精细化工

过渡金属催化的羰基化反应及杂环合成

1. Hucheng Ma, Chen-Yang Hou, Ruyi Zhao, Xinxin Qi* and Xiao-Feng Wu*
Nickel-Catalyzed Cyclization/Carbonylation Reaction of N‑Allylbromoacetamides with Arylboronic Acids toward 2‑Pyrrolidinones
Org. Lett. 2025, 27, 1299−1303.
2. Chen-Yang Hou, Hucheng Ma, Ruyi Zhao, Xinxin Qi* and Xiao-Feng Wu*
Nickel-Catalyzed Cyclization/Thiocarbonylation of Alkene-Tethered indoles with sulfonyl Chlorides: Synthesis of Thioester-Substituted Indolo [2,1-a]isoquinolines
J. Catal. 2024, 439, 115765.
3. Dan Wen, Boyu Yao, Xinxin Qi* and Xiao-Feng Wu*
Facile synthesis of HFIP esters-containing 2H-benzopyrans through palladium-catalyzed one-pot cyclization/carbonylation using formic acid as the CO source
J. Catal. 2024, 436, 115602.
4. Ren-Guan Miao, Weiqi Dai, Xinxin Qi* and Xiao-Feng Wu*
Nickel-catalyzed desulfonative cross-coupling of benzylsulfonyl chlorides with arylsulfonyl chlorides for synthesis of asymmetric thioethers
Cell Rep. Phy. Sci. 2023, 4, 101219.
5. Zekai Shen, Yong-Wang Huo, Xinxin Qi* and Xiao-Feng Wu*
Palladium-Catalyzed Thiocarbonylative Synthesis of α,β-Unsaturated Thioesters Using S-Aryl Thioformates as the Thioester Source
Org. Lett. 2023, 25, 4140–4144.
6. Ren-Rui Xu, Xuanzhang Bao, Yong-Wang Huo, Ren-Guan Miao, Dan Wen, Weiqi Dai, Xinxin Qi* and Xiao-Feng Wu*
Palladium-Catalyzed Domino Carbopalladation/Carbonylative Cyclization: Synthesis of Heterocycles bearing Oxindoles and 3‑Acylbenzofuran/3-Acylindole Moieties
Org. Lett. 2022, 24, 6477–6482.
7. Yong-Wang Huo, Xinxin Qi* and Xiao-Feng Wu*
Nickel-Catalyzed Carbonylative Synthesis of α,β-Unsaturated Thioesters from Vinyl Triflates and Arylsulfonyl Chlorides
Org. Lett. 2022, 24, 4009–4013.
8. Jian-Li Liu, Wei Wang, Xinxin Qi* and Xiao-Feng Wu*
Palladium-Catalyzed Reductive Aminocarbonylation of o-Iodophenol-Derived Allyl Ethers with o-Nitrobenzaldehydes to 3- Alkenylquinolin-2(1H)-ones
Org. Lett. 2022, 24, 2248–2252.
9. Wei Wang, Zhi-Peng Bao, Xinxin Qi* and Xiao-Feng Wu*
Nickel-Catalyzed One-Pot Carbonylative Synthesis of 2-Mono- and 2,3-Disubstituted Thiochromenones from 2-Bromobenzenesulfonyl Chlorides and Alkynes
Org. Lett. 2021, 23, 6589–6593.
10. Zhi-Peng Bao, Ren-Guan Miao, Xinxin Qi* and Xiao-Feng Wu*
A novel construction of acetamides from rhodium-catalyzed aminocarbonylation of DMC with nitro compounds
Chem. Commun. 2021, 57, 1955–1958.
11. Wei Wang, Xinxin Qi* and Xiao-Feng Wu*
Palladium-Catalyzed Thiocarbonylation of Benzyl Chlorides with Sulfonyl Chlorides for the Synthesis of Arylacetyl Thioesters
Adv. Synth. Catal. 2021, 363, 2541–2545.
12. Yongzhu Liu, Xinxin Qi* and Xiao-Feng Wu*
Palladium-Catalyzed Reductive Aminocarbonylation of Benzylammonium Triflflates with o-Nitrobenzaldehydes for the Synthesis of 3- Arylquinolin-2(1H)-ones
J. Org. Chem. 2021, 86, 13824–13832.

1. 浙江省自然科学基金探索非Q项目：基于替代羰源的对甲苯磺酰腙的羰基化反应及杂环合成研究，LY21B020010，2021-01至2023-12，10万，主持
2. 国家自然科学基金青年科学基金：过渡金属催化的惰性sp3碳的羰基化转化合成杂环，21602201，2017-01至2019-12，20万，主持
3. 浙江省教育厅科研项目：钯催化的氯代化合物的羰基化反应的研究，Y201432060，2014-01至2017-10，1.5万，主持
4. 国家自然科学基金青年科学基金：烯丙基类化合物的可调控发散型羰基化反应研究，21801225，2019-01至2021-12，26万元，参与
5. 国家自然科学基金面上项目：绿色替代羰源的开发及其在羰基化反应中的应用研究，21772177，2018-01至2021-12，64万，参与
6. 国家自然科学基金青年科学基金：铜催化羰基化／三氟甲基化合成三氟甲基酮及其衍生物的研究，21602204，2017-01至2019-12，20万，参与