Zn/ZSM-5 Zeolite for Efficient Isomerization/Aromatization of FCC Light Gasoline.” Industrial & Engineering Chemistry Research 2022, 61, 9667-9677.

1. 一种无定形硅铝催化剂及其制备方法和应用
中国石油大学（北京）; 中国农业科学院农业环境与可持续发展研究所
王喜龙; 李东泽; 王春雅; 徐春明; 张茂林; 何文清
公开日期: 2024-12-13 申请日期: 2024-08-27 公开号: CN119114063A

2. 蛋黄壳型复合分子筛及其制备方法、加氢精制催化剂及其制备方法和应用
中国石油大学（北京）
王喜龙; 邹予桐; 王春雅; 徐春明
公开日期: 2024-11-22 申请日期: 2024-08-08 公开号: CN118988394A

3. 加氢精制催化剂及其制备方法与废润滑油油品的加氢精制反应
中国石油大学（北京）
段爱军; 肖承坤; 王奥诚; 邹予桐; 郑鹏; 王喜龙
公开日期: 2023-06-06 申请日期: 2023-02-22 公开号: CN116212947A

4. ZSM-5-SBA-15复合分子筛及其制备方法与加氢精制催化剂及其应用
中国石油大学（北京）
王奥诚; 段爱军; 王恩华; 王喜龙; 肖承坤
公开日期: 2023-06-06 申请日期: 2023-02-22 公开号: CN116216739A

5. 介微孔复合分子筛及其制备、正构烷烃临氢异构化催化剂及其制备与应用
中国石油大学(北京)
王喜龙; 王恩华; 段爱军; 徐春明
公开日期: 2023-04-21 申请日期: 2022-12-09 公开号: CN115991484A

6. 一种氧化铝基加氢精制催化剂及其制备方法与应用
中国石油大学(北京)
段爱军; 方鹤; 张明会; 高善彬; 赵震; 姜桂元; 刘坚; 韦岳长; 王喜龙
公开日期: 2015-09-30 申请日期: 2015-05-21 公开号: CN104941654A

1. 酸性位与边/角金属位对催化裂化柴油加氢脱硫路径的影响机制
立项时间: 2023

技术咨询