新能源,精细化工

新型功能有机多孔材料设计、合成及应用研究，包括：
1.  新能源领域（燃料电池、固态锂电池、超级电容器）；
2.  催化领域（光解水制H2，CO2还原、电催化）；
3.  环境领域（光降解、水处理、气体分离）；
4.  器件（膜器件、光电传感器、离子/气体/生物传感器）；

Air Pollution;Ozone;HAZE;Climate;Black Carbon;Multiphase Chemistry;Biomass Burning;Observation-based Model;Atmospheric Dust;Aerosol Formation

2022
46. Shuyang Bian, Guoji Huang, Yufeng Xuan, Boying He, Jincheng Liu, Bingqing Xu,* Gen Zhang*
Pore Surface Engineering of Covalent Organic Framework Membrane by Alkyl Chains for Lithium Based Batteries
J. Membr. Sci., 2022, 10.1016/j.memsci.2022.121268

45. Kaijie Yang, Yuxiang Wang, Zhiyi Ling, Xiaogang Pan, Gen Zhang,* Jian Su*
Alkoxy Phosphonic Acid-Functionalized Conjugated Microporous Polymers for Efficient and Multi-environmental Proton Conduction
Mater. Adv., 2022, doi.org/10.1039/D2MA00909A


44. Miaomiao Wu, Zhen Shan, Jinjian Wang, Tongtong Liu, Gen Zhang*
Three-dimensional covalent organic framework with tty topology for enhanced photocatalytic hydrogen peroxide production
Chemical Engineering Journal, 2022, 10.1016/j.cej.2022.140121

43. Yufeng Xuan, Yuxiang Wang, Boying He, Shuyang Bian, Jincheng Liu, Bingqing Xu*,  Gen Zhang*
Covalent Organic Framework-Derived Quasi-Solid Electrolyte for Low-Temperature Lithium-Ion Battery
Chem. Mater. 2022, 10.1021/acs.chemmater.2c01982

42. Shengdong Wang, Xiaohui Tang, Kaijie Yang, Bin Chen, Kun Zhang, Hong Xu, Weitao Wang, Gen Zhang,* Cheng Gu*
Facile, Direct, De Novo Synthesis of an Alkyl Phosphoric Acid-Decorated Covalent Organic Framework
Macromol. Rapid Commun. 2022, 2200678

41. Zhangjie Gu, Jinjian Wang, Zhen Shan, Miaomiao Wu, Tongtong Liu, Liang Song, Guixiang Wang, Xuehai Ju, Jian Su*, Gen Zhang*
Modulating electronic structure of triazine-based covalent organic frameworks for photocatalytic organic transformations
J. Mater. Chem. A, 2022,10, 17624-17632.

40. Hong-Rui Huang, Zhi-Mei Yang, Xiao-Cheng Zhou, Gen Zhang*, Jian Su*
Redox-Active Metal-Organic Frameworks withThree-Dimensional Lattice Containing the m-Tetrathiafulvalene-Tetrabenzoate
Molecules 2022, 27(13), 4052 (Invited Paper)


39. Zhen Shan, Siyao Cheng, Fan Wu, Xihao Pan, Weijin Li, Wei Dong, Aming Xie*, Gen Zhang*
Electrically Conductive Two-dimensional Metal-Organic Frameworks for Superior Electromagnetic Wave Absorption
Chemical Engineering Journal, 2022, 10.1016/j.cej.2022.137409

38. Miaomiao Wu, Hongrui Huang,  Bingqing Xu*, Gen Zhang*
Poly(ethylene glycol)-functionalized 3D covalent organic frameworks as solid-state polyelectrolytes
RSC Adv., 2022,12, 16354-16357

37. Zhen Shan, Miaomiao Wu, Dongyang Zhu, Xiaowei Wu*, Kan Zhang, Rafael Verduzco, Gen Zhang*
3D Covalent Organic Frameworks with Interpenetrated pcb Topology Based on 8-Connected Cubic Nodes
J. Am. Chem. Soc. 2022, 144, 5728−5733

36. Guang-Hui Yu, Chun-Lei Yang, Hong-Lei Zhao, Ai-Xuan Yu, Gen Zhang, Dong-Ying Du,* Zhong-Min Su
Mixed-linker Strategy for Construction of Metal–Organic Framework Combined with Dyes toward Alcohol Detection
Inorganic Chemistry, 2022, 61, 5318–5325


