精细化工

电催化 [C–N2] 偶联、氮气高效活化方法、对称电催化

Nitrile;Alcohol;6-tetramethylpiperidinyl-1-oxy(tempo);Electrooxidation;Hexamethyldisilazane (hmds);Humanities And Social Sciences;Science;Multidisciplinary

1. Chen Chen; Xiaorong Zhu; Xiaojian Wen; Yangyang Zhou; Ling Zhou; Hao Li; Li Tao; Qiling Li; Shiqian Du; Tingting Liu; Dafeng Yan; Chao Xie; Yuqin Zou; Yanyong Wang; Ru Chen; Jia Huo; Yafei Li; Jun Cheng; Hui Su; Xu Zhao; Weiren Cheng; Qinghua Liu; Hongzhen Lin; Jun Luo; Jun Chen; Mingdong Dong; Kai Cheng; Conggang Li; Shuangyin Wang*; Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions, Nature Chemistry, 2020, 12(8): 717-724.
2. Yujie Wang; Dawei Chen; Chen Chen*; Shuangyin Wang*; Electrocatalytic urea synthesis via C-N coupling from CO2 and nitrogenous species, Accounts of Chemical Research, 2024, 57(2): 247-256.
3. Xiaoxiao Wei; Xiaojian Wen; Yingying Liu; Chen Chen*; Chao Xie; Dongdong Wang; Mengyi Qiu; Nihan He; Peng Zhou; Wei Chen; Jun Cheng*; Hongzhen Lin*; Jianfeng Jia; Xian-Zhu Fu*; Shuangyin Wang*; Oxygen vacancy-mediated selective C-N coupling toward electrocatalytic urea synthesis, J. Am. Chem. Soc. 2022, 144(26): 11530-11535.
4. Dongdong Wang; Zhi-Wen Chen; Kaizhi Gu; Chen Chen*; Yingying Liu; Xiaoxiao Wei; Chandra Veer Singh*; Shuangyin Wang*; Hexagonal cobalt nanosheet for high-performance electrocatalytic NO reduction to NH3, J. Am. Chem. Soc. 2023, 145(12): 6899-6904.
5. Kefan Zhang; Yuyan Liu; Xupeng Qin; Peilian Hou; Chu Zhang; Dafeng Yan; Chade Lv; Dawei Chen; Yong Feng; Ze Wu; Yujie Wang; Shuxuan Liu; Yingjie Li; Yongpan Hu; Kun Feng; Jun Zhong; Qinghua Liu; Chen Chen*; Shuangyin Wang; Designing molecular reactor of interlayer dual-atom toward urea electrosynthesis, Angew. Chem. Int. Ed. 2025, 64: e202513341.
6. Yujie Wang; Xiaorong Zhu; Qizheng An; Xiaoran Zhang; Xiaoxiao Wei; Chen Chen*; Han Li; Dawei Chen*; Yangyang Zhou; Qinghua Liu; Huaiyu Shao; Shuangyin Wang*; Electron deficiency is more important than conductivity in C-N coupling for electrocatalytic urea synthesis, Angew. Chem. Int. Ed. 2024, 63: e202410938.
7. Xiaoran Zhang; Xiaorong Zhu; Shuowen Bo; Chen Chen*; Kai Cheng; Jianyun Zheng; Shuang Li; Xiaojin Tu; Wei Chen; Chao Xie; Xiaoxiao Wei; Dongdong Wang; Yingying Liu; Pinsong Chen; San Ping Jiang*; Yafei Li; Qinghua Liu; Conggang Li; Shuangyin Wang*; Electrocatalytic urea synthesis with 63.5% Faradaic efficiency and 100% N-selectivity via one-step C-N coupling, Angew. Chem. Int. Ed. 2023, 62(33): e202305447.
8. Xiaojin Tu; Xiaorong Zhu; Shuowen Bo; Xiaoran Zhang; Ruping Miao; Guobin Wen; Chen Chen*; Jing Li; Yangyang Zhou; Qinghua Liu; Dawei Chen; Huaiyu Shao; Dafeng Yan; Yafei Li; Jianfeng Jia; Shuangyin Wang; A universal approach for sustainable urea synthesis via intermediate assembly at the electrode/electrolyte interface, Angew. Chem. Int. Ed. 2024, 63(3): e202317087.
9. Yingying Liu; Xiaojin Tu; Xiaoxiao Wei; Dongdong Wang; Xiaoran Zhang; Wei Chen; Chen Chen*; Shuangyin Wang; C-bound or O-bound surface: Which one boosts electrocatalytic urea synthesis, Angew. Chem. Int. Ed. 2023, 62(19): e202300387.
10. Wei Chen; Leitao Xu; Xiaorong Zhu; Yu-Cheng Huang; Wang Zhou; Dongdong Wang; Yangyang Zhou; Shiqian Du; Qiling Li; Chao Xie; Li Tao; Chung-Li Dong; Jilei Liu; Yanyong Wang; Ru Chen; Hui Su; Chen Chen*; Yuqin Zou*; Yafei Li; Qinghua Liu; Shuangyin Wang*; Unveiling the electrooxidation of urea: the intramolecular coupling of N‐N bond, Angew. Chem. Int. Ed. 2021, 60(13): 7297-7307.
