精细化工

催化反应的机理研究

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[1]Zhen-Zhen Xie, Kai Chen*, Hua Yang*, Yu Zheng, Yu-Lun Qian.Organocatalytic domino sequence to asymmetrically access spirocyclic oxindole-α-methylene-γ-lactams.Tetrahedron, 2021, 89: 132163.
[2]Tian‐Yu Sun, Kai Chen*, Tingting You*, Xiao Wang*, Huakang Zhou, Penggang Yin.Revisiting the effect of f‐functions in predicting the right reaction mechanism for hypervalent iodine reagents[J].Journal of Computational Chemistry, 2021, 42 (7) : 470-474.
[3]Jing Wan, Kai Chen*, Xiao-Qing Chen*, Hua Yang*, Xian-Zhou Zheng, Jun-An Xiao, Hao-Yue Xiang.Enantioselectivity-Switchable Organocatalytic [4+ 2]-Annulation to Access the Spirooxindole–Norcamphor Scaffold.Organic Letters, 2021, 23 (3) : 963-968.
[4]Ji-Wei Ren#, Zhen-Zhen Xie#, Kai Chen*, Hao-Yue Xiang*, Hua Yang*, Lan Zheng, Zhi-Peng Ye, Xiao-Qing Chen.An organocatalytic enantioselective ring-reorganization domino sequence of methyleneindolinones with 2-aminomalonates[J].Organic Chemistry Frontiers, 2020, 8 (4) : 778-783.
[5]Zhi-Peng Ye, Peng-Ju Xia*, Kai Chen*, Hao-Yue Xiang*, Hua Yang*, Yuan-Zhuo Hu.Photocatalytic intermolecular anti-Markovnikov hydroamination of unactivated alkenes with N-hydroxyphthalimide.Organic Chemistry Frontiers, 2020, 8 (2) : 273-277.
[6]Rui Wu#, Kai Chen#, Jun Ma#, Zhi-Xiang Yu*, Shifa Zhu*, Synergy of activating substrate and introducing CH··· O interaction to achieve Rh 2 (II)-catalyzed asymmetric cycloisomerization of 1, n-enynes[J], 2020, 63 (9) : 1230-1239.
[7]Peng-Ju Xia, Zhi-Peng Ye, Yuan-Zhuo Hu, Jun-An Xiao, Kai Chen*, Hao-Yue Xiang*, Xiao-Qing Chen*, Hua Yang*.Photocatalytic C–F Bond Borylation of Polyfluoroarenes with NHC-boranes[J].Org. Lett., 2020, 22: 1742-1747.
[8]Tian‐Yu Sun, Kai Chen*, Tingting You*, Changyuan Zhang, Penggang Yin.1, 3‐O‐Transposition or Trisubstituted Z‐Enol Ester? A Comparative Study of Reactions of Ynones[J].Chemistry–An Asian Journal, 2019, 14 (11) : 1941-1944.
[9]Lianfen Chen#, Kai Chen#, Shifa Zhu*, Transition Metal-Catalyzed Intramolecular Nucleophilic Addition of Carbonyl Group to Alkyne[J].Chem, 2018, 4: 1208-1262.
[10]Kai Chen, Shifa Zhu*, NHC-AuCl/Selectfluor: An Efficient Catalytic System for π-Bond Activation[J], 2017, 28: 640-653.

[1]不对称自诱导的Morita-Baylis-Hillman醋酸酯 [3+3]环化反应的机理研究,立项时间:2021-01-01
[2]中国博士后基金会:金属卡宾数据库的构建及其反应预测的理论研究(2016T90777),开始日期:2016-02-01,立项时间:2016-02-01,结项时间:2017-05-31.
[3]中国博士后基金会:基于“瞬态物种的产生及捕捉”的有机反应机理研究,开始日期:2015-09-01,结项时间:2017-05-31.
[4]过渡金属催化的基于邻苯碳醌中间体的反应机理研究,开始日期:2019-06-01,立项时间:2016-06-01
[5]基于金属卡宾的反应机理研究,立项时间:2018-01-01