新能源,储能

1.高分子材料结构设计与性能调控
2.有机-无机杂化分子材料的设计制备与应用研究
3.新化学电源设计及新能源材料的设计制备
4.功能高分子材料及其复合材料制备与性能调控
5.国防技术基础研究
2023-2026，国家自然科学基金，酶@二维导电MOFs协同催化电极的构筑及其自充电生物超级电容器的性能，53万直接经费
2021-2025，纵向，高低温XXX制备与性能研究，56万，主持；
2021-2025，纵向，活性阻燃烧蚀填料的制备及XXXXX研究，99万，主持；
2022-2023，陕西省重点研发计划一般项目，二茂铁腙及其配合物类燃烧催化剂的设计、合成与性能，12万，主持；
2021-2023，横向课题，XXX标准物质的定值研究，39.8万，主持；
2021-2024，横向课题，耐烧蚀材料的研制，20万，主持；
2020-2021，横向课题，计量标准物质的研制，10万，主持；
2020-2021，陕西省重点研发计划项目，高性能储能固态聚合物电解质的制备与性能，20万，主持；
2020-2021，横向课题，低介电、耐高温树脂用反应型POSS研制，37万，主持；
2018-2021，国家自然基金（面上），可调控双重响应立体金杂化碳基酶电极及其可“开/关”燃料电池的性能，61万，主持；
2019-2020，陕西省重点研发计划项目，新型功能性化学品及其杂化树脂复合材料的研制，90万，主持；
2017-2020，国防科技项目，固体推进剂燃速催化剂XXX标准物质研制，300万，主持；
2017-2019，深圳市科技计划项目，柔性多孔导电基底表面可控聚合及其响应性酶生物电极的构筑研究，50万，主持；
2017-2019，深圳市科技计划项目，主持；
2016-2017，陕西省科技统筹项目，主持；
2014-2017，国家自然科学基金项目，主持。

凝胶聚合物电解质;离子电导率;自组装;力学性能;有机累托石;嵌段共聚物;凝胶电解质;热稳定性;热性能;聚合物

Rectorite;Thermal Stability;Mechanical Properties;Nanocomposites;POSS;Ionic Conductivity;Gel Polymer Electrolyte;Molecular Simulation;Sensor;Thermal Properties