35. Ziya Liu, Kun Zhang, Guoji Huang, Shuyang Bian, Yang Huang, Xinzhu Jiang, Yaoyao Pan, Yuxiang Wang, Xifeng Xia, Bingqing Xu,* Gen Zhang*
Lithium-Ion Transport in Covalent Organic Framework Membrane
Chemical Engineering Journal, 2022, 433, 133550


2021
33. Ziya Liu, Kun Zhang, Guoji Huang, Bingqing Xu*, You-lee Hong, Xiaowei Wu, Yusuke Nishiyama, Satoshi Horike*, Gen Zhang*Susumu Kitagawa, High-Processable COF Gel Electrolyte Enabled by Side Chain Engineering for Lithium-ion Battery
Angew. Chem. Int. Ed., 2021, 10.1002/anie.202110695



32. Yuxiang Wang, Kun Zhang, Xinzhu Jiang, Ziya Liu, Shuyang Bian, Yaoyao Pan, Zhen Shan, Miaomiao Wu, Bingqing Xu,* Gen Zhang*
Branched Poly(ethylene glycol)-Functionalized Covalent Organic Frameworks as Solid Electrolytes
ACS Applied Energy Materials, 2021, 11720–11725

31. Yihan Du1, Kun Zhang1, Ziya Liu, Shaoxian Liu, Guoji Huang, Yang Huang, Qianqian Qin, Jiaxin Luo, Bingqing Xu,* Gen Zhang*
Encapsulating NH4Br in metal organic framework: achieving remarkable proton conduction in wide relative humidity range
Dalton Transactions, 2021, DOI: 10.1039/d1dt02253a


30.  Miaomiao Wu, Zhen Shan, Jinjian Wang, Zhangjie Gu, Xiaowei Wu, Bingqing Xu, Gen Zhang*
Three-Dimensional Covalent Organic Frameworks Based on π-Conjugated Tetrahedral Node, Chemical Communications, 2021, 57, 10379-10382

29.  Zhen Shan, Miaomiao Wu, Zhangjie Gu, Yusuke Nishiyama, Gen Zhang*
A Nonplanar 2D Covalent Organic Framework Derived from a Z-shaped Building Unit, Chemical Communications, 2021, 57, 9236-9239


28. Miaomiao Wu, Zhen Shan, Bingqing Xu,*  Gen Zhang*
Anion Anchored Conjugated Microporous Polymers as Solid Electrolytes, Chemical Engineering Journal, 2022, 427, 131728


27. Xiaowei Wu,1 Ziya Liu,1 Hu Guo, You-lee Hong, Bingqing Xu*, Kun Zhang, Yusuke Nishiyama, Wei Jiang, Satoshi Horike, Susumu Kitagawa, Gen Zhang*
Host–Guest Assembly of H-Bonding Networks in Covalent Organic Frameworks for Ultrafast and Anhydrous Proton Transfer
ACS Appl. Mater. Interfaces 2021,13, 37172–37178


26. Zhen Shan,‡ Miaomiao Wu,‡ Yihan Du, Bingqing Xu,* Boying He, Xiaowei Wu, Gen Zhang*
Covalent Organic Framework-Based Electrolytes for Fast Li+ Conduction and High-Temperature Solid-State Lithium-Ion Batteries
Chemistry of Materials, 2021, 33, 13, 5058–5066（selected as an ACS Editors' Choice）selected as Most Read Articles

25. Xinzhu Jiang, Kun Zhang, Yang Huang, Bingqing Xu*, Xuefeng Xu, Jiajun Zhang, Ziya Liu, Yuxiang Wang, Yaoyao Pan, Shuyang Bian, Qihang Chen, Xiaowei Wu, Gen Zhang*
Conjugated Microporous Polymer with C≡C and C-F Bonds: Achieving Remarkable Stability and Super Anhydrous Proton Conductivity
ACS Applied Materials & Interfaces. 2021, 10.1021/acsami.1c02355

2020
24. Zhen Shan,§ Xiaowei Wu,§ Bingqing Xu, Y. Hong, M. Wu, Y. Wang, Y. Nishiyama, J. Zhu, S. Horike, S. Kitagawa, Gen Zhang*
Dynamic Transformation between Covalent Organic Frameworks and Discrete Organic Cages
J. Am. Chem. Soc. 2020, 142, 21279-21284


