天然气化工,环保,新材料,煤化工,石油炼制,石油化工,精细化工

配合物功能材料: 立足于配位化学，合理选择和引入具有特定光/电/磁性质的构筑单元，设计合成具有刺激响应性的金属-有机材料，认识其组成-结构-性能关系，研究其在智能传感、信息存储与处理等方面的应用.
金属-有机框架材料与催化：以多孔金属-有机框架材料为平台，针对CO2的转化利用及重要有机合成反应，通过直接合成和后合成修饰等策略引入和调节催化活性组分，设计开发新型高效绿色催化材料

Magnetic Properties;Metal-organic Frameworks;Crystal Structure;Manganese;Coordination Polymers;Cobalt;Azides;Fluorescence;Heterogeneous Catalysis;Coordination Polymer

Zhou, L.-J.; Sun, W.; Yang, N.-N.; Li, P.; Gong, T.; Sun, W.-J.; Sui, Q.; Gao, E.-Q., A facile and versatile “click” approach toward multifunctional ionic metal–organic framework for efficient conversion of CO2. ChemSusChem 2019, DOI: 10.1002/cssc.201802990.

Yang, N.-N.; Zhou, L.-J.; Li, P.; Sui, Q.; Gao, E.-Q., Space-confined indicator displacement assay inside a metal–organic framework for fluorescence turn-on sensing. Chem. Sci. 2019, 10, 3307-3314.

Yue, Q.; Gao, E.-Q., Azide and carboxylate as simultaneous coupler for magnetic coordination polymers. Coord. Chem. Rev. 2019, 382, 1-31.

Gong, T.; Sui, Q.; Li, P.; Meng, X.-F.; Zhou, L.-J.; Chen, J.; Xu, J.; Wang, L.; Gao, E.-Q., Versatile and Switchable Responsive Properties of a Lanthanide-Viologen Metal-Organic Framework. Small 2019, 15, 1803468.

Sun, W.-J.; Gao, E.-Q., MIL-101 supported highly active single-site metal catalysts for tricomponent coupling. Appl. Catal., A 2019, 569, 110-116.

Gao, L.-L.; Fang, J.-J.; Yang, N.-N.; Bu, R.; Yin, X.-M.; Zhou, L.-J.; Sun, W.-J.; Gao, E.-Q., Synergetic Effects between a Bipyridyl-Functionalized Metal-Organic Framework and Graphene for Sensitive Electrochemical Detection of Norepinephrine. J. Electrochem. Soc. 2019, 166, B328-B335.

Gong, T.; Li, P.; Sui, Q.; Zhou, L.-J.; Yang, N.-N.; Gao, E.-Q., Switchable Ferro-, Ferri-, and Antiferromagnetic States in a Piezo- and Hydrochromic Metal-Organic Framework. Inorg. Chem. 2018, 57, 6791-6794.

Li, P.; Zhou, L.-J.; Yang, N.-N.; Sui, Q.; Gong, T.; Gao, E.-Q., Metal-Organic Frameworks with Extended Viologen Units: Metal-Dependent Photochromism, Photomodulable Fluorescence, and Sensing Properties. Cryst. Growth Des. 2018, 18, 7191-7198.

Li, X.-B.; Ma, Y.; Gao, E.-Q., Random Co(II)-Ni(II) Ferromagnetic Chains Showing Coexistent Antiferromagnetism, Metamagnetism, and Single-Chain Magnetism. Inorg. Chem. 2018, 57, 7446-7454.

Li, X.-B.; Cheng, A.-L.; Gao, E.-Q., Random mixed-metal Co1-xNix single-chain magnets with simultaneous azide, carboxylate and tetrazolate bridges. Dalton Trans. 2018, 47, 9685-9692.

Gong, T.; Li, P.; Sui, Q.; Chen, J.; Xu, J.; Gao, E.-Q.* A stable electron-deficient metal-organic framework for colorimetric and luminescence sensing of phenols and anilines. Journal of Materials Chemistry A 2018, 6, 9236-9244.