1.     Ma PC, Ma XY. High-sensitivity and temperature-controlled switching methanol sensor prepared based on the dual catalysis of copper particles. Talanta. 2022; 237,122888.
2.     Song SY, Ma XY, Zhang BY, Li WY, et al. Morphologies of thienyl based bimetallic metal-organic frameworks controlled by solvents for high specific capacitance supercapacitor. Journal of Energy Storage. 2022; 47, 103627.
3.     Ma JY, Ma XY*, et al. In-situ generation of poly(ionic liquid) flexible quasi-solid electrolyte supported by polyhedral oligomeric silsesquioxane/polyvinylidene fluoride electrospun membrane for lithium metal battery. Journal of Membrane Science. 2022; 659: 120811.
4.     Ma JY, Ma XY, et al. Star-shaped polyethylene glycol methyl ether methacrylate-co-polyhedral oligomeric silsesquioxane modified poly(ethylene oxide)-based solid polymer electrolyte for lithium secondary battery. Solid State Ionics. 2022; 380: 115923.
5.     Zhang Z, Zhou Y, Cai L, Xuan L, Wu X, Ma X. Synthesis of eugenol-functionalized polyhedral oligomer silsesquioxane for low-k bismaleimide resin combined with excellent mechanical and thermal properties as well as its composite reinforced by silicon fiber. Chemical Engineering Journal. 2022; 439: 135740.
6.     Zhou Y, Zhang Z, Wang P, Ma X. High-performance and low-dielectric cyanate ester resin optimized by regulating the structure of linear polyhydroxy ether modifier. Composites Part A: Applied Science and Manufacturing. 2022; 162: 107136.
7.     Niu ZQ, Li G, Ma XY, Shen S, Xin Y, Cai LF, et al. Synergetic effect of O-POSS and T-POSS to enhance ablative resistant of phenolic-based silica fiber composites via strong interphase strength and ceramic formation. Composites Part A: Applied Science Manufacturing. 2022; 155, 106855.
8.     Niu ZQ, Chen BX, Shen S, Zhang HP, Ma XY, Chen F, Li LY, Xin Y, Zhang CS, Hou X. Zirconium chelated hybrid phenolic resin with enhanced thermal and ablation resistance properties for thermal insulation composites. Composites Communications. 2022; 35: 101284.
9.     Niu ZQ, Li G, Xin Y, Ma XY, Zhang CS, Hou X. Enhanced thermal and anti-ablation properties of high-temperature resistant reactive POSS modified boron phenolic resin. Journal of Applied Polymer Science. 2022; 139: 52087.
10.  Shen S, Guo HB, Ma XY, Ma XT, Niu ZQ, Xin Y, Hou X. Enhanced ablation resistance of Divinyl-POSS modified additional liquid silicone rubber and its fiber reinforced composite. Polymer Composites. 2022; 43(5): 2896.
11.  Shen S, Xin Y, Niu ZQ, Ma XT, Zhang JA, Hou X, Ma XY. Phosphazene derivative cross-linked liquid silicone rubber and its mechanical and thermal properties. Polymer Degradation and Stability. 2022; 203: 110086.
12.  Ma XT, Ji TZ, Ma XY. Effects of Bifunctional Reactive Polyhedral Oligomeric Silsesquioxane on the Properties of EPDM. Journal of applied polymer science. 2022; 139: e51486.
13.  Liu XJ, Feng HT, Li Y, Ma XY, Yan QL. Effects of high‐energy multicore ferrocene‐based catalysts on the thermal decomposition of ammonium perchlorate, Applied Organometallic Chemistry. 2022; 36: e6605.
14.  Feng HT, Liu XJ, Li Y, Ma XY, Yan QL, Zhao FQ. Novel powder catalysts of ferrocene-based metal-organic framework and their catalytic performance for thermal decomposition of ammonium perchlorate. Powder Technology. 2022; 397: 117035.
15.  Hui YC, Ma XY, et al. Spider nest shaped multi-scale three-dimensional enzymatic electrodes for glucose/oxygen biofuel cells. International Journal of Hydrogen Energy. 2022; 47(9): 6187-6199.
16.  Song SS, Ma XY, et al. Morphologies of thienyl based bimetallic metal-organic frameworks controlled by solvents for high specific capacitance supercapacitor. Journal of Energy Storage. 2022; 47: 103627.
17.  Liu XJ, Feng HT, Li Y, Ma XY, Chen F, Yan QL. Ferrocene-based hydrazone energetic transition-metal complexes as multifunctional combustion catalysts for the thermal decomposition of ammonium perchlorate. Journal of Industrial and Engineering Chemistry. 2022; online.