11. Dongdong Wang; Nihan He; Lei Xiao; Fan Dong; Wei Chen; Yangyang Zhou; Chen Chen*; Shuangyin Wang*; Coupling electrocatalytic nitric oxide oxidation over carbon cloth with hydrogen evolution reaction for nitrate synthesis, Angew. Chem. Int. Ed.  2021, 60(46): 24605-24611.
12. Xiaoran Zhang; Xiaorong Zhu; Shuowen Bo; Chen Chen*; Qingfeng Zhai; Shuang Li; Xiaojin Tu; Jianyun Zheng; Dongdong Wang; Xiaoxiao Wei; Wei Chen; Tehua Wang; Yafei Li; Qinghua Liu; San Ping Jiang; Liming Dai*; Shuangyin Wang*; Selective nitrogen fixation via Janus C-N coupling in co-electrolysis, Chem, 2024, 10(5):1516-1527.
13. Han Li; Leitao Xu; Shuowen Bo; Yujie Wang; Han Xu; Chen Chen*; Ruping Miao; Dawei Chen*; Kefan Zhang; Qinghua Liu; Jingjun Shen; Huaiyu Shao; Jianfeng Jia; Shuangyin Wang*; Ligand engineering towards electrocatalytic urea synthesis on a molecular catalyst, Nature Communications, 2024, 15: 8858.
14. Xiaoran Zhang; Xiaorong Zhu; Shuowen Bo; Chen Chen*; Mengyi Qiu; Xiaoxiao Wei; Nihan He; Chao Xie; Wei Chen; Jianyun Zheng*; Pinsong Chen; San Ping Jiang*; Yafei Li; Qinghua Liu; Shuangyin Wang*; Identifying and tailoring C-N coupling site for efficient urea synthesis over diatomic Fe-Ni catalyst, Nature Communications, 2022, 13(1): 5337.
15. Dongdong Wang; Xiaorong Zhu; Xiaojin Tu; Xiaoran Zhang; Chen Chen*; Xiaoxiao Wei; Yafei Li; Shuangyin Wang*; Oxygen-bridged copper-iron atomic pair as dual-active sites for boosting electrocatalytic NO reduction, Adv. Mater. 2023, 35(39): 2304646.
16. Mengyi Qiu; Xiaorong Zhu; Shuowen Bo; Kai Cheng; Nihan He; Kaizhi Gu; Dezhong Song; Chen Chen*; Xiaoxiao Wei; Dongdong Wang; Yingying Liu; Shuang Li; Xiaojin Tu; Yafei Li; Qinghua Liu; Conggang Li; Shuangyin Wang*; Boosting electrocatalytic urea production via promoting asymmetric C-N coupling, CCS Chem. 2023, 5(11): 2617-2627.
17. Chen Chen*; Shuang Li; Xiaorong Zhu; Shuowen Bo; Kai Cheng; Nihan He; Mengyi Qiu; Chao Xie; Dezhong Song; Youzhen Liu; Wei Chen; Yafei Li; Qinghua Liu; Conggang Li; Shuangyin Wang; Balancing sub-reaction activity to boost electrocatalytic urea synthesis using a metal-free electrocatalyst, Carbon Energy, 2023, 5(10): e345.
18. Dongdong Wang; Chen Chen*; Shuangyin Wang*. Defect engineering for advanced electrocatalytic conversion of nitrogen-containing molecules. Sci. China Chem. 2023, 10.1007/s11426-022-1419-y.
19. Chen Chen; Li Tao; Shiqian Du; Wei Chen; Yanyong Wang; Yuqin Zou; Shuangyin Wang*; Advanced exfoliation strategies for layered double hydroxides and applications in energy conversion and storage, Adv. Funct. Mater. 2020, 30(14): 1909832.
20. Chen Chen; Dafeng Yan; Yu Wang; Yangyang Zhou; Yuqin Zou*; Yafei Li*; Shuangyin Wang*; B-N pairs enriched defective carbon nanosheets for ammonia synthesis with high efficiency, Small, 2019, 15(7): 1805029.
21. Chen Chen*; Nihan He; Shuangyin Wang*; Electrocatalytic C-N coupling for urea synthesis, Small Sci. 2021, 1(11): 2100070.
22. Dawei Chen; Jiani Liu; Jingjun Shen; Yiqiong Zhang*; Huaiyu Shao*; Chen Chen*; Shuangyin Wang*; Electrocatalytic C-N couplings at cathode and anode; Adv. Energy Mater. 2024, 14(28): 2303820.