Sui, Q.; Li, P.; Yang, N.-N.; Gong, T.; Bu, R.; Gao, E.-Q.* Differentiable Detection of Volatile Amines with a Viologen-Derived Metal-Organic Material. ACS Appl. Mater. Interfaces 2018, 10, 11056-11062.

Yang, N.-N.; Fang, J.-J.; Sui, Q.; Gao, E.-Q.* Incorporating Electron-Deficient Bipyridinium Chromorphores to Make Multiresponsive Metal–organic Frameworks. Acs Appl Mater Inter 2018, 10, 2735-2744.

Fang, J.-J.; Yang, N.-N.; Gao, E.-Q.* Making metal–organic frameworks electron-deficient for ultrasensitive electrochemical detection of dopamine. Electrochem. Commun. 2018, 89, 32-37.

Q. Sui, Y. Yuan, N.-N. Yang, X. Li, T. Gong, E.-Q. Gao* and L. Wang,* Coordination-modulated piezochromism in metal–viologen materials, Journal of Materials Chemistry C, 2017,5, 12400-12408.

Q. Sui, N.-N. Yang, T. Gong, P. Li, Y. Yuan, E.-Q. Gao* and L. Wang,* Impact of Lattice Water on Solid-State Electron Transfer in Viologen Pseudopolymorphs: Modulation of Photo- and Piezochromism, J. Phys. Chem. Lett., 2017, 8, 5450-5455.

Q. Sui, X.-T. Ren, Y.-X. Dai, K. Wang, W.-T. Li, T. Gong, J.-J. Fang, B. Zou, E.-Q. Gao* and L. Wang,* Piezochromism and hydrochromism through electron transfer: new stories for viologen materials, Chem. Sci., 2017, 8, 2758-2768.

