新材料

精细化学品催化合成、催化剂工程、化工过程强化、光催化新材料等

新戊二醇;合成;加氢;四羰基钴钾;3-丙二醇;3-羟基丙酸甲酯;非晶态合金;酯化反应

Synergistic Effect;Hydrogen Evolution;Hydroesterification;H-2 Evolution;Heterogeneous Catalysis;Neopentyl Glycol;Oxidation;CDS;Methyl 3-hydroxypropionate;H2O2

[1] X. Yan, C. Zhang, J. Hu, Y. Zhou, Z. Lv, Immobilization of Co nanoparticles into N-doped carbon nanotube on g-C3N4 via coordination-polymerization integrated strategy for efficient H2 evolution reaction at all pH values, Applied Catalysis B: Environmental, 342 (2024).
[2] D. Wang, C. Zhang, J. Hu, T. Zhuang, Z. Lv, Nitriding-reduction fabrication of coralloid CoN/Ni/NiO for efficient electrocatalytic overall water splitting, Journal of Colloid and Interface Science, 655 (2024) 217-225.
[3] P. Qin, C. Zhang, Y. Guo, D. Zhang, Q. Liu, Y. Li, H. Song, Z. Lv, Hydroxyl and amino dual-functionalized core-shell molecular sieves featuring hydrogen bond donor groups for efficient CO2 cycloaddition, Journal of Colloid and Interface Science, 656 (2024) 68-79.
[4] Huiqi Qu, Bin Li, Yiru Ma, Zhenyu Xiao, Zhiguo Lv, Zhenjiang Li, Wei Li and Lei Wang*. Defect-enriched Hollow Porous Carbon Nanocages Enable Highly Efficient Chlorine Evolution Reaction, Advanced Materials, (2023)
[5] Huiqi Qu, Yiru Ma, Xiaolong Li, Yuhao Duan, Yuan Li, Feng Liu, Bin Yu, Minge Tian, Zhenjiang Li, Yueqin Yu, Bin Li d,*, Zhiguo Lv a,c,*, Lei Wang. Ternary alloy (FeCoNi) nanoparticles supported on hollow porous carbon with defects for enhanced oxygen evolution reaction, Journal of Colloid and Interface Science, 645 (2023) 107–114
[6] D. Zhang, C. Zhang, H. Song, Z. Guo, J. Hu, Z. Lv, Advanced bio-inspired Cu3P/g-C3N5@Cu with highly dispersed Cu3P nanoclusters for superior visible-light-driven pollutant degradation, Journal of Cleaner Production, 427 (2023).
[7] C. Zhang, Y. Liu, J. Wang, W. Li, Y. Wang, G. Qin, Z. Lv, A well-designed fencelike Co3O4@MoO3 derived from Co foam for enhanced electrocatalytic HER, Applied Surface Science, 595 (2022).
[8] Zhang, C.; Wang, J.; Liu, Y.; Li, W.; Wang, Y.; Qin, G.; Lv, Z. Electrocatalytic HER Enhancement of C3N4 in NiCo2O4. Chem Asian J 2022, 17 (14), e202200377.
[9] Lv, Z.; Wang, Y.; Liu, Y.; Wang, J.; Qin, G.; Guo, Z.; Zhang, C. NiB as a Substitute for the Pt Cocatalyst in CdS with Enhanced Visible-Light Photocatalytic H2 Production. The Journal of Physical Chemistry C 2022, 126 (21), 9041.
[10] Z. Lv, W. Li, X. Cheng, B. Liu, Z. Guo, T. Zhuang, C. Zhang, Constructing internal electric field in CdS via Bi, Ni co-doping strategy for enhanced visible-light H2 production, Applied Surface Science, 556 (2021).
[11] Zhang, C.; Cheng, X.; Liu, B.; Guo, Z.; He, G.; Lv, Z. Noble-metal-free hexagonal wurtzite CdS nanoplates with exposed (110) and (112) crystal facets for efficient visible-light H2 production. New Journal of Chemistry 2021, 45 (1), 217.
[12] Zhang, C.; Chu, S.; Liu, B.; Liu, Y.; Guo, Z.; Lv, Z. MOF-mediated fabrication of coralloid Ni2P@CdS for enhanced visible-light hydrogen evolution. Applied Surface Science 2021, 569.
[13] Zhang, C.; Liu, B.; Li, W.; Liu, X.; Wang, K.; Deng, Y.; Guo, Z.; Lv, Z. A well-designed honeycomb Co3O4@CdS photocatalyst derived from cobalt foam for high-efficiency visible-light H2 evolution. Journal of Materials Chemistry A 2021, 9 (19), 11665.
