研究成果:
在国际期刊上发表高水平研究论文41篇, 引用次数超1800次;
获得国家发明专利授权9项。
一、研究论文:
[41] Bi, H.; Chen, Z.; Bi, C.; Qu, S.*; Liu, J.*, Electroreductive amination of carboxylic acids by cobalt catalysis. Nature Communications. 2025, 16, 7167. DOI: https://doi.org/10.1038/s41467-025-62396-4
[40] He, F.; Wang, Y.; Huang, X.; Qu, S.*; Liu, J.*, Electrochemical C–O bond cleavage of diaryl ethers: upcycling of lignin 4-O-5 models and polyphenylene oxide. Green Chemistry. 2025, 27, 9178. DOI: https://doi.org/10.1039/D5GC02174J
[39] Li, W.; Wei, H.; Wang, B.; He, X.; Jiang, Y.; Nie, M.; Yan, H.; Hu, Z.; Gao, Q.*; Qu, S.*; Wang, X.*, Selective Hydrodisulfuration of Alkenes with Dithiosulfonate. Angew. Chem. Int. Ed. 2025, 64, e202424209. DOI: https://doi.org/10.1002/anie.202424209
[38] Zhou, J.; Chen, Z.; Nie, M.; Li, W.; Tong, W.-Y.; Wei, H.; Yan, H.; Gao, Q.*; Qu, S.*; Wang, X.*, Nickel-catalyzed enantioselective reductive iminodisulfuration of alkene-tethered oxime esters with dithiosulfonate. Chem. Commun. 2025, 61, 7329-7332. DOI: https://doi.org/10.1039/D5CC01654A
[37] Chen, W.; Qu, Z.; Qu, S.; Duan, A.*, Chiral phosphoric acid catalyzed intermolecular [4+2] cycloaddition for the synthesis of chiral azomethine imines: mechanism and stereochemical model. Org. Chem. Front. 2025, 12, 2694-2703. DOI: https://doi.org/10.1039/D5QO00203F
[36] Li, J.*; Deng, Y.; Li, J.; Guo, Y.; Wang, G.; Duan, A.*; Qu, S.*, Mechanistic Study of Palladium-Catalyzed Ring-Opening/Cross-Coupling Reactions of Silacycles. Chinese Journal of Organic Chemistry. 2025, (accepted). DOI: 10.6023/cjoc202501003.
[35] Yao, J.-S.; Su, X.; Yu, Y.-Z.; Wu, J.-B.; Qu, S.*; Zhuo, C.-X.*, Divergent Synthesis of 2‐Quinolinones and Indolin‐3‐ones via Mo‐Catalyzed Controllable Carbonyl Deoxygenative Coupling and Formal Deoxygenative N—H Insertion Reactions. Chinese Journal of Chemistry. 2025, (accepted). DOI: https://doi.org/10.1002/cjoc.70016
[34] Tong, W.-Y.; Chen, Z.; Qu, S.*; Wang, Xiao.*, Mechanistic insight into Ni(i)-catalyzed regioselective alkene hydroarylation: is it carbonickelation or hydronickelation? Org. Chem. Front. 2024, 11, 7176-7185. DOI: https://doi.org/10.1039/D4QO01579G
[33] Ma, Y.; Zhang, Y.; Xie, G.; Huang, Z.; Peng, L.; Yu