石油化工,精细化工

主要从事石油化工和精细化工领域分子筛材料催化与分离基础科学研究与技术开发，尤其在分子筛吸附扩散和活性中心微结构辨析研究新方法和理论创新等方面研究。

[1] Zhou H, Yi XF, Hui Y, Wang L, Chen W, Qin YC, Wang M, Ma JB, Chu XF, Wang YQ, Hong X, Chen ZF, Meng XJ, Wang H, Zhu QY, Song LJ, Zheng AM, Xiao FS. Isolated boron in zeolite for oxidative dehydrogenation of propane[J]. Science, 2021, 372(6537): 76-80.
[2] Wang H, Luo QS, Wang L, Hui Y, Qin YC, Song LJ, Xiao FS. Product selectivity controlled by manganese oxide crystals in catalytic ammoxidation[J]. Chinese Journal of Catalysis, 2021, 42(12): 2164-2172.
[3] 翟鹏, 郑健, 张锦研, 王焕, 秦玉才*, 刘宏海*, 宋丽娟. HZSM-5上正己烷酸催化裂解反应路径及机理的探讨 [J]. 燃料化学学报, 2021, 49(10): 1522-1530.
[4] Zheng J, Qin YC*, Li A, Zhang L, Gao XH, Song LJ. A Periodic DFT study of the synergistic mechanisms between extraframework aluminum species and Bronsted acid sites in HY Zeolites[J]. Industrial & Engineering Chemistry Research, 2020, 59(7): 2736-2744.
[5] Jiao JH, Qin YC*, Zheng J, Hui Y, Zhang L, Gao XH, Song LJ. Synergistic mechanism between Bronsted acid site and active cerium species in hydride transfer reaction over CeY zeolites[J]. Journal of Rare Earths, 2020, 38(8): 912-920.
[6] 王思画, 祖运, 秦玉才, 张晓彤, 宋丽娟. CeY分子筛中有效脱硫物种活性位的构建及其吸附机理研究[J]. 燃料化学学报, 2020, 48(1): 52-62.
[7] Zu Y, Wang SH, Hui Y, Ni N, Zhang XT, Qin YC, Zhang L, Liu HH, Gao XH, Song LJ. Facile fabrication of a superior Cu(I)-NH4Y zeolite adsorbent for improving thiophene adsorption selectivity in the presence of aromatics or olefins [J]. Chemical Engineering Journal, 2020, 401(12): 126112.
[8] Zu Y, Guo ZS, Zheng J, Hui Y, Wang SH, Qin YC, Zhang L, Liu HH, Gao XH, Song LJ. Investigation of Cu(I)-Y zeolites with different Cu/Al ratios towards the ultra-deep adsorption desulfurization: Discrimination and role of the specific adsorption active sites [J]. Chemical Engineering Journal, 2020, 380(17): 122319-122319.
[9] Li Y, Qin YC, Chen BK. The crystal structure of dimethylammonium catena- di(mu-aqua)-bis(mu(9)-benzene-1,3,5-tricarboxylato) pentalithium, C20H16Li5NO13[J]. Zeitschrift Fur Kristallographie-New Crystal Structures, 2020, 235(6): 1289-1291.
[10] Li TT, Qin YC, Chen BK. The crystal structure of poly (Mu(10)-5-carboxyisophthalato-kappa O-10)disodium , C9H4Na2O6 [J]. Zeitschrift Fur Kristallographie-New Crystal Structures, 2020, 235(4): 987-988.
[11] Zu Y, Zhang C, Qin YC, Zhang XT, Zhang L, Liu HH, Gao XH, Song LJ. Ultra-deep adsorptive removal of thiophenic sulfur compounds from FCC gasoline over the specific active sites of CeHY zeolite[J]. Journal of Energy Chemistry, 2019, 39: 256-267.
[12] Zu Y, Hui Y, Qin YC, Zhang L, Liu HH, Zhang XT, Guo ZS, Song LJ, Gao XH. Facile fabrication of effective Cerium(III) hydroxylated species as adsorption active sites in CeY zeolite adsorbents towards ultra-deep desulfurization[J]. Chemical Engineering Journal, 2019, 375(12): 122014.
[13] Zhang L, Qin YC, Zhang XT, Gao XH, Song LJ. Further findings on the stabilization mechanism among modified Y Zeolite with different rare earth ions[J]. Industrial & Engineering Chemistry Research, 2019, 58(31): 14016-14025.
[14] Sun X, Liu X, Qin YC, Qiang L, He YP, Su DS, Song LJ, Sun ZL. Direct conversion of acetylene and 1,2-Dichloroethane to vinyl chloride monomer over a supported carbon nitride catalyst: Tunable activity controlled by the synthesis temperature [J]. Industrial & Engineering Chemistry Research, 2019, 58(14): 5404­­­-5413.
