石油化工,精细化工,天然气化工

催化反应工程；工业催化；有机催化；磷化工

1) 针对石油化工和能源化工中小分子烃类转化的复杂反应体系，开发了MFI、MWW分子筛系列催化剂，研究催化剂酸性、双功能位协同效应与齐聚和芳构化产物构效关系。研究拓展了single-event微动力学方法建立本征动力学模型。从反应动力学角度关注从小分子烃类催化转化，脱氢、齐聚、芳构化的催化剂构效关系研究，将为从页岩气、煤、天然气化工和生物质转化过程生成C2-C3小分子烃类的过程与传统石油化工过程进行交叉融通架构理论桥梁；
2) 开发磷化工副产氟硅酸的综合利用合成分子筛材料及应用，减少环境危害，拓展磷化工产业链，融合磷化工、精细化工和石油化工行业；
3) 合成了新型分子筛烯烃环氧化，特别是大分子环烯烃的环氧化反应催化剂，合成精细化工和医药化工中间体。

1) Chaoyin.Wang#,Kang Lu#, Fang Jin*, et al.,. Modification of MWW layerstructure to investigate the effect of acidity and Zn-type sites on ethanedehydroaromatization. Catalysis Today, 2021, 368, 250-259.
2) Fang Jin*, PengZhang, et al., Fundamental kinetics model of acidity-activity relation for ethyleneoligomerization and aromatization over ZSM-5 zeolites, Chemical EngineeringScience, 2021, 229: 116144-116159.
3) Fang Jin*,#, Yuanzhi Yan#, et al., Ethyleneoligomerization over H- and Ni-form aluminosilicate composite with ZSM-5 andMCM-41 structure: Effect of acidity strength, nickel site and porosity, CatalysisToday, 2020, 355: 148-161.
4) Kang Lu#,Fang Jin*,#, et al., The synergetic effect of acid and nickelsites on bifunctional MWW zeolite catalysts for ethylene oligomerization andaromatization, Sustainable Energy & Fuels, Sustainable Energy & Fuels,2019, 3: 3569-3581.
5) MenghuiYan#, Fang Jin*,#, et al., Synthesis of titanium-incorporatedMWW zeolite by sequential deboronation and atom-planting treatment of ERB-1 asan epoxidation catalyst, Industrial & Engineering Chemistry Research, 2019,58: 4764-4773.
6) Fang Jin, Yang Chun Fan, et al, Single-eventkinetic modeling of ethene oligomerization on ZSM-5,CatalysisToday, 2018, 316: 129-141.
7) Fang Jin*, YangChun Fan, et al., Modified Brønsted Type Equation withAmmonia as Probe Molecule: Quantitative acidity-activity relationship for pyridinesynthesis with ZSM-5 catalyst, Reaction Kinetics, Mechanisms and Catalysis, 2018, 123:517-527.
8) Tie Liang Liu, FangJin*, et al., Synthesis of titanium containing MCM-41from industrial hexafluorosilicic acid as epoxidation catalyst, Catalysis Today, 2017, 297: 316-323
9) Fang Jin, Xianqiao Wang, et al., Synthesis ofZSM-5 with the silica source from industrial hexafluorosilicic acid astransalkylation catalyst, Chinese Journal of Chemical Engineering, 2017, 25: 1303-1313
10) Fang Jin, Y.X. Wu, et al., Effect of Ti incorporatedMWW supports on Au loading and catalytic performance for direct propylene epoxidation,Catalysis Today, 2016, 264: 98-108
11) C.C. Chang, Fang Jin,et al., Effect of the grafting agent on the structure and catalytic performanceof Ti-MCM-22, Catalysis Science & Technology, 2016, 6: 7631-7642
12) Fang Jin, C.C. Chang, et al., New mesoporous titanosilicateMCM-36 material synthesized from pillaring layered ERB-1 precursor, Journalof Materials Chemistry A, 2015, 3: 8715-8724
13) Fang Jin, S.J. Huang, et al., The influences of Al speciesand Ti species on the catalytic epoxidation over Si/Ti-pillared MCM-36synthesized from MCM-22, Catalysis Science & Technology, 2015, 5: 3007-3016
14) Fang Jin, T.H. Lin, et al., Gold supported on Ti incorporatedMCM-36 as efficient catalysts in propylene epoxidation with H2 and O2,RSC Advances, 2015, 5: 61710-61718
15) Fang Jin, C.C. Chang, et al., New Ti-incorporatedMCM-36 as an efficient epoxidation catalyst prepared by pillaring MCM-22 layerswith titanosilicate, Journal of Catalysis, 2014, 319: 247-257

1) 金放, 层状含介孔钛硅分子筛催化剂及其制备方法和应用, CN2014106743385
2) 金放，等, 利用氟硅酸合成介孔分子筛并副产冰晶石的方法, CN2015106004778
3) 金放，等, 一种利用氟硅酸合成MWW结构分子筛的方法和应用,CN2016107836723

甲醇合成汽油工艺中烯烃催化聚合过程的单元步骤(single event)微动力学理论研究，国家自然科学基金青年科学基金；
低碳烃芳构化过程复杂反应体系的有限元微动力学理论研究，留学回国人员科研启动基金；
磷肥工业副产氟硅酸合成分子筛催化剂新材料，湖北省教育厅自然科学研究重点项目；
乙烷氧化脱氢催化剂的开发和构效关系研究,国家能源石油炼制技术研发中心开放课题。

技术咨询