18.  Qu FJ, Ma XY, et al. Precise positioning of enzymes within hierarchical polymer nanostructures for switchable bioelectrocatalysis. Biosensors & Bioelectronics. 2021; 179(3): 113045.
19.  Hui YC, Ma XY, et al. Three-Dimensional Glucose/Oxygen Biofuel Cells Based on Enzymes Embedded in Tetrabutylammonium Modified Nafion. Journal of Electrochemical Energy Conversion and Storage. 2021, 18(4): 1-16.
20.  Ma PC, Ma XY, et al. The Construction of Stimulus-responsive Film Electrode by the Cu-catalyzed Radical Polymerization and its Application in Multi-valued Biologic Systems. Electroanalysis. 2021; 33(12): 2437-2444.
21.  Yan L, Ma XY, et al. A feasible electrochemical biosensor for determination of glucose based on Prussian blue - Enzyme aggregates cascade catalytic system. Bioelectrochemistry. 2021, 141(10): 107838.
22.  Miao KP, Ma XY, et al. Enzymatic Biosensor Based on One-step Electrodeposition of Graphene-gold Nanohybrid Materials and its Sensing Performance for Glucose. Electroanalysis, 2021, 33(10): 2243-2251.
23.  苗昆鹏,闫龙,马鹏程,马晓燕. 酶生物燃料电池的研究进展. 电源技术. 2021; 45(03): 406-409+423.
24.  Zhang BY, Song SY, Li WY, et al. Asymmetric supercapacitors with high energy density and high specific capacitance based on Ni-Co-Mn multiphase metal structure MOF. Ionics. 2021; 27: 3553-3566.
25.  Ma JY, Ma XY, et al. Li6.4La3Zr1.4Ta0.6O12/star-shaped hybrid polyhedral oligomeric cage silsesquioxane polymer composite electrolytes for all-solid-state lithium metal batteries. ACS Applied Energy Materials. 2021; 4(12): 14709–14717.
26.  Ma JY, Ma XY, et al. Polyethylene glycol functionalized polyhedral cage silsesquioxane as all solid-state polymer electrolyte for lithium metal batteries. Solid State Ionics. 2021; 363: 115606.
27.  Zhang ZW, Tian D, Niu ZQ, Zhou YJ, Hou X, Ma XY. Enhanced toughness and lowered dielectric loss of reactive POSS modified bismaleimide resin as well as the silica fiber reinforced composites. Polymer Composite. 2021; 42(12): 6900-11.
28.  刘晓菊, 索奇, 冯海涛, 张驰, 马晓燕. 高含量卡托辛合成的理论与实验研究. 北京航空航天大学学报. 2021; 47(12): 7.
29.  冯海涛, 索齐, 张驰, 刘晓菊, 马晓燕. 工业级卡托辛成分分析及其双核二茂铁制备工艺. 兵工学报. 2021; 42(05): 961-967.
30.  冯海涛, 刘晓菊, 张弛, 王艳丽, 马晓燕. 复合固体推进剂用新型二茂铁类燃速催化剂研究进展. 化工进展. 2021; 40(05): 2560-2573.
31.  Liu XJ, Ma XY, Feng HT, Zhang C. Theoretical Simulation and Experimental Optimization of Reaction Conditions and Product Composition of Ferrocene Acylation. Russian Journal of Physical Chemistry A. 2021; 95: S252-S258.
32.  Yan L, Ma XY, et al. 3D coral-like gold/carbon paper electrode modified with covalent and cross-linked enzyme aggregates for electrochemical sensing of glucose. Microchemical Journal. 2020; 159(8): 105347.
33.  田丹, 索奇, 马晓燕. 双环氧基笼型倍半硅氧烷/氰酸酯树脂复合材料的制备与性能. 复合材料学报. 2020; 37(03): 512-518.
34.  Niu ZQ, Tian D, Yan L, Ma XY, Zhang CS, Hou X. Synthesis of 3,13-diglycidyloxy-propyloctaphenyl double-decker polyhedral oligomeric silsesquioxane and the thermal reaction properties with thermosetting phenol-formaldehyde resin. Journal of Applied Polymer Science. 2020; 137: 49376.
35.  Qu FJ, Ma XY, et al. A Kinetic Model of Oligonucleotide-Brush Interactions for the Rational Design of Gene Delivery Vectors. Biomacromolecules. 2019; 20(6): 2218-2229.
36.  Hui YC, Ma XY, et al. Flexible glucose/oxygen enzymatic biofuel cells based on three-dimensional gold-coated nickel foam. Journal of Solid State Electrochemistry. 2019; 23(1): 169-178.
37.  Ma PC, Ma XY, et al. Cu NPs@NiF electrode preparation by rapid one-step electrodeposition and its sensing performance for glucose. Sensors & Actuators, B: Chemical. 2019; 292: 203-209.
38.  马敬玉, 马晓燕, 等. POSS-(PMMA46)8浸渍涂覆商业PP隔膜的结构与性能. 材料工程. 2019; 9: 116-122.
39.  马敬玉, 马晓燕, 等. 静电纺丝法制备POSS-(C3H6Cl)8复合聚偏氟乙烯聚合物隔膜的结构与性能. 高分子材料科学与工程. 2018; 6: 54-59.
40.  Yu J, Yin WY, Peng T, Chang YN, Zu Y, Li J, et al. Biodistribution, excretion, and toxicity of polyethyleneimine modified NaYFW4: Yb, Er upconversion nanoparticles in mice via different administration routes. Nanoscale. 2017;9(13):4497-507.