23. Xiaowei Wu, Y.-l. Hong, Bingqing Xu, Y.Nishiyama, W. Jiang, J. Zhu, Gen Zhang* S. Kitagawa, S. Horike*
Perfluoroalkyl-functionalized Covalent Organic Frameworks with Superhydrophobicity for Anhydrous Proton Conduction
J. Am. Chem. Soc. 2020,142, 14357−14364



22.Ming-Shui Yao, Jia-Jia Zheng, Ai-Qian Wu, Gang Xu,Sanjog S Nagarkar,Gen Zhang,Masahiko Tsujimoto, Shigeyoshi Sakaki, Satoshi Horike, Kenichi Otake, SusumuKitagawa*
Dual-Ligand Porous Coordination Polymer Chemiresistor withModulated Conductivity and Porosity
Angew. Chem. Int. Ed.2020, 59, 172 –176


Prior to Najing University of Sci & Tech（before 2019）
2019
21. Gen Zhang, Y.-l. Hong, Y. Nishiyama, S. Bai, S. Kitagawa, S. Horike,Accumulation of Glassy Poly(ethylene oxide) Anchored in a Covalent Organic Framework as a Solid-State Li+ Electrolyte. J. Am. Chem. Soc. 2019, 141,1227–1234.


20. Jie Tang, Dan Chen, Gen Zhang, Hongwei Yang, Guangbin Cheng, A “Green” Primary Explosive: Design, Synthesis, and Testing, Synlett, 2019,DOI: 10.1055/s-0037-1611696

19.Beibei Zhou, Tengwu Zeng, Zhao-Lin Shi, Gen Zhang, Satoshi Horike,Yue-Biao Zhang, An Allosteric Metal–Organic Framework That Exhibits MultiplePore Configurations for the Optimization of HydrocarbonSeparation, Chem. Asian J.2019, DOI: 10.1002/asia.201900239

2018
18. Gen Zhang, M. Tsujimoto, D. Packwood, N. Duong, Y. Nishiyama, K. Kadota, S. Kitagawa, S. Horike, Construction of a Hierarchical Architecture of Covalent Organic Frameworks via a Post-Synthetic Approach.J. Am. Chem. Soc.,2018,140, 2602–2609.

2016
17. G Gil-Ramirez, S Hoekman, M O Kitching, D A Leigh, I Vitorica-Yrezabal, Gen Zhang, Tying a molecular overhand knot of single handedness and asymmetric catalysis with the corresponding pseudo-D3-symmetric trefoil knot. J. Am. Chem. Soc., 2016, 138, 13159-13162.

2015
16. Gen Zhang, G. Gil-Ramírez, A. Markevicius, C. Browne, I. J. Vitorica- Yrezabal, D. A. Leigh, Lanthanide Template Synthesis of Trefoil Knots of Single Handedness, J. Am. Chem. Soc., 2015, 137, 10437-10442.

2014
15.J.-F. Ayme, G. Gil-Ramirez, D. A. Leigh, J.-F. Lemonnier, A. Markevicius, C. A. Muryn, Gen Zhang, Synthesis of a Molecular Trefoil Knot, J. Am. Chem. Soc., 2014,136, 13142-13145.
14. Gen Zhang, Yunxia Ma, Guangbin Cheng, Dabin Liu, Rui Wang, A Unique Combined Source of “CN” from 1,2-Dichloroethane and TMSN3 in the Copper-Catalyzed Cyanation of a C(sp3)–H Bond Adjacent to a Nitrogen Atom, Org. Lett.2014, 16, 656-659.

13. Yunxia Ma, Gen Zhang, Jinlong Zhang, Dongxu Yang, Rui Wang, Organocatalyzed Asymmetric Oxidative Coupling of α-Csp3-H of Tertiary Amines to α,β-Unsaturated γ-Butyrolactam: Synthesis of MBH-Type Products,Org. Lett.2014,16, 5358-5361.

2013
12. Gen Zhang, Yunxia Ma, Shoulei Wang, Weidong Kong, Rui Wang, Chiral Organic Contact Ion Pairs in Metal-free Catalytic Enantioselective Oxidative Cross-dehydrogenative Coupling of Tertiary Amines to Ketones. Chem. Sci. 2013,4, 2645-2651.

