精细化工

氢及其同位素的多相催化转化的实验与理论计算研究：选择性加氢、高效催化加氢/储氢&脱氢/产氢、仲氢诱导超极化、氢同位素标记、氢同位素分离

Hydrogenation;Catalysis;Heterogeneous Catalysis;Selective Hydrogenation;Catalysts;Supported Catalysts;Palladium;Nitroaromatics;Noble Metal Nanoclusters;Borrowing Hydrogen

1. Q Wu, Y Zhong, L Zhou, M Zhu, S Liu, R Qin*, N Zheng*. Oxygen Vacancy-Enriched Alumina Stabilized Pd Nanocatalysts for Selective Hydrogenation of Phenols. J. Am. Chem. Soc. 2024, 146, 47, 32263–32268.
2. Q Meng, L Liu, D Song, S Wang, R Qin*, G Fu*. Flexible Iron Clusters Promoting Ammonia Synthesis: A Density Functional Theory Prediction. J. Phys. Chem. Lett. 2024, 15, 42, 10623–10628.
3. M Qiao, Q Wu, Y Wang, S Gao, R Qin*, S Liu, K Ding, D Zhao, N Zheng*. Selective hydrogenation catalysis enabled by nanoscale galvanic reactions. Chem, 2024, 10 (11), 3385-3395.
4. Y Wang, X Wang, M Qiao, Q Wu, K Liu, X Yi, R Qin*, G Fu*, N Zheng*. Color center-rich γ-Al2O3 promotes propane dehydrogenation. Sci. China Chem. 2024. 67, 4134-4141.
5. P You, L Wu, L Zhou, Y Xu*, R Qin*. Impact of Oxygen-Containing Groups on Pd/C in the Catalytic Hydrogenation of Acetophenone and Phenylacetylene. Catalysts 2024, 14, 545.
6. M Qiao, Y Wang, S Gao, Q Fu, X Wang, R Qin*, N Zheng*. Ligand Modification-Induced Electronic Effects and Synergistic Protic Solvent Effects Promote C═O Bond Hydrogenation. ACS Catal. 2024, 14, 11468–11476.
7. Jing, W.; Mo, S.; Zhang, W.; Zhou, W.; Liu, K.; Wei, J.; Qin, R.*; Zheng, N.* Surface Ligand Evolution: Sulfur-Directed Covalent Bonding of PPh3 on Pd4S with Improved Semi-hydrogenation of Terminal Alkynes. Precis. Chem. 2024, 2, 200–207.
8. Wu, Q.||; Qin R||; Zhu, M.; Shen, H; Yu, S; Zhong, Y; Fu, G.; Yi, X.*; Zheng, N.* Frustrated Lewis pairs on penta-coordinated Al3+-enriched Al2O3 promote heterolytic hydrogen activation and hydrogenation. Chem. Sci. 2024, 15, 3140.
9. Qin, R.*; Chen, Z; Wu, Q; Zheng, N; Liu, P.* Supported atomically dispersed Pd catalyzed direct alkoxylation and allylic alkylation. Chin. J. Chem., 2024, 42, 719.
10. Zhang, W.; Qin, R.* Fu, G.; Zheng, N*. Hydrogen Bond Network Induced by Surface Ligands Shifts the Semi-hydrogenation Selectivity over Palladium Catalysts. J. Am. Chem. Soc. 2023. 145, 10178.
11. Mo, S.; Jing, W.; Zhang, W.; Liu, K.; Wu, B.; Qin, R.*; Zheng, N.* Self-reduction synthesis of supported ultrafine Pd nanoparticles for hydrogenation with high activity and stability. Sci. China Mater. 2023. 66, 2708.
12. Liu, K.||; Qin, R.||; Li, K.; Zhang, W.; Ruan, P.; Fu, G.*; Zheng, N.* Atomically dispersed palladium catalyzes H/D exchange and isomerization of alkenes via reversible insertion and elimination. Chem Catal. 2021, 1, 1480.
13. Zhang, W.||; Qin, R.||; Fu, G.*; Zheng, N.* Heterogenous Isomerization for Stereo-selective Alkyne Hydrogenation to trans-Alkene Mediated by Frustrated Hydrogen Atoms. J. Am. Chem. Soc. 2021, 143, 15882.
14. Li, K||; Qin, R.||; Liu, K.;|| Liu, N.; Zhang, Y.; Liu, S.; Chen, J.; Fu, G.*; Zheng, N.*; Carbon Deposition on Heterogeneous Pt Catalysts Promotes the Selective Hydrogenation of Halogenated Nitroaromatics. ACS Appl. Mater. Interfaces 2021, 13, 52193.
15. Liu, K.||; Qin, R.||; Zheng, N.*, Insights into the Interfacial Effects in Heterogeneous Metal Nanocatalysts toward Selective Hydrogenation. J. Am. Chem. Soc. 2021, 143, 83.
16. Qin, R.||; Zhou, L.||; Liu, P.; Gong, Y.; Liu, K.; Xu, C.; Zhao, Y.; Gu, L.; Fu, G.*; Zheng, N.* Alkali ions secure hydrides for catalytic hydrogenation. Nat. Catal. 2020, 3, 703.
17. Qin, R.; Deng, G.; Zheng, N.* Assembling Effects of Surface Ligands on Metal Nanomaterials. Prog. Chem. 2020, 32, 1140.
18. Qin, R.; Liu, K.; Wu, Q.; Zheng, N.* Surface Coordination Chemistry of Atomically Dispersed Metal Catalysts. Chem. Rev. 2020, 120, 11810.
19. Qin, R.||; Wang, P.||; Liu, P.; Mo, S.; Gong, Y.; Ren, L.; Xu, C.; Liu, K.; Gu, L.; Fu, G.* Zheng, N.* Carbon Monoxide Promotes the Catalytic Hydrogenation on Metal Cluster Catalysts. Research 2020, 4172794.
20. Qin, R.; Zheng, N.* Catalysis Selects Its Own Favorite Facets. Chem 2019, 5, 1935.
21. Liu, K.||; Qin, R.||; Zhou, L.; Liu, P.; Zhang, Q.; Jing, W.; Ruan, P.; Gu, L.; Fu, G.*; Zheng, N.* Cu2O-Supported Atomically Dispersed Pd Catalysts for Semihydrogenation of Terminal Alkynes: Critical Role of Oxide Supports. CCS Chem. 2019, 1, 207.
22. R Qin, P Liu, G Fu, N Zheng*, Strategies for Stabilizing Atomically Dispersed Metal Catalysts. Small Methods 2018, 2 (1), 1700286.
23. Mitchell, S.; Qin, R.; Zheng, N.; Pérez-Ramírez, J., Nanoscale Engineering of Catalytic Materials for Sustainable Technologies. Nat. Nanotechno. 2021, 16, 129.