N.-N. Yang, W. Sun, F.-G. Xi, Q. Sui, L.-J. Chen and E.-Q. Gao*, Postsynthetic N-methylation making a metal-organic framework responsive to alkylamines, Chem. Commun., 2017, 53, 1747-1750.
J.-Y. Zhang, Y. Ma, A.-L. Cheng, Q. Yue, Q. Sun and E.-Q. Gao*, Synthesis, structures, and magnetic properties of transition metal compounds with 2,2'-dinitrobiphenyl-4,4'-dicarboxylate and N,N'-chelating ligands, Dalton Trans., 2011, 40, 7219-7227.
X.-M. Zhang, Y.-Q. Wang, Y. Song and E.-Q. Gao*, Synthesis, structures, and magnetism of copper(II) and manganese(II) coordination polymers with azide and pyridylbenzoates, Inorg. Chem., 2011, 50, 7284-7294.
Y.-Q. Wang, Q. Sun, Q. Yue, A.-L. Cheng, Y. Song and E.-Q. Gao*, Manganese(II)-carboxylate-pseudohalide systems derived from 1,4-bis(4-carboxylatopyridinium-1-methylene)benzene: structures and magnetism, Dalton Trans., 2011, 40, 10966-10974.
X.-M. Zhang, K. Wang, Y.-Q. Wang and E.-Q. Gao*, Isomorphous Co(II) and Ni(II) antiferromagnets based on mixed azide- and carboxylate-bridged chains: metamagnetism and single-chain dynamics, Dalton Trans., 2011, 40, 12742-12749.
H. Tian, Q.-X. Jia, E.-Q. Gao* and Q.-L. Wang, Long-range ordering or not: magnetic properties modulated by second ligands in flexible three-dimensional metal-organic frameworks, Chem. Commun., 2010, 46, 5349-5351.
Y.-Q. Wang, Q.-X. Jia, K. Wang, A.-L. Cheng and E.-Q. Gao*, Diverse Manganese(II) Coordination Polymers with Mixed Azide and Zwitterionic Dicarboxylate Ligands: Structure and Magnetic Properties, Inorg. Chem., 2010, 49, 1551-1560.
J.-Y. Zhang, A.-L. Cheng, Q. Sun, Q. Yue and E.-Q. Gao*, Syntheses, Structures, and Properties of Honeycomb and Square Grid Coordination Polymers with In Situ Formed 5-(2 '-Pyrimidyl)tetrazolate, Cryst. Growth Des., 2010, 10, 2908-2915.
Y. Ma, X.-B. Li, X. C. Yi, Q.-X. Jia, E.-Q. Gao* and C. M. Liu, Novel Three-Dimensional Metal-Azide Network Induced by a Bipyridine-Based Zwitterionic Monocarboxylate Ligand: Structures and Magnetism, Inorg. Chem., 2010, 49, 8092-8098.
Q. Yue, Q. Sun, A.-L. Cheng and E.-Q. Gao*, Metal-Organic Framework Based on [Zn(4)O(COO)(6)] Clusters: Rare 3D Kagome Topology and Luminescence, Cryst. Growth Des., 2010, 10, 44-47.
Q. Yue, L. Yan, J.-Y. Zhang and E.-Q. Gao*, Novel Functionalized Metal-Organic Framework Based on Unique Hexagonal Prismatic Clusters, Inorg. Chem., 2010, 49, 8647-8649.
Y. Ma, A.-L. Cheng and E.-Q. Gao*, Ferromagnetic interactions through triple hydrogen bonds in the coordination polymers of alpha,alpha '-dihydroxy-bibenzyl-4,4 '-dicarboxylate, Dalton Trans., 2010, 39, 3521-3526.
Y. Ma, A.-L. Cheng and E.-Q. Gao*, Novel 2D -> 2D Entanglement Pattern in the Coordination Network with Both Polyrotaxane and Polycatenane Features, Cryst. Growth Des., 2010, 10, 2832-2834.
Y. Ma, Y. Q. Wen, J.-Y. Zhang, E.-Q. Gao* and C. M. Liu, Structures and magnetism of azide- and carboxylate-bridged metal(II) systems derived from 1,2-bis(N-carboxymethyl-4-pyridinio)ethane, Dalton Trans., 2010, 39, 1846-1854.
W. W. Sun, C. Y. Tian, X.-H. Jing, Y.-Q. Wang and E.-Q. Gao*, Solvent-modulated metamagnetism in a nickel(II) coordination polymer with mixed azide and carboxylate bridges, Chem. Commun., 2009, 4741-4743.
