精细化工

(1)CO、CO2催化加氢高值转化关键基础及技术研究；
(2)工业有机高盐废水深度处理技术研究；
(3)工业催化剂动态构效关系研究；
(4)催化反应机理及动力学研究。

Co2 Hydrogenation;Olefins;Methanol;Oxygen Chemical Potential;Iron-based Catalysts;Mechanism;Kinetics;Syngas;Heavy Olefins;Graphite Carbon

(1)Wenqi Liu,Shanshan Dang, Sifan Cheng, Zhenzhou Zhang, Xiaoya Ding, Yanling Shi, Pengchao Ren, Weifeng Tu*, and Yi-Fan Han*.Revealing the Interaction between Cu and MgO in Cu/MgO Catalysts for CO Hydrogenation to CH3OH. ACS Catalysis. 2024, 14, 9, 7097–7110

(2)Yanjia Guo, Lingyu Jia, Zhenzhou Zhang, Mengze Gong, Shanshan Dang, Yanqiang Huang, Xinhua Gao, Weifeng Tu*, Yi-Fan Han*.Revealing the mechanism of Ce promoter in modulating product distribution of CO2hydrogenation over Fe-based catalysts. Chemical Engineering Journal, 2024, 491, 151964.

(3)Weifeng Tu; Pengchao Ren; Yuanjie Li; Yongpeng Yang; Yun Tian; ZhenzhouZhang; Minghui Zhu; Ya-Huei Cathy Chin; Jinlong Gong*; Yi-Fan Han*; Gas-Dependent Active Sites on Cu/ZnO Clusters for CH3OH Synthesis, Journal of the American Chemical Society, 2023 145(16), 8751-8756.

(4)Zhenzhou Zhang; Baojian Chen; Lingyu Jia; Wenqi Liu; Xinhua Gao; Jian Gao; Bo Meng; Yisheng Tan; Yurong He*; Weifeng Tu*; Yi-Fan Han*; Unraveling the role of Fe5C2in CH4formation during CO2hydrogenation over hydrophobic iron catalysts, Applied Catalysis B: Environmental, 2023, 327(1): 122449.

(5)Zhenzhou Zhang, Sifan Cheng, Wenqi Liu, Baojian Chen, Xinhua Gao, Peng Wang, Jian Gao, Yisheng Tan, Shanshan Dang, Weifeng Tu*.Unraveling the regulation of Mn in Cu-ZnOxformation during methanol synthesis from syngas over Cu/ZnO/Al2O3-Mn catalysts. Applied Catalysis B: Environmental, 2023, 338(1): 122985.

(6)Haripal Singh Malhi; Zhenzhou Zhang; Shi Yanling; Xinhua Gao; Wenqi Liu; Weifeng Tu*; Yi-Fan Han*; The Promotional Effects of Carbon Nanotube onFe5C2-ZnO Catalysts for CO2Hydrogenation to Heavy Olefins, Fuel, 2023, 339(1): 127267.

(7)Haripal Singh Malhi#, Chao Sun#, Zhenzhou Zhang, Yangyang liu, Wenqi Liu, Pengchao Ren, Weifeng Tu*, Yi-Fan Han*,Catalytic consequences of the decoration of sodium and zinc atoms during CO2hydrogenation to olefins over Iron-based Catalyst. Catalysis Today, 2022, 387, 28-37.

(8)Pengchao Ren1, Weifeng Tu1, Chanchan Wang, Sifan Cheng, Wenqi Liu, Zhenzhou Zhang, Yun Tian, Yi-Fan Han*, Mechanism and sites requirement for CO hydrogenation to CH3OH over Cu/CeO2catalysts. Applied Catalysis B: Environmental, 2022, 305, 121016.

(9)Zhenzhou Zhang*, Yangyang Liu, Lingyu Jia*, Chao Sun, Baojian Chen, Rui Liu, Yisheng Tan, Weifeng Tu*, Effects of the reducing gas atmosphere on performance of FeCeNa catalyst for the hydrogenation of CO2to olefins.Chemical Engineering Journal, 2022, 428, 131388.

(10)Yangyang Liu; Baojian Chen; Rui Liu; Wenqi Liu; Xinhua Gao; Yisheng Tan; Zhenzhou Zhang; Weifeng Tu*; CO2hydrogenation to olefins on supported iron catalysts: Effects of support properties on carbon-containing species and product distribution, Fuel, 2022, 324(1): 124649

(11)Wenqi Liu, Sifan Cheng, Haripal Singh Malhi, Xinhua Gao, Zhenzhou Zhang* and Weifeng Tu*. Hydrogenation of CO2to Olefifins over Iron-Based Catalysts: A Review. Catalysts 2022, 12 (11), 1432.

(12)Weifeng Tu, Chao Sun, Zhenzhou Zhang, Wenqi Liu, Haripal Singh Malhi, Wei Ma, Minghui Zhu, Yi-Fan Han*, Chemical and structural properties of Na decorated Fe5C2-ZnO catalysts during hydrogenation of CO2to linearα-olefins.Applied Catalysis B: Environmental, 2021, 298, 120567.

(1)涂维峰;时彦玲;韩一帆,一种吸附测试方法和装置,中国授权发明专利，ZL 201711103129.5
(2)涂维峰;时彦玲;韩一帆;王仁铨;窦竞;陈高翔,固定床反应器,中国授权发明专利，ZL201810765655.6

1.国家自然科学基金,面上项目，CO₂甲烷化环境诱导Ni基催化剂动态活性结构与反应机理研究，22278379，2023.01-2026.12，54万元，主持;
2.河南省科技研发计划联合基金,优势学科联合基金重点项目，低温甲烷化镍基催化剂结构调控及催化反应机理研究，222301420010，2023.01-2025.12，80万元，主持
3.河南省自然科学基金,优秀青年科学基金项目，COx催化加氢制直链α烯烃反应过程原位动态解析与调控，232300421090，2023.01-2025.12，25万元，主持;
4.国家自然科学基金委员会,面上项目，22078307，铁基催化剂二氧化碳加氢制烯烃反应机制及反应动力学研究，2021.01-2024.12，64万元，主持
5.郑州大学青年教师基础研究培育项目，JC202019017，铁基催化剂二氧化碳加氢的反应机制及反应动力学研究，2020.08-2021.12，20万元，主持
6.郑州大学青年骨干教师培养项目，2018ZDGGJS039，煤基合成气制低碳醇机理及催化剂研究，2019.01-2021.12，主持
7.国家自然科学基金委员会,青年科学基金项目, 21606208,贵金属催化剂催化氢氧直接合成过氧化氢的反应本征动力学及机理研究, 2017-01至2019-12, 20万元,主持
8.郑州大学优秀教师发展基金，F0000987，合成气制低碳醇的催化反应动力学及机理研究，2017.01-2019.12，30万元，主持
9.低品位能源利用技术及系统教育部重点实验室开放基金，LLEUTS-201707，微细通道内钯基催化剂上甲醇催化燃烧反应动力学及机理研究，2017.01-2018.12，主持

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