[15] Mo ZS, Qin YC, Zu Y, Huan W, Zhang XT, Song LJ. Effect of content of cerium ion on Bronsted-Acid-catalyzed reaction of thiophene over CeY Zeolite studied by In situ FTIR spectroscopy[J]. Chemistryselect, 2019, 4(44): 13034-13044.
[16] 莫周胜, 秦玉才, 裴婷婷, 王琳, 宋丽娟. 分子筛Bronsted酸可接近性对噻吩吸附和反应的影响[J]. 石油学报(石油加工), 2018, 34(5): 1020-1026.
[17] 丁润东, 祖运, 周传行, 王焕, 莫周胜, 秦玉才*, 孙兆林, 宋丽娟*. CuNaY分子筛的有效吸附位与其脱硫性能的关联性研究 [J]. 燃料化学学报, 2018, 4: 451-458.
[18] Sun X, Qin YC, Li Q, Liu X, Liu Z, Song LJ, Sun ZL. Supported structure-controlled graphitic carbon nitride catalyst for dehydrochlorination of 1,2-dichloroethane [J]. Catalysis Science & Technology, 2018, 8(20): 5334-5343.
[19] Li Q, Qin YC, Tan DP, Xie Y, Lv ML, Song LJ. Theoretical investigation of conversion between different C2Hx species over Pd-Ag/Pd(100) surface alloys: influence on the selectivity and transformation of carbonaceous species[J]. New Journal of Chemistry, 2018, 42(24): 19827-19836.
[20] Geng DT, Zhang M, Hang XX, Xie WJ, Qin YC*, Li Q, Bi YF, Zheng ZP. A 2D metal-thiacalix 4 arene porous coordination polymer with 1D channels: gas absorption/separation and frequency response [J]. Dalton Transactions, 2018, 47(27): 9008-9013.
[21] Geng DT, Han X, Bi YF, Qin YC, Li Q, Huang LL, Zhou K, Song LJ, Zheng ZP. Merohedral icosahedral M-48 (M = Co-II, Ni-II) cage clusters supported by thiacalix 4 arene [J]. Chemical Science, 2018, 9(45): 8535-8541.
[22] 莫周胜, 秦玉才, 张晓彤, 段林海, 宋丽娟. 环己烯对噻吩在CuY分子筛上吸附的影响机制(英文)[J]. 物理化学学报, 2017, 6): 1236-1241.
[23] Zu Y, Qin YC, Gao X, Liu H, Zhang X, Zhang J, Song L. Insight into the correlation between the adsorption-transformation behaviors of methylthiophenes and the active sites of zeolites Y [J]. Applied Catalysis B: Environmental, 2017, 203: 96-107.
[24] Zhang L, Qin YC, Ji DQ, Chu G, Gao XH, Zhang XT, Song LJ. Effect of cerium ions initial distribution on the crystalline structure and catalytic performance of CeY zeolite [J]. Journal of Rare Earths, 2017, 35(8): 791-799.
[25] Mo ZS, Qin YC, Zhang XT, Duan LH, Song LJ. Influencing mechanism of cyclohexene on thiophene adsorption over CuY Zeolites [J]. Acta Physico-Chimica Sinica, 2017, 33(6): 1236-1241.
[26] 张媛媛, 秦玉才, 高雄厚, 朱萌萌, 张莉, 宋丽娟. FCC催化剂上烃分子吸附行为与其构型的关联[J]. 化学工程, 2016, 44(10): 23-27.
[27] 张乐, 秦玉才, 汲德强, 杨野, 贾未鸣, 宋丽娟. 铈离子迁移对Y分子筛活性中心的影响[J]. 稀土, 2016, 37(4): 16-22.
[28] 秦玉才, 高雄厚, 石利飞, 张莉, 段林海, 宋丽娟. 原位晶化FCC催化剂传质性能的频率响应法辨析[J]. 物理化学学报, 2016, 32(2): 527-535.
[29] Zhang L, Li Q, Qin YC, Zhang XT, Gao XH, Song LJ. Investigation on the mechanism of adsorption and desorption behavior in cerium ions modified Y-type zeolite and improved hydrocarbons conversion [J]. Journal of Rare Earths, 2016, 34(12): 1221-1227.
[30] Qin YC, Gao XH, Shi LF, Zhang L, Duan LH, Song LJ. Discrimination of the mass transfer performance of in situ crystallization FCC catalysts by the frequency response method [J]. Acta Physico-Chimica Sinica, 2016, 32(2): 527-535.
[31] Qin YC, Song LJ. Mass transfer behaviors in porous catalytic materials: an important basic science for heavy oil catalytic conversion [J]. Abstracts of Papers of the American Chemical Society, 2016, 252-1.
[32] Mo ZS, Li Q, Qin YC, Duan LH, Zhang XT, Song LJ. A DFT study of the effect of NNN Al atom on strength of Bronsted acid sites of HY zeolite [J]. Molecular Simulation, 2016, 42(12): 986-992.