E.-Q. Gao*, P. P. Liu, Y.-Q. Wang, Q. Yue and Q. L. Wang, Complex Long-Range Magnetic Ordering Behaviors in Anisotropic Cobalt(II)-Azide Multilayer Systems, Chem. Eur. J., 2009, 15, 1217-1226.
Q.-X. Jia, W. W. Sun, C. F. Yao, H. H. Wu, E.-Q. Gao* and C. M. Liu, Coordination chemistry of tetrazolate-5-carboxylate with manganese(II): synthesis, structure and magnetism, Dalton Trans., 2009, 2721-2730.
Y. Ma, A.-L. Cheng, J.-Y. Zhang, Q. Yue and E.-Q. Gao*, One-, Two-, and Three-Dimensional Coordination Polymers of Stilbenedicarboxylate with Different Metal Ions, Cryst. Growth Des., 2009, 9, 867-873.
Y. Ma, J.-Y. Zhang, A.-L. Cheng, Q. Sun, E.-Q. Gao* and C. M. Liu, Antiferro- and Ferromagnetic Interactions in Mn(II), Co(II), and Ni(II) Compounds with Mixed Azide-Carboxylate Bridges, Inorg. Chem., 2009, 48, 6142-6151.
Q. Sun, Q. Yue, J.-Y. Zhang, L. Wang, X. Li and E.-Q. Gao*, Hydrothermal Synthesis, Structures, and Properties of Manganese(II) and Zinc(II) Coordination Polymers with Different Phenylenediacrylates, Cryst. Growth Des., 2009, 9, 2310-2317.
C. Y. Tian, W. W. Sun, Q.-X. Jia, H. Tian and E.-Q. Gao*, A novel manganese(II) coordination polymer with azide and neutral dicarboxylate ligands: helical structure and magnetic properties, Dalton Trans., 2009, 6109-6113.
Y.-Q. Wang, K. Wang, Q. Sun, H. Tian, E.-Q. Gao* and Y. Song, Novel manganese(II) and cobalt(II) 3D polymers with mixed cyanate and carboxylate bridges: crystal structure and magnetic properties, Dalton Trans., 2009, 9854-9859.
Y.-Q. Wang, J.-Y. Zhang, O. X. Jia, E.-Q. Gao* and C. M. Liu, Unprecedented Self-Catenated Eight-Connected Network Based on Novel Azide-Bridged Tetramanganese(II) Clusters, Inorg. Chem., 2009, 48, 789-791.
L. Yan, Q. Yue, Q.-X. Jia, G. Lemercier and E.-Q. Gao*, Lanthanide Metal-Organic Frameworks Based on Octahedral Secondary Building Units: Rare Net Topology and Luminescence, Cryst. Growth Des., 2009, 9, 2984-2987.
Q.-X. Jia, Y.-Q. Wang, Q. Yue, Q. L. Wang and E.-Q. Gao*, Isomorphous Co(II) and Mn(II) materials of tetrazolate-5-carboxylate with an unprecedented self-penetrating net and distinct magnetic behaviours, Chem. Commun., 2008, 4894-4896.
J.-Y. Zhang, A.-L. Cheng, Q. Yue, W. W. Sun and E.-Q. Gao*, Eight coordination with bis(bidentate) bridging ligands: zeolitic topology versus square grid networks, Chem. Commun., 2008, 847-849.
A.-L. Cheng, Y. Ma, J.-Y. Zhang and E.-Q. Gao*, Towards tuning the packing and entanglement of zigzag coordination chains by terminal ligands, Dalton Trans., 2008, 1993-2004.
N. Liu, Q. Yue, Y.-Q. Wang, A.-L. Cheng and E.-Q. Gao*, Coordination compounds of bis(5-tetrazolyl)amine with manganese(II), zinc(II) and cadmium(II): synthesis, structure and magnetic properties, Dalton Trans., 2008, 4621-4629.
P. P. Liu, A.-L. Cheng, N. Liu, W. W. Sun and E.-Q. Gao*, Cobalt(II) coordination networks dependent upon the spacer length of flexible bis(tetrazole) ligands, Cryst. Growth Des., 2008, 8, 1668-1674.
J.-Y. Zhang, Y. Ma, A.-L. Cheng, Q. Yue, Q. Sun and E.-Q. Gao*, A manganese(II) coordination polymer with mixed pyrimidine-2-carboxylate and oxalate bridges: synthesis, structure, and magnetism, Dalton Trans., 2008, 2061-2066.
A.-L. Cheng, N. Liu, Y. F. Yue, Y. W. Jiang, E.-Q. Gao*, C. H. Yan and M. Y. He, Unprecedented 3D entanglement of 1D zigzag coordination polymers leading to a robust microporous framework, Chem. Commun., 2007, 407-409.
