精细化工

1）精细化学品合成技术
2）CO2资源化利用技术

Ni/zro2;4-butynediol;Hydrogenation;Ni/al2o3;Ni/sio2;Nitro Compounds;Hypervalent Iodine Compounds;Heterogeneous Catalysts;Nano-composites;Homogeneous Catalysts

1. C. Wang*, L. Liu, Y. Liu, X. Yu, Z. Chen, Y. Han, Y. Wang, Y. Zhao, CO2 reforming of ethane using Ni-La intermetallic sites within a nanocapsule framework, Chemical Engineering Journal, 491 (2024) 152091.
2. C. Wang*, X. Hai, J. Bai, Y. Shi, L. Jing, H. Shi, Z. Chen, Y. Zhao, Elucidating the atomic stacking structure of nickel phyllosilicate catalysts and their consequences on efficient hydrogenation of 1, 4-butynediol to 1, 4-butanediol, Chemical Engineering Journal, 488 (2024) 150723.
3. L. Zhao, X. Yu, R. Wu, H. Li C. Wang*, Y. Zhao*, Effect of the Nature of Ni Species on Hydrogenation of 1,4-Butynediol over Ni/SiO2 Catalysts, ChemCatChem, (2024)
4. C. Wang*, J Li, F Zhang, et al. Heterogeneous synergistic catalysts enable efficient catalytic transfer hydrogenation of nitro compounds via in-situ provided hydrogen[J]. International Journal of Hydrogen Energy, 51 (2024) 1286–1305
5. Y. Liu, L. Liu, X. Yu, Y. Wang, G. Li, L. Li, C. Wang*, CO2 assistant oxidative dehydrogenation of isobutane to isobutene catalyzed by ZnCaZr solid solution, Journal of Fuel Chemistry and Technology, 52 (2024) 1.
6. L. Zhao, C. Wang*, J. Bai, R. Wu, H. Li, Y. Zhao, Hydrogenation of 2-hydroxytetrahydrofuran to 1,4-butanediol over Ni-Fe/SiO2 bimetallic catalysts, Catalysis Letters, 154 (2024) 448-460.
7. C. Wang*, X. Hai, J. Li, Y. Liu, X. Yu, Y. Zhao, Investigation of Ni-Cu-acid multifunctional synergism in NiCu-phyllosilicate catalysts toward the 1,4-butynediol hydrogenation to 1,4-butanediol, Dalton Transactions, 52 (2023) 17981-17992.
8. C. Wang*, C. Jiang, J. Bai, G. Yang, R. Wu, Y. Zhao, T. Xiao, Effect of pore structures on 1,4-butynediol hydrogenation over mesoporous Ni/Al2O3-SiO2 Catalysts, Industrial & Engineering Chemistry Research, 60 (2021) 17840-17849.
9. C. Wang*, H. Wu, X. Jie, X. Zhang, Y. Zhao, B. Yao, T. Xiao, Yolk–shell nanocapsule catalysts as nanoreactors with various shell structures and their diffusion effect on the CO2 reforming of methane, ACS Applied Materials & Interfaces, 13 (2021), 31699−31709.
10. Y. Gao, X. Jie, C. Wang, R.M.J. Jacobs, W. Li, B. Yao, J.R. Dilworth, T. Xiao, P.P. Edwards, One-pot synthesis of Ca oxide-promoted Cr catalysts for the dehydrogenation of propane using CO2, Industrial & Engineering Chemistry Research, 59 (2020) 12645-12656.
11. W. Li, X. Jie, C. Wang, MnOx-promoted, coking-resistant nickel-based catalysts for microwave-initiated CO2 utilization, Industrial & Engineering Chemistry Research, 59 (2020) 6914-6923.
12. 吴昊, 仇媛, 田亚妮, 王长真*, 赵永祥, Ni-SiO2催化剂空间限域维度对CH4-CO2重整反应金属抗积碳能力的影响, 高等学校化学学报, 41 (2020) 2488-2495.
13. C. Wang*, X. Jie, Y. Qiu, Y. Zhao, H.A. Al-Megren, S. Alshihri, P.P. Edwards, T. Xiao, The importance of inner cavity space within Ni@SiO2 nanocapsule catalysts for excellent coking resistance in the high-space-velocity dry reforming of methane, Applied Catalysis B: Environmental, 259 (2019) 118019.
14. C. Wang*, Y. Tian, R. Wu, H. Li, B. Yao, Y. Zhao, T. Xiao, Bimetallic synergy effects of phyllosilicate-derived NiCu@SiO2 catalysts for 1,4-butynediol direct hydrogenation to 1,4-butanediol, ChemCatChem, 11 (2019) 4777-4787.
