天然气化工,新材料,石油炼制,石油化工,精细化工

经典有机反应的拓展，金属-碳多重键化学及导向有机合成的金属有机化学

Metallacycles;Aromaticity;Osmium;Metallabenzenes;Metallabenzene;Stability;Cycloaddition;Ruthenium;Synthetic Methods;Photoluminescence

1. Zhao, J.; Cai, Y.; Yang, X.; Zhang, H.* Heavier Group 14 Congeners of Metalla-isobenzenes: Access to Metalla-isosilabenzene and Metalla-isogermabenzene by One-Pot Reactions. Chin. J. Chem. 2024, 42, 1121-1127.
2. Lin, Z.;† Cai, Y.;† Zhang, Y.; Zhang, H.;* Xia, H.* Heterocyclic Suzuki–Miyaura coupling reaction of metalla-aromatics and mechanistic analysis of site selectivity. Chem. Sci. 2023,14, 1227-1233.
3. Cai, Y.; † Hua, Y.; † Lu, Z.; Lan, Q.; Lin, Z.; Fei, J.; Chen, Z.; Zhang, H.;* Xia, H.* Electrophilic aromatic substitution reactions of compounds with Craig-Mobius aromaticity. Proc. Natl. Acad. Sci. U. S. A. 2021, 118, e2102310118.
4. Zhang, H.;* Thogersen, M. K.; Jamieson, C. S.; Xue, X.-S.; Jorgensen, K. A.;* Houk, K. N.* Ambimodal Transition States in Diels-Alder Cycloadditions of Tropolone and Tropolonate with N-Methylmaleimide. Angew. Chem. Int. Ed. 2021, 60, 24991–24996.
5. Zhang, H.;* Novak, A. J. E.; Jamieson, C. S.; Xue, X. S.; Chen, S.; Trauner, D.;* Houk, K. N.* Computational Exploration of the Mechanism of Critical Steps in the Biomimetic Synthesis of Preuisolactone A, and Discovery of New Ambimodal (5 + 2)/(4 + 2) Cycloadditions. J. Am. Chem. Soc. 2021, 143, 6601-6608.
6. Lu, Z.; † Zhu, Q.; † Cai, Y.; Chen, Z.; Zhuo, K.; Zhu, J.; Zhang, H.;* Xia, H.* Access to Tetracyclic Aromatics with Bridgehead Metals via Metalla-click Reactions. Sci. Adv. 2020, 6, eaay2535.
7. Huang, F.; Zheng, X.; Lin, X.; Ding, L.; Zhuo, Q.; Wen, T. B.; Zhang, H.;* Xia, H.* Extension of the Simmons–Smith Reaction to Metal-carbynes: Efficient Synthesis of Metallacyclopropenes with σ-Aromaticity. Chem. Sci. 2020, 11, 10159-10166.
8. Zhou, X.; Pang, X.; Nie, L.; Zhu, C.; Zhuo, K.; Zhuo, Q.; Chen, Z.; Liu, G.; Zhang, H.;* Lin, Z.; Xia, H. Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun. 2019, 10, 1488.
9. Zhou, X.; Zhang, H.* Reactions of Metal–Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. - Eur. J. 2018, 24, 8962-8973. (mini review)
10. Luo, M.; Long, L.; Zhang, H.;* Yang, Y.; Hua, Y.; Liu, G.; Lin, Z.;* Xia, H.* Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates. J. Am. Chem. Soc. 2017, 139, 1822-1825.

1. Chain multiyne compound, preparation method and application thereof
Xiamen University
Haiping Xia; Qingde Zhuo; Jianfeng Lin; Xiaoxi Zhou; Zhixin Chen; Yifan Shao; Hong Zhang; Xumin He
公开日期: 2019-05-14 申请日期: 2017-11-13 公开号: US10287225B2

2. 锇过氧配合物及其制备方法和应用
厦门大学
夏海平; 邓志鸿; 罗明; 张弘; 卓庆德; 何旭敏
公开日期: 2018-09-07 申请日期: 2017-10-18 公开号: CN108503672A

3. 锇过氧配合物及其制备方法和应用
厦门大学
夏海平; 邓志鸿; 罗明; 张弘; 卓庆德; 何旭敏
公开日期: 2018-09-07 申请日期: 2017-10-18 公开号: CN108503672A

4. CHAIN MULTIYNE COMPOUND, PREPARATION METHOD AND APPLICATION THEREOF
UNIV XIAMEN
LIN JIANFENG; ZHOU XIAOXI; SHAO YIFAN; ZHANG HONG; XIA HAIPING; ZHUO QINGDE; CHEN ZHIXIN; HE XUMIN
公开日期: 2018-03-08 申请日期: 2017-11-13 公开号: US2018065908A1

5. 链状多炔化合物及其制备方法和应用
UNIV XIAMEN
XIA HAIPING; ZHUO QINGDE; LIN JIANFENG; ZHOU XIAOQIAN; CHEN ZHIXIN; SHAO YIFAN; ZHANG HONG; HE XUMIN
公开日期: 2017-01-04 申请日期: 2015-05-13 公开号: CN106279100A

6. 一种金属桥位稠环化合物及其中间体和制备方法及应用
UNIV XIAMEN
XIA HAIPING; ZHUO QINGDE; LIN JIANFENG; ZHOU XIAOXI; CHEN ZHIXIN; SHAO YIFAN; ZHANG HONG; HE XUMIN
公开日期: 2016-11-17 申请日期: 2016-05-09 公开号: WO2016180297A1

1. 基于配位联烯的新型茂金属化合物的合成、性能及应用研究
立项时间: 2009-2011 项目经费：180000

2. 共轭型过渡金属杂环化合物的转化及应用基础研究
立项时间: 2013-2016 项目经费：800000

3. 五元环内高张力金属-碳多重键的构筑及其反应性研究
立项时间: 2016-2019 项目经费：650000

4. 含Os、Pt双金属杂环的合成及催化性能研究
立项时间: 2021-2022

5. 钌杂芳香环与不饱和小分子的反应探究
立项时间: 2022

6. CCC型pincer配合物在小分子活化和转化中的应用探索
立项时间: 2019-2022

7. VIII族双金属杂小环的设计、合成与应用研究
立项时间: 2021

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