1.   马晓燕，鹿海军，颜红侠，有机累托石的生产工艺，专利号：ZL 02139340.0
2.   马晓燕，刘海林，梁国正，一种制备带环氧基倍半硅氧烷的方法，专利号：ZL 200410073197.8
3.   马晓燕，鹿海军，朱光明，累托石/热塑性聚氨酯弹性体纳米复合材料及制备方法，专利号：ZL 02139341.9
4.   马晓燕，鹿海军，梁国正，累托石/聚丙烯纳米复合材料及其制备方法，专利号：ZL 02139339.7
5.   马晓燕，黄韵，梁国正，陈芳，凝胶型聚甲基丙烯酸甲酯/有机累托石电解质及其制备方法，专利号：ZL 200510041814.0
6.   马晓燕，王书会，颜红侠，黄韵，一种凝胶聚合物电解质及其制备方法，专利号：ZL 200610105180.5
7.   马晓燕，朱雅红，梁国正，液体聚氨酯弹性体/热固性氰酸酯树脂的改性体系及其制备方法，专利号：ZL 200410073196.3
8.   梁国正，姚雪丽， 马晓燕 ，纳米二氧化硅/聚氨酯/氰酸酯树脂复合材料的制备，专利号：ZL 200510042653.7
9.   马晓燕， 陈芳，原位聚合制备有机累托石/聚甲基丙烯酸甲酯凝胶聚合物电解质的方法，专利号：ZL 200610043126.2
10.  马晓燕，陈芳，梁国正，黄韵，一步法引发聚合制备纳米二氧化硅/聚甲基丙烯酸甲酯凝胶聚合物电解质的方法，专利号：ZL 200610043125.8
11.  马晓燕，侯宪冰，强秀，星型倍半硅氧烷聚乙二醇单甲醚丙烯酸酯嵌段共聚物凝胶聚合物电解质及制备方法，专利号：ZL 201210039593.3
15.  马晓燕，佘希锋，徐敬生，唐林，余韬，一种有机累托石/聚脲纳米复合材料，专利号：201110274736.4
17.  马晓燕，朱小波，聚烯烃类凝胶聚合物电解质锂离子电池的组装工艺，专利号：CN201010185436.4。
20.  马晓燕，栗志广，强秀，余杰，张杰， 一种两亲含氟丙烯酸酯五嵌段共聚物及其制备方法，专利号： ZL201210396096
21.  马晓燕，郭志贤，霍晓卿，孙会昭，金龙，张帆，分离辛基二茂铁同分异构体（2-辛基）-二茂铁、（3-辛基）-二茂铁、（4-辛基）-二茂铁的方法，专利号：ZL20150390562.6
12.  马晓燕，周华龙，张启路，一种有机累托石改性复合凝胶型电解质及其制备方法，专利号：ZL200910218670.X
13.  马晓燕，李冬梅，唐林，田娜，两步聚合方法制备聚（苯乙烯-b-丙烯腈）的方法，专利号：ZL201010221814.X
14.  马晓燕，宋颖，惠昱晨，一种功能化氧化石墨烯改性复合凝胶电解质及其制备方法，专利号：ZL201210387782.X
16.  马晓燕，宋颖，有机累托石复合聚甲基丙烯酸甲酯嵌段聚苯乙烯共聚物凝胶聚合物电解质及其制备方法，专利号：ZL201210120357.4
18.  马晓燕，周华龙，宋颖，强秀，一种基于两嵌段聚甲基丙烯酸甲酯-聚苯乙烯共聚物的锂离子凝胶电解质及其制备方法，专利号：ZL201110223100.7
19.  马晓燕，强秀，夏雨，栗志广，张檬，余韬，基于蝌蚪型倍半硅氧烷接枝含氟丙烯酸酯类杂化高分子的蜂窝状多孔薄膜的制备方法，专利号：ZL201310391184.4
22.  马晓燕，郭志贤，霍晓卿，一种辛基二茂铁原料的分级分离纯化方法，专利号：ZL201510128581.1
23.  马晓燕，郭志贤，霍晓卿，邢佩雯，刘敏等，混合溶剂重结晶高效制备高纯度正辛基二茂铁的方法，专利号：ZL201410810883.2
24.  马晓燕，惠昱晨，屈枫锦，一种环糊精与纳米金修玻碳电极的制备方法，专利号：ZL201410282808.3

1. 环糊精调制杂化石墨烯双重电子转移网络酶电极及其燃料电池的性能
立项时间: 2014-2017 项目经费：800000

2. 酶@二维导电MOFs协同催化电极的构筑及其自充电生物超级电容器的性能
立项时间: 2022

3. POSS改性锂离子电池复合凝胶聚合物电解质的制备与性能
立项时间: 2017

4. POSS-(PEG)8聚合物锂离子电池固态电解质的结构与性能
立项时间: 2018

5. POSS超支化聚合物的设计合成与其全固态电解质的性能
立项时间: 2020

6. 新型共轭金属有机框架材料的设计及电容性能研究
立项时间: 2022

7. POSS杂化高分子基全固态聚合物电解质结构与性能的研究
立项时间: 2019-2021

8. 定向固定法温度刺激响应酶电极的制备与调控
立项时间: 2019-2021

9. 杂化酚醛树脂及其碳纤维复合材料性能研究
立项时间: 2021

10. 电化学聚合法温度刺激响应酶电极的制备与性能调控
立项时间: 2018

11. 可调控 双重响应立体金杂化碳基酶电极及其可“开/关”燃料电池的性能
立项时间: 2018-2021

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