15. 赵芳; 王长真*; 田亚妮; 王菊霞; 李海涛; 赵永祥, Ni-M/SiO2催化1,4-丁炔二醇加氢的金属助剂效应, 分子催化, 1 (2019) 83-89.
16. 田亚妮; 赵芳; 王长真*; 李海涛; 武瑞芳; 赵永祥,Cu对Ni-Cu/SiO2催化1,4-丁炔二醇加氢性能的影响, 分子催化, 2 (2019) 132-139.
17. C. Wang*, Y. Qiu, X. Zhang, Y. Zhang, N. Sun, Y. Zhao, Geometric design of a Ni@silica nano-capsule catalyst with superb methane dry reforming stability: enhanced confinement effect over the nickel site anchoring inside a capsule shell with an appropriate inner cavity. Catalysis Science & Technology, 8 (2018) 4877-4890.
18. H. Li, Y. Qiu, C. Wang*, et al, Nickel catalysts supported on ordered mesoporous SiC materials for CO2 reforming of methane. Catalysis Today, 317 (2018) 76–85.
19. 仇媛; 王长真*; 李海涛; 胡晓波; 王永钊; 赵永祥, 单分散Co3O4@SiO2核壳催化剂的制备及N2O催化分解性能, 化工学报, 4 (2018) 1493-1499.
20. C. Wang*, Y. Zhang, Y. Wang, Y. Zhao, Comparative studies of non-noble metal modified mesoporous M-Ni-CaO-ZrO2 (M=Fe, Co, Cu) catalysts for simulated biogas dry reforming, Chinese Journal of Chemistry, 35 (2017) 113-120.
21. C. Wang*, N. Sun, N. Zhao, W. Wei, Y. Zhao, Template-free preparation of bimetallic mesoporous Ni-Co-CaO-ZrO2 catalysts and their synergetic effect in dry reforming of methane, Catalysis Today, 281 (2017) 268-275.
22. X. Huang, C. Jia, C. Wang, F. Xiao, N. Zhao, N. Sun, W. Wei, Y. Sun, Ordered mesoporous CoO-NiO-Al2O3 bimetallic catalysts with dual confinement effects for CO2 reforming of CH4, Catalysis Today, 281 (2017) 241-249.
23. C. Wang, N. Sun, W. Wei, Y. Zhao, Carbon intermediates during CO2 reforming of methane over Ni-CaO-ZrO2 catalysts: A temperature-programmed surface reaction study, International Journal of Hydrogen Energy, 41 (2016) 19014-19024.
24. X. Huang, G. Xue, C. Wang, N. Zhao, N. Sun, W. Wei, Y. Sun, Highly stable mesoporous NiO-Y2O3-Al2O3 catalysts for CO2 reforming of methane: effect of Ni embedding and Y2O3 promotion, Catalysis Science & Technology, 6 (2016) 449-459.
25. C. Wang, N. Sun, N. Zhao, W. Wei, Y. Sun, C. Sun, H. Liu, C.E. Snape, Coking and deactivation of a mesoporous Ni-CaO-ZrO2 catalyst in dry reforming of methane: A study under different feeding compositions, Fuel, 143 (2015) 527-535.
26. X. Huang, N. Sun, G. Xue, C. Wang, H. Zhan, N. Zhao, F. Xiao, W. Wei, Y. Sun, Effect of pore geometries on the catalytic properties of NiO-Al2O3 catalysts in CO2 reforming of methane, RSC Advances, 5 (2015) 21090-21098.
27. C. Wang, N. Sun, N. Zhao, W. Wei, J. Zhang, T. Zhao, Y. Sun, C. Sun, H. Liu, C.E. Snape, The properties of individual carbon residuals and their influence on the deactivation of Ni-CaO-ZrO2 catalysts in CH4 dry reforming, ChemCatChem, 6 (2014) 640-648.
28. C. Wang, N. Sun, M. Kang, X. Wen, N. Zhao, F. Xiao, W. Wei, T. Zhao, Y. Sun, The bi-functional mechanism of CH4 dry reforming over a Ni-CaO-ZrO2 catalyst: further evidence via the identification of the active sites and kinetic studies, Catalysis Science & Technology, 3 (2013) 2435-2443.
29. C. Wang, L. Si, H. Li, X. Wen, N. Sun, N. Zhao, W. Wei, Y. Sun, Template-free one-pot synthesis of mesoporous Ni-CaO-ZrO2 catalyst and its application in CH4-CO2 reforming, Journal of Fuel Chemistry and Technology, 41 (2013) 1204-1209.