1. 一种基于适配树脂定制型AFM探针的纤维复合材料界面微观粘附力原位定量表征方法
北京化工大学
贾晓龙; 李宇辰; 黎何丰; 朱家宝; 董敬轩; 陈孝鹏; 李天明; 丁文辉; 陈晨; 吴浩明; 祖磊; 葛磊; 杨小平
公开日期: 2024-06-14 申请日期: 2024-03-18 公开号: CN118190790A

2. 基于管状和层状纳米材料混合的可饱和吸收体及其激光器
南京信息工程大学
刘雪明; 张天国; 吴乾超; 朱威; 陈晨
公开日期: 2024-02-23 申请日期: 2023-02-20 公开号: CN116191191B

3. 催化剂及其制备方法和应用
清华大学
屠仁勇; 黄爱鉴; 陈晨
公开日期: 2023-12-01 申请日期: 2023-07-31 公开号: CN117144404A

4. 一种基于毛细模型的大丝束碳纤维浸润性评估方法
北京化工大学
贾晓龙; 宋宇霄; 葛磊; 黎何丰; 朱家宝; 董敬轩; 陈晨; 吴浩明; 祖磊; 杨小平
公开日期: 2023-09-01 申请日期: 2023-06-05 公开号: CN116678790A

5. 一种二氧化碳循环固氮的合成氨的方法
佛山仙湖实验室
蒋三平; 郑建云; 王双印; 张潇然; 陈晨
公开日期: 2023-06-13 申请日期: 2023-01-04 公开号: CN116254548A

6. 金属复合化合物基贵金属单原子催化剂材料及其制备方法
清华大学
孟格; 陈晨; 陈建刚; 王定胜; 连超; 孙甲强; 李亚栋; 彭卿; 李杨
公开日期: 2021-12-07 申请日期: 2020-06-03 公开号: CN113751020A

7. Method for heating working fluid for power block to temperature greater than specified value, involves preheating thermochemical energy storage (TCES) fluid in dissociated state flowing from reservoir to synthesis reactor.
LAVINE ADRIENNE GAIL; ARYAFAR HAMARZ; WARRIER GOPINATH; JORDAN JOSHUA; KAVEHPOUR HOSSEIN PIROUZ; CHEN CHEN; LOVEGROVE KEITH P; WIRZ RICHARD EDWARD; BRAN-ANLEU GABRIELA ALEJANDRA; SIMONETTI DANTE ADAM; KENNEDY JONATHON
公开日期: 2021-06-24 申请日期: 2016-06-27 公开号: AU2016281723B2

8. 一种用于锂离子电池的凝胶型离子液体电解质及其制备方法和用途
北京化工大学
于乐; 李念武; 关俊; 陈晨
公开日期: 2020-09-11 申请日期: 2020-06-09 公开号: CN111653822A

9. Nanoframes with three-dimensional electrocatalytic surfaces
THE REGENTS OF THE UNIVERSITY OF CALIFORNIA; UCHICAGO ARGONNE LLC
Peidong Yang; Vojislav Stamenkovic; Gabor A. Somorjai; Nenad Markovic; Chen Chen; Yijin Kang; Nigel H. Becknell
公开日期: 2020-06-16 申请日期: 2015-02-18 公开号: US10686195B2

10. 一种金属单原子位点催化剂的制备方法
清华大学
彭卿; 李启恒; 李治; 陈文星; 王定胜; 陈远均; 李亚栋; 陈晨
公开日期: 2020-04-17 申请日期: 2017-10-23 公开号: CN107626294B