[33] 祖运, 秦玉才, 高雄厚, 莫周胜, 张磊, 张晓彤, 宋丽娟. 催化裂化条件下噻吩与改性Y分子筛的作用机制[J]. 燃料化学学报, 2015, 43(7): 862-869.
[34] 张畅, 秦玉才, 高雄厚, 张海涛, 莫周胜, 初春雨, 张晓彤, 宋丽娟. Ce改性对Y型分子筛酸性及其催化转化性能的调变机制[J]. 物理化学学报, 2015, 31(2): 344-352.
[35] Zhang C, Qin YC, Gao XH, Zhang HT, Mo ZS, Chu CY, Zhang XT, Song LJ. Modulation of the acidity and catalytic conversion properties of Y Zeolites modified by cerium cations [J]. Acta Physico-Chimica Sinica, 2015, 31(2): 344-352.
[36] Qin YC, Gao XH, Zhang HT, Zhang SH, Zheng LG, Li Q, Mo ZS, Duan LH, Zhang XT, Song LJ. Measurements and distinguishment of mass transfer processes in fluid catalytic cracking catalyst particles by uptake and frequency response methods [J]. Catalysis Today, 2015, 245(147-154.
[37] 秦玉才, 高雄厚, 段林海, 范跃超, 于文广, 张海涛, 宋丽娟. 酸催化及竞争吸附对CeY分子筛吸附脱硫性能的影响(英文)[J]. 物理化学学报, 2014, 30(3): 544-550.
[38] Qin YC, Mo ZS, Yu WG, Dong SW, Duan LH, Gao XH, Song LJ. Adsorption behaviors of thiophene, benzene, and cyclohexene on FAU zeolites: Comparison of CeY obtained by liquid-, and solid-state ion exchange [J]. Applied Surface Science, 2014, 292:5-15.
[39] 秦玉才, 高雄厚, 裴婷婷, 郑兰歌, 王琳, 莫周胜, 宋丽娟. 噻吩在稀土离子改性Y型分子筛上吸附与催化转化研究 [J]. 燃料化学学报, 2013, 41(7): 889-896.
[40] 董世伟, 秦玉才, 阮艳军, 王源, 于文广, 张磊, 范跃超, 宋丽娟. 改性Y型分子筛对FCC汽油脱硫性能的研究 [J]. 燃料化学学报, 2013, 41(3): 341-346.
[41] 于吉红 主编，纳米孔材料化学：NMR表征、理论模拟及吸附分离-宋丽娟，秦玉才：第五章微孔分子筛材料的吸附与分离, 科学出版社, 参编7万字，2013.

1) 2024/01-2026/12，项目名称：石油化工和精细化工领域分子筛材料催化与分离，辽宁省“兴辽英才计划”青年拔尖人才项目，项目负责人；
2) 2021/01-2024/12，项目名称：分子筛绿色催化碳四烯烃高值定向转化应用基础研究，国家自然科学基金-辽宁联合基金重点项目（U20A20120），项目负责人；
3) 2020/01-2023/12，项目名称：稀土与碱土金属复合改性超稳Y分子筛制备技术在重油催化裂化催化剂开发中的应用，中国石油天然气股份有限公司的科技开发项目（2021DJ0701），项目负责人；
4) 2020/01-2023/12，项目名称：催化剂活性位与孔道扩散性能的荧光显微成像方法，中国石油天然气股份有限公司的科技开发项目（KYWX-21-019），项目负责人；
5) 2020/01-2022/12，项目名称：多级孔分子筛孔隙结构与扩散性能关联性的频率响应法研究，国家自然科学基金青年科学基金项目（21902068）， 项目负责人；
6) 2021/01-2022/12，项目名称：ZSM-5分子筛催化裂解选择性调控的基础化学研究，中国石油科技创新基金（2020D-5007-0401），项目负责人；
7) 2020/01-2022/12，项目名称：催化裂解干气乙烯高效吸附剂开发及分离技术（2020-MS-284），辽宁省自然科学基金资助项目-面上项目，项目负责人；
8) 2019/01-2021/12，项目名称：基于调控传质性能的多产丙烯FCC催化剂设计新策略（L2019035），辽宁省教育厅优青培育项目，项目负责人；
9) 2017/01-2019/12，项目名称：重油转化助剂结构、传质与催化性能的关联性探究，中国石油天然气股份有限公司重大专项课题（2016E-0701），项目负责人；
10) 2017/01-2018/12，项目名称：低绿油碳二后加氢催化剂小试研究-碳二后加氢反应绿油形成机理研究及催化剂精细结构表征，中国石油天然气股份有限公司项目（2017wx056），项目负责人；
11) 2016/01-2018/12，项目名称：FCC汽油中噻吩硫吸附、转化脱除与Y分子筛酸中心的构效关系，辽宁省博士科研启动基金（201601318），项目负责人。