11. Gen Zhang, Shoulei Wang, Yunxia Ma, Weidong Kong, Rui Wang, Mild Metal-Free Intramolecular Oxidative Alkylation of a Csp3-H Bond Adjacent to a Nitrogen Atom: AVersatile Approach to Ring-Fused Tetrahydroquinolines, Adv. Synth. Catal.2013, 355, 874-879.

2012
10.Gen Zhang, Yunxia Ma, Shoulei Wang, Yaohu Zhang, Rui Wang, Enantioselective Metal/Organo-Catalyzed Aerobic Oxidative sp3 C-H Olefination of Tertiary Amines Using Molecular Oxygen as the Sole Oxidant, J. Am. Chem. Soc. 2012, 134, 12334-12337.

9.GenZhang, Yaohu Zhang, Jiexi Yan, Ru Chen, Shoulei Wang, Yunxia Ma, Rui Wang, One-Pot Enantioselective Synthesis of Functionalized Pyranocoumarins and 2-Amino-4H-chromenes: Discovery of a Type of Potent Antibacterial Agent, J. Org. Chem.2012, 77, 878-888.

2011
8. Gen Zhang, Yaohu Zhang, Rui Wang,Catalytic Asymmetric Activation of a Csp3-H Bond Adjacent to a Nitrogen Atom: A Versatile Approach to Optically Active α-Alkyl α-Amino Acids and C1-Alkylated Tetrahydroisoquinoline Derivatives. Angew. Chem. Int. Ed.2011, 50, 10429-10433.

7. Gen Zhang, Yaohu Zhang, Xianxing Jiang, Wenjin Yan, Rui. Wang, Highly Enantioslective Synthesis of Multisubstituted Polyfunctional Dihydropyrrole via an Organocatalytic Tandem Michael/Cyclization Sequence, Org. Lett.2011,13, 3806-3809.

6. Xianxing Jiang, Yiqing Wang, Gen Zhang, Dan Fu, Futing Zhang, Ming Kai, Rui Wang, Enantioselective Synthesis of Cyclic Thioureas via Mannich Reaction and Concise Synthesis of Highly Optically Active Methylthioimidazolines: Discovery of a More Potent Antipyretic Agent, Adv. Synth. Catal.2011,353, 1787-1796.

2010
5. Xianxing Jiang, Gen Zhang, Dan Fu, Yiming Cao, Fangfang Shen, Rui Wang，Direct Organocatalytic Asymmetric Aldol Reaction of α-Isothiocyanato Imides to α-Ketoesters under Low Ligand Loading: A Doubly Stereocontrolled Approach to Cyclic Thiocarbamates Bearing Chiral Quaternary Stereocenters, Org. Lett.2010,12, 1544-1547.

4. Xianxing Jiang, Dan Fu, Gen Zhang, Yiming Cao, Luping Liu, Jingjing Song, Rui Wang, Highly Diastereo- and Enantioselective Mannich Reaction of Lactones with N-Boc-Aldimines Catalyzed by Bifunctional Rosin-derived Amine Thiourea Catalysts, Chem. Commun.2010,46, 4294-4296.

2009
3. Xianxing Jiang, Yifu Zhang, Lipeng Wu, Gen Zhang, Xing Liu, Hailong Zhang, Dan Fu, Rui Wang, Doubly Stereocontrolled Asymmetric Aza-Henry Reaction with in situ Generation of N-Boc-Imines Catalyzed by Novel Rosin-Derived Amine Thiourea Catalysts, Adv. Synth. Catal.2009, 351, 2096-2100.

2. Xianxing Jiang, Yifu Zhang, Xing Liu, Gen Zhang, Luhao Lai, Lipeng Wu, Jiannan Zhang,  Rui Wang, Enantio- and Diastereoselective Asymmetric Addition of 1,3-Dicarbonyl Compounds to Nitroalkenes in a Doubly Stereocontrolled Manner Catalyzed by Bifunctional Rosin-Derived Amine Thiourea Catalysts, J. Org. Chem.2009,74, 5562-5567.

1.陆瑛玮，李唯，冯云，张根，王锐. 天然多酚类化合物对谷氨酸引起嗜铬细胞瘤12细胞损伤的保护作用. 兰州大学学报, 2009, 3, 49-52.

1.  中组部 海外高层次人才项目经费
2.  国家自然科学基金委面上项目
3.  江苏省杰出青年基金
4.  南京理工大学科研启动经费
5.  江苏省双创人才经费
6.  中央高校基础科研业务费