精细化工

1、精细化学品制备与应用
2、有机氟化学反应与材料
3、荧光核苷合成与探针性质
4、天然产物提取分离和再加工
5、金属有机骨架材料

Crystal Structure;Hydrogen Bonding;Copper;Single-crystal X-ray Study;Palladium(ii) Complex;Square-planar Coordination;Tetramethylethylenediamine;Radical Reactions;Synthetic Methods;Sulfur Dioxide

1、Changge Zheng,* Chao Jiang, Shuai Huang, Kui Zhao, Yingying Fu, Mingyu Ma, and Jianquan Hong,* Transition-metal-free synthesis of aryl trifluoromethyl thioethers through indirect trifluoromethylthiolation of sodium arylsulfinate with TMSCF3,Org. Lett.2021, 23, 6982−6986.
2、Changge Zheng,* Shuai Huang, Yang Liu, Chao Jiang, Wei Zhang, Ge Fang, and Jianquan Hong,* Geometrically Selective denitrative trifluoromethylthiolation ofβ‑nitrostyrenes with AgSCF3for (E)‑vinyl trifluoromethyl thioethers,Org. Lett.2020, 22, 4868−4872.
3、Changge Zheng,* Yang Liu, Jianquan Hong, Shuai Huang, Wei Zhang, Yupeng Yang, Ge Fang, Ag(I)-Mediated oxidative radical trifluoromethylthiolation of alkenes,Synlett, 2019, 30, 1324-1328.
4、Changge Zheng,* Yang Liu, Jianquan Hong, Shuai Huang, Wei Zhang, Yupeng Yang, Ge Fang, Copper(I)-promoted trifluoromethylthiolation of arenediazonium salts with AgSCF3,Tetrahedron Lett., 2019, 60, 1404-1407.
5、Qiongzhen Lin, Yongan Liu, Zhiwei Xiao, Liping Zheng, Xiumiao Zhou, Yong Guo, Qingyun Chen,Changge Zheng,* Chao Liu, Intermolecular oxidative radical fluoroalkylfluorosulfonylation of unactivated alkenes with (fluoroalkyl)trimethylsilane, silver fluoride, sulfur dioxide andN-fluorobenzenesulfonimide,Org. Chem. Front., 2019, 6, 447–450.
6、Jianquan Hong, Xiaoxiao Zhang, Ruixue Long,Changge Zheng,* Syntheses, crystal structures, and properties of metal(ii) coordination polymers based on flexible ligand 1,3-bis(4-phenoxy)benzenedicarboxylic acid and bis(benzimidazole),Z. Anorg. Allg. Chem., 2018, 644, 518-524.
7、Changge Zheng,* Wenji Zhai, Jianquan Hong, Xiaoxiao Zhang, Zhenhua Zhu, Ling Wang, Synthesis of two 6-aza-uridines modified by benzoheterocycle as environmentally sensitive fluorescent nucleosides,Tetrahedron Lett., 2017, 58, 3008-3013.
8、Jianquan Hong, Lianguang Huo, Yazhao Wang, Ruixue Long,Changge Zheng,* Syntheses, crystal structures and properties of two coordination polymers derived from flexible dicarboxylate and N-donor ligands,Inorg. Chim. Acta, 2017, 455, 81-87.
9、Jianquan Hong, Guifu Wang, Lianguang Huo,Changge Zheng,* Copper-promoted conversion of aromatic amines into trifluoromethylated arenes: one-pot sandmeyer trifluoromethylation,Chin. J. Chem., 2017, 35, 1761-1767.
10、Jianquan Hong, Lianguang Huo, Yupeng Yang, Guifu Wang,Changge Zheng,* Copper-promoted one-pot trifluoromethylation of aromatic amines with Togni’s reagent,ChemistrySelect, 2017, 2, 3716-3720.
11、Changge Zheng,* Ruixue Long, Jianquan Hong, Yazhao Wang, Syntheses, crystal structures, and photoluminescence of Zinc(II) and Cobalt(II) coordination polymers based on semiflexible 1,4-bis(4-phenoxy)benzenedicarboxylate,Z. Anorg. Allg. Chem,.2016, 642, 377–382.
12、Jianquan Hong, Wenji Zhai, Likui Wang, Yazhao Wang,Changge Zheng,* Syntheses, structures, and luminescence of metal(II) coordination polymers based on flexible 1,1’-(1,4-butanediyl)bis(imidazole) and tetrachlorobenzene-1,4-dicarboxylate ligands,Z. Anorg. Allg. Chem,.2016, 642, 1486–1492.

1、一种三氟甲基芳基硫醚的制备方法，ZL202011221887.9，郑昌戈，蒋超，黄帅，洪建权，马明玉，富莹莹。
2、一种芳乙烯基三氟甲硫醚类化合物的合成方法，ZL201811390424.8，郑昌戈，刘洋，洪建权。
3、一种α-三氟甲硫基取代芳香酮类化合物的合成方法，ZL201811423112.2，郑昌戈，刘洋，洪建权。
4、一种联苯类缩水甘油醚的制备方法，ZL201410835376.4，郑昌戈，王贵富，严津津。
5、一种含4,4'-二溴-2,2'-联吡啶的新型钌配合物的制备方法及其抗肿瘤活性，ZL201410835341.0，郑昌戈，谢晨，李明月。
6、一种缩水甘油基单取代的双端氨基封端剂的制备方法，ZL201210578409.2，郑昌戈，李萍，苏多猛。
7、一种常温下空气氧化a-蒎烯制备马鞭烯醇和马鞭烯酮的方法，ZL201010539291.3，郑昌戈，刘煊业，喻晓蔚，徐岩。
8、高含量厚朴提取物分离纯化及人工合成工艺，ZL200810124091.4，郑昌戈，罗凤平，罗安东。

1、L-薄荷醇生物拆分用酶的分子改造与高效表达关键技术研究，科技部863项目，副组长。
2、硫氮杂的扩展核苷及其衍生物的合成、结构与荧光性质，国家自然科学基金项目，主持。
3、新型农用表面活性剂的研制与开发，企业横向项目，主持。
4、高含量厚朴提取物分离纯化及人工合成工艺研究，企业横向项目，主持。
5、新型柔顺剂的改良与应用，企业横向项目，主持。
6、新型防指纹涂料的开发与应用，企业横向项目，主持。

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