[14] Lv, Z.; Li, W.; Cheng, X.; Liu, B.; Guo, Z.; Zhuang, T.; Zhang, C. Constructing internal electric field in CdS via Bi, Ni co-doping strategy for enhanced visible-light H2 production. Applied Surface Science 2021, 556.
[15] Liu X, Wang K, Liu, B, Guo Z, Zhang, C, Lv, Z. Novel WO3/SO42--ZrO2–TiO2 double bridge coordination catalyst hfor oxidation of cyclohexene. Journal of Solid State Chemistry 2021, 300: 122239.
[16] Wang K, Liu X, Liu, B, Guo Z, Zhang, C, Lv, Z. Preparation of carbonyl rhodium polyether guanidinium ionic liquids and application in asymmetric hydroformylation based on homogeneous catalysis-biphasic separation system. Journal of Organometallic Chemistry. 2021, 948: 121931
[17] Z. Lv, X. Cheng, B. Liu, Z. Guo, C. Zhang, Py-COOH modified g-C3N4 nanosheets with enhanced visible-light photocatalytic H2 production, Applied Surface Science, 504 (2020).
[18] C. Zhang, B. Liu, X. Cheng, Z. Guo, T. Zhuang, Z. Lv, A CdS@NiS reinforced concrete structure derived from nickel foam for efficient visible-light H2 production, Chemical Engineering Journal, 393 (2020).
[19] Wang B, Jin M, Guo Z, Lv Z*. Hydrogenation performance of acetophenone to 1-phenylethanol on highly active nano Cu/SiO2 catalyst[J]. Catalysis Letters. 2020, 150(1): 56-64.
[20] Lv Z, Wang J, Zhang S, Wang B, Guo Z, Zhang C. Highly selective hydrogenation of acetophenone over supported amorphous alloy catalyst[J]. Applied Organometallic Chemistry. 2020, e5555.
[21] Lv Z, Zhang S, Guo Z, Cheng X, Wang J, Zhang C. Synthesis of alcohol ester 12 in 1, 8-diazabicyclo [5.4.0] undec-7-ene (DBU)-based Self-separation catalytic system. Applied Organometallic Chemistry. 2019, 33(10): e5145.
[22] Lv Z, Cheng X, Liu B, Guo Z, Jin M, Zhang C. Enhanced photoredox water splitting of Sb-N donor-acceptor pairs in TiO2[J]. Inorganic Chemistry Frontiers. 2019, 6(9): 2404-2411.
[23] Zhang C, Liu B, Cheng X, Guo Z, Zhuang T, Lv Z*. Noble-metal-free CdS decorated porous NixCo1-xO skeleton derived from metal–organic framework for efficient visible-light H2 production[J]. ACS Applied Energy Materials, 2019.
[24] Song Y, Lv Z*, Guo Z. Study on Hydroformylation of Octene Catalyzed by Rhodium-Containing Functional Ionic Liquid[C]. IOP Conference Series: Materials Science and Engineering. IOP Publishing, 2019, 490(2): 022075.
[25] Jin M, Wang J, Wang B, Guo Z, Lv Z*.Highly effective green oxidation of aldehydes catalysed by recyclable tungsten complex immobilized in organosilanes-modified SBA-15[J]. Microporous Mesoporous Mater. 2019, 277(84-94).
[26] Wang B, Zhang C, Wang J, An H, Guo Z, Lv Z*.Study on nano Cu/SiO2 catalysts for highly selective hydrogenation of acetophenone[J]. Applied Organometallic Chemistry. 2019,33(8): e5000.
[27] Manman Jin, Guodi Zhang, Zhenmei Guo, Zhiguo Lv*.Tungsten doped mesoporous SBA-16 as novel heterogeneous catalysts for oxidation of cyclopentene to glutaric acid. Applied Organometallic Chemistry, 2018, 32(5): e4317.
[28] Manman Jin, Zhenmei Guo, Zhiguo Lv*. Immobilization of tungsten chelate complexes on functionalized mesoporous silica SBA-15 as heterogeneous catalysts for oxidation of cyclopentene. Journal of Materials Science, 2019, 54(9): 6853-6866.
[29] Manman Jin, Zhenmei Guo, Zhiguo Lv*. Synthesis of convertible {PO4[WO3W(O)2(O2)]4}-DMA16 in SBA-15 nanochannels and its catalytic oxidation activity. Catalysis Letters, 2019, 149(10): 2794-2806.