11. HIGH TEMPERATURE SYNTHESIS FOR POWER PRODUCTION AND STORAGE
UNIV CALIFORNIA
LAVINE ADRIENNE GAIL; WIRZ RICHARD EDWARD; KAVEHPOUR HOSSEIN PIROUZ; ARYAFAR HAMARZ; BRAN-ANLEU GABRIELA ALEJANDRA; CHEN CHEN; WARRIER GOPINATH; SIMONETTI DANTE ADAM; LOVEGROVE KEITH; JORDAN JOSHUA; KENNEDY JONATHON
公开日期: 2018-06-28 申请日期: 2016-06-27 公开号: US2018180325A1

12. 用于直接甲酸燃料电池的铱单原子催化剂及其制备方法
清华大学
李亚栋; 陈远均; 李治; 冀淑方; 王定胜; 彭卿; 陈晨
公开日期: 2018-03-13 申请日期: 2017-10-23 公开号: CN107799779A

13. 用于直接甲酸燃料电池的铱单原子催化剂及其制备方法
清华大学
李亚栋; 陈远均; 李治; 冀淑方; 王定胜; 彭卿; 陈晨
公开日期: 2018-03-13 申请日期: 2017-10-23 公开号: CN107799779A

14. 一种烃类催化选择氧化制备有机含氧化合物的方法
中国科学院大连化学物理研究所
陈晨; 徐杰; 石松; 刘梦; 苗虹
公开日期: 2018-02-13 申请日期: 2014-12-05 公开号: CN105712837B

15. 一种金属单原子位点催化剂的制备方法
清华大学
彭卿; 李启恒; 李治; 陈文星; 王定胜; 陈远均; 李亚栋; 陈晨
公开日期: 2018-01-26 申请日期: 2017-10-23 公开号: CN107626294A

16. High temperature synthesis for power production and storage
UNIV CALIFORNIA
LAVINE ADRIENNE GAIL; WIRZ RICHARD EDWARD; KAVEHPOUR HOSSEIN PIROUZ; ARYAFAR HAMARZ; BRAN-ANLEU GABRIELA ALEJANDRA; CHEN CHEN; WARRIER GOPINATH; SIMONETTI DANTE ADAM; LOVEGROVE KEITH P; JORDAN JOSHUA; KENNEDY JONATHON
公开日期: 2018-01-25 申请日期: 2016-06-27 公开号: AU2016281723A1

17. 一种氮掺杂石墨烯负载金属单原子催化剂的制备方法
清华大学
李亚栋; 朱有启; 李治; 彭卿; 王定胜; 陈晨
公开日期: 2017-12-15 申请日期: 2017-09-29 公开号: CN107469855A

18. HIGH TEMPERATURE SYNTHESIS FOR POWER PRODUCTION AND STORAGE
UNIV CALIFORNIA
LAVINE ADRIENNE GAIL; WIRZ RICHARD EDWARD; KAVEHPOUR HOSSEIN PIROUZ; ARYAFAR HAMARZ; BRAN-ANLEU GABRIELA ALEJANDRA; CHEN CHEN; WARRIER GOPINATH; SIMONETTI DANTE ADAM; LOVEGROVE KEITH P; JORDAN JOSHUA; KENNEDY JONATHON
公开日期: 2016-12-29 申请日期: 2016-06-27 公开号: WO2016210433A1

19. 一种合成纳米三效催化剂的方法
清华大学
李亚栋; 张享波; 刘向文; 陈晨; 王定胜
公开日期: 2016-07-06 申请日期: 2016-01-27 公开号: CN105727943A

20. 一种还原稀硝酸到亚硝酸的方法
中国科学院大连化学物理研究所
马继平; 徐杰; 贾秀全; 陈晨; 李德财; 王敏; 石松
公开日期: 2015-08-26 申请日期: 2014-02-21 公开号: CN104860276A

国家自然科学基金委员会，青年科学基金项目，22102054，缺陷氧化物负载有序合金纳米颗粒用于氮气与二氧化碳电催化偶联制备尿素，2022-01 至 2024-12，30.0 万元，结题，主持；
中国博士后科学基金会，博士后基金项目，BX20200116，2020年度博士后创新人才支持计划，2020-06 至 2022-03，63.0 万元，结题，主持；
中国博士后科学基金会，博士后基金项目，2020M682540，中国博士后科学基金第68批面上资助二等，2020-06 至 2022-03，8.0 万元，结题，主持；
湖南大学科研启动经费，2022年 至 2027年，50.0 万元，在研，主持。

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