E.-Q. Gao*, N. Liu, A.-L. Cheng and S. Gao, Novel frustrated magnetic lattice based on triangular [Mn-3(mu(3)-F)] clusters with tetrazole ligands, Chem. Commun., 2007, 2470-2472.
P. P. Liu, A.-L. Cheng, N. Liu, W. W. Sun and E.-Q. Gao*, Toward tuning the bulk magnetic behaviors of metal-azido materials by organic pillars, Chem. Mater., 2007, 19, 2724-2726.
A.-L. Cheng, N. Liu, J.-Y. Zhang and E.-Q. Gao*, Assembling the cage-based metal-organic network from a cubic metalloligand, Inorg. Chem., 2007, 46, 1034-1035.
W. W. Sun, A.-L. Cheng, Q.-X. Jia and E.-Q. Gao*, Metal-coordination-directed assembly of binuclear trigonal prisms and three-dimensional hydrogen-bonded networks, Inorg. Chem., 2007, 46, 5471-5473.
E.-Q. Gao, S. Q. Bai, H. Zheng and C. H. Yan, Tetramanganese(II) cluster with centered trigonal topology: Structure and magnetic properties, Inorg. Chem., 2005, 44, 677-682.
E.-Q. Gao*, A.-L. Cheng, Y. X. Xu, M. Y. He and C. H. Yan, From low-dimensional manganese(II) azido motifs to higher-dimensional materials: Structure and magnetic properties, Inorg. Chem., 2005, 44, 8822-8835.
E.-Q. Gao*, A.-L. Cheng, Y. X. Xu, C. H. Yan and M. Y. He, New inorganic-organic hybrid supramolecular architectures generated from 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene, Cryst. Growth Des., 2005, 5, 1005-1011.
E.-Q. Gao, Y. F. Yue, S. Q. Bai, Z. He and C. H. Yan, One-dimensional copper(II) complexes containing only single end-on azido bridges: Crystal structures and magnetic properties, Cryst. Growth Des., 2005, 5, 1119-1124.
E.-Q. Gao, Y. F. Yue, S. Q. Bai, Z. He and C. H. Yan, From achiral ligands to chiral coordination polymers: Spontaneous resolution, weak ferromagnetism, and topological ferrimagnetism, J. Am. Chem. Soc., 2004, 126, 1419-1429.
E.-Q. Gao, Y. F. Yue, S. Q. Bai, Z. He, S. W. Zhang and C. H. Yan, New two-dimensional manganese(II)-azido polymers with bidentate coligands: Structure and magnetic properties, Chem. Mater., 2004, 16, 1590-1596.
E.-Q. Gao, Z. M. Wang and C. H. Yan, From manganese(II)-azido layers to a novel three-dimensional molecular magnet: spin canting and metamagnetism, Chem. Commun., 2003, 1748-1749.
E.-Q. Gao, S. Q. Bai, Z. M. Wang and C. H. Yan, Two-dimensional homochiral manganese(II)-azido frameworks incorporating an achiral ligand: Partial spontaneous resolution and weak ferromagnetism, J. Am. Chem. Soc., 2003, 125, 4984-4985.
E.-Q. Gao, S. Q. Bai, C. F. Wang, Y. F. Yue and C. H. Yan, Structural and magnetic properties of three one-dimensional azido-bridged copper(II) and manganese(II) coordination polymers, Inorg. Chem., 2003, 42, 8456-8464.
E.-Q. Gao, S. Q. Bai, Y. F. Yue, Z. M. Wang and C. H. Yan, New one-dimensional azido-bridged manganese(II) coordination polymers exhibiting alternating ferromagnetic-antiferromagnetic interactions: Structural and magnetic studies, Inorg. Chem., 2003, 42, 3642-3649.

1. 一种共价有机框架高效绿色通用的熔融合成方法
浙江大学杭州国际科创中心
卜然; 高恩庆; 穆鹏飞
公开日期: 2024-10-29 申请日期: 2024-07-11 公开号: CN118852568A

2. 一种适用于多种类型共价有机框架的绿色合成方法
华东师范大学
高恩庆; 穆鹏飞; 张大卫
公开日期: 2024-08-30 申请日期: 2024-06-03 公开号: CN118562081A

国家自然科学基金重大项目(No. 20490210)。
国家自然科学基金面上项目(No. 20201009)。
上海市教委和上海市教育发展基金会“曙光”计划(04SG28, 人才培养项目)。
上海市科委自然科学基金(03ZR14024)。
北京大学稀土材料化学与应用国家重点实验室开放基金。
中科院福建物质结构研究所结构化学国家重点实验室开放基金。

技术咨询