[1]吕志果,郭振美,柳培,张伟伟.一种甘油制备丙二醇的方法.2015,中国,授权专利号：ZL201210419541.9.
[2]吕志果,郭振美,王恒生.一种由环氧乙烷制备3-羟基丙酸酯及1,3丙二醇的方法.2013,中国,授权专利号：ZL201010501535.9.
[3]吕志果,郭振美,聂涛,陈强,王志会.一种由1-（4-异丁基苯基）乙醇制备2-(4-异丁基苯基)丙酸酯的方法.2013,中国,授权专利号：ZL200710114367.5.
[4]吕志果,赵正康,郭振美,应于舟,杨菊群,张旭红,冯看卡.一种3-羟基丙酸酯加氢制备1,3-丙二醇的催化剂及制备方法.2011,中国,授权专利号：ZL200710114367.5.
[5]吕志果,赵正康,郭振美,应于舟,杨菊群,张旭红,冯看卡.一种3-羟基丙酸酯加氢制备1,3-丙二醇的方法.2011,中国,授权专利号：ZL200710114366.
[6]吕志果,宋湛谦,郭振美.一种N-烷基芳胺的制备方法.2009,中国,授权专利号：ZL200610149056.9.
[7]吕志果,郭振美,聂涛,陈强,王志会.一种由1-（4-异丁苯基）乙醇制备2-（4-异丁苯基）丙酸酯的方法.2014,中国,授权专利号：ZL20131004893.0.

1、纵向项目
[1]2020.01-2023.12，国家自然科学基金面上项目，21978141，基于温控相转移羰基铑离子液体构建高效可循环手型羰基化催化体系，在研，项目负责人。
[2]2017.08-2019.12，山东省自然科学基金重大基础研究项目，ZR2017ZC0632，清洁合成布洛芬酰化-加氢工艺及催化剂技术，在研，项目负责人。
[3]2014.01-2017.12，国家自然科学基金面上项目，21376128，洛芬合成过程高效羰基化反应可循环催化体系的构建，结题完成，项目负责人。
[4]2010.01-2012.12，山东自然科学基金，ZR2009BL016，甘油一步法择形催化氢解脱羟基酯1,3-丙二醇研究，已结题，项目负责人。
[5]2010.06-2012.12，山东省高校科研计划，J10LB07，两相催化对异丁基苯乙烯氢酯化制布洛芬机制研究，已结题，项目负责人。
[6]2008.01-2010.12，国家自然科学基金面上项目，20776071，可回收液-液两相环氧乙烷氢酯基化-加氢耦合制1,3-丙二醇机制研究，已结题，项目负责人。
2、横向项目
[1]2022.08~，碳酸亚乙烯酯合成新工艺研究，在研，项目负责人。
[2]2019.01~，糠醛加氢合成2-甲基呋喃无铬催化剂研制，在研，项目负责人。
[3]2016.01~，低碳醛液相连续氧化制有机酸连续生产技术开发，在研，项目负责人。
[4]2015.01~，布洛芬生产过程新戊二醇回收循环利用及连续化新技术开发，在研，项目负责人。
[5]2014.01~，环烯烃一锅法绿色氧化制二元酸（酐、酯、酰肼）工艺技术开发，在研，项目负责人。
[6]2007.01~，异丁醛下游衍生物新戊二醇、115酯、泛内酯、CS12醇酯、异丁酸异丁酯、螺二醇等合成工艺研究，在研，项目负责人。

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