(1) 王长真; 刘玲技; 李磊; 一种C2+烷烃和二氧化碳向合成气转化反应的催化剂及制备, 2024-4-16, 中国, ZL202211149117.7.
(2) 王长真;李磊;刘玉鹏; 一种异丁烷-CO2脱氢反应的催化剂及其制备方法, 2024-3-15, 中国, ZL202211145320.7.
(3) 王长真;刘玉鹏;李磊;韩耀华; 一种CO2辅助烷烃脱氢的双功能催化剂及其制备和应用, 2023-12-26, 中国, ZL202211287507.0.
(4) 李磊;王长真;刘玉鹏; 一种微胶囊状改性Zn@ZSM-5催化剂及其制备方法和应用, 2023-10-27, 中国, ZL202211248942.2.
(5) 李磊;王长真;刘玉鹏; 一种异丁烷CO2氧化脱氢制异丁烯反应的钒基催化剂及制备, 2023-9-8, 中国, ZL 202211146097.8.
(6) 王长真; 赵永祥; 李海涛; 用于煤基1,4-丁炔二醇低温低压直接加氢催化剂及其制备方法, 2022-5-27, 中国, ZL202011369315.5.
(7) 王长真; 赵永祥; 张因; 武瑞芳; 一种镍-页硅酸盐结构催化剂及其制备方法, 2021-12-31, 中国, ZL202011369314.0.
(8) 王长真; 赵永祥; 李海涛; 田亚妮; 一种镍基核壳结构催化剂及其制备方法和应用, 2021-7-2, 中国, ZL201811563295.8.
(9) 王长真;赵永祥;李海涛;仇媛;周玮; 一种Ni基双金属纳米胶囊催化剂及其制备和应用, 2021-2-2, 中国, ZL201810712246.X.
(10) 王长真; 赵永祥; 王永钊; 李海涛; 一种中低温催化分解N2O的催化剂及制备方法和应用, 2020-7-10, 中国, ZL201710287978.4.
(11) 赵永祥; 王长真; 张因; 李海涛; 一种顺酐加氢制备丁二酸酐的催化剂及其制备方法, 2020-6-12, 中国, ZL201710815713.7.
(12) 王长真; 赵永祥; 王永钊; 仇媛; 李建立; 和进伟; 张方; 林伟; 用于甲烷和二氧化碳重整反应的镍负载碳化硅催化剂及制法和应用, 2020-6-12, 中国, ZL201710815722.6.
(13) 王长真; 赵永祥; 王永钊; 李海涛; 一种双金属钴基催化剂及制备方法和应用, 2020-1-3, 中国, ZL201710287979.9.
(14) 王长真; 王永钊; 赵永祥; 一种包覆纳米材料及其制备方法, 2018-10-19, 中国,ZL201610200597.3.

（1）国家自然科学基金面上项目，22178202，1,4-丁炔二醇“加氢-抗异构”多中心协同催化剂的构筑及作用机制研究，2022.1-2025.12，在研、主持。
（2）中央引导地方科技发展资金项目，YDZJSX2024D004，焦炉气CO2-蒸汽-氧重整制富氢还原气功能材料精准调控及其催化机理，2024.7-2027.7，在研、主持。
（3）山西省科技创新人才团队子课题，202204051001012，CO2捕集及矿化固废减污降碳关键技术，2022.7-2025.7，在研、主持。
（4）煤炭高效低碳利用全国重点实验室开放课题，J23-24-609-2，核壳催化剂微纳限域效应对低碳烷烃CO2重整催化性能影响机制研究，2023.4-2024.12，在研、主持。
（5）山西大学2024年度学科基础能力建设项目，煤基精细化学品催化合成产教融合研究生联合培养示范基地建设，2024.5-2026.5，在研、主持。
（6）山西省高等学校科技创新项目、2020L0018，新型功能协同催化剂应用于丁炔二醇高选择性加氢技术中的性能及机理，2021.1-2022.12，已结题、主持。
（7） 国家自然科学基金青年项目，21603127，基于核壳催化剂的微纳限域空间构筑及其在CH4-CO2重整中的抗积碳机制研究，2017.1-2019.12，已结题、主持。
（8）山西省应用基础研究计划、201601D202020，CH4-CO2重整核壳结构催化剂的设计及其空间限域效应对积碳转化作用机制的影响，2016.12-2018.12，已结题、主持。
（9）山西大学科研启动基金项目， 2014.9-2017.12，已结题，主持。

技术咨询