1. 一种改性的金属纳米催化剂及其制备方法与应用
厦门大学
郑南峰; 尤鹏耀; 张亚周; 秦瑞轩; 陈洁; 刘圣杰
公开日期: 2025-05-02 申请日期: 2022-11-22 公开号: CN115837273B

2. 一种负载型铱基OER催化剂制备方法与应用
厦门大学
郑南峰; 黄可欣; 劳科杰; 秦瑞轩; 刘圣杰; 陈洁
公开日期: 2025-03-14 申请日期: 2024-12-20 公开号: CN119615269A

3. 一种多孔型钛基脱硝催化剂及其制备方法与应用
嘉庚创新实验室
徐永; 王慧; 姚建年; 秦瑞轩
公开日期: 2024-11-26 申请日期: 2024-08-20 公开号: CN119016041A

4. 复合载体、脱硝催化剂及其制备方法和应用
嘉庚创新实验室
姚建年; 秦瑞轩; 李锡哲; 徐永
公开日期: 2024-04-05 申请日期: 2024-01-17 公开号: CN117816144A

5. Using atomic-level dispersed ruthenium catalyst in catalytic hydrogenation, involves introducing hydrogen gas and a gaseous reaction substrate to perform a hydrogenation reaction in the presence of the catalyst.
秦瑞轩; 郑南峰; 陈洁; 刘圣杰
公开日期: 2021-08-13 申请日期: 2020-03-06 公开号: CN111269086B

6. 一种N-乙基咔唑的合成方法
厦门大学
郑南峰; 秦瑞轩; 郑卫东; 刘圣杰
公开日期: 2017-12-19 申请日期: 2017-10-10 公开号: CN107488140B

7. 一种N‑乙基咔唑的合成方法
厦门大学
郑南峰; 郑卫东; 秦瑞轩; 刘圣杰
公开日期: 2017-12-19 申请日期: 2017-10-10 公开号: CN107488140A

8. 一种超薄B相二氧化钛纳米片的制备方法
厦门大学
郑南峰; 刘朋昕; 秦瑞轩; 莫世广; 臧丹丹
公开日期: 2016-08-03 申请日期: 2016-03-18 公开号: CN105819502A

9. 一种大负载量的原子分散钯催化剂的制备方法
厦门大学
郑南峰; 刘朋昕; 莫世广; 秦瑞轩
公开日期: 2016-07-27 申请日期: 2016-03-18 公开号: CN105797718A

10. 农药插层水化氯铝酸钙合成缓释剂的方法
厦门大学; 江苏隆昌化工有限公司
郑南峰; 秦瑞轩; 臧丹丹; 佘道才; 赵雪松; 佘卫民
公开日期: 2014-09-10 申请日期: 2014-06-18 公开号: CN104026125A

11. 一种利用含镍废水插层生产镍铝类水滑石的方法
厦门大学; 江苏隆昌化工有限公司
郑南峰; 臧丹丹; 秦瑞轩; 佘卫民; 赵雪松; 佘道才
公开日期: 2014-09-10 申请日期: 2014-06-18 公开号: CN104030369A

福建省自然科学基金-优青项目，氢及其同位素的多相催化精准转化，2024-05 至 2027-04，20万，主持；
国家自然科学基金委员会, 青年科学基金项目, 多相催化加氢促进仲氢诱导超极化, 2023-01-01 至 2025-12-31, 30万元, 主持；
福建省自然科学基金青创项目，多相催化有机液体储氢研究，2023-08 至 2026-07，8万元，主持；
中国博士后科学基金, 特别资助&面上资助, 表界面活性氢物种与单氢加成诱导烯烃异构化反应研究, 2021-06 至 2022-06, 26万元, 主持；
国家自然科学基金委员会，卓越研究群体（原基础科学中心项目），单原子催化，2024-01 至 2027-12，100万元（项目总经费6000万元），参与；
国家重点研发计划，“催化科学”重点专项，甲烷C-H的低温高效催化活化和定向转化，2022-01 至 2026-12，80万元（项目总经费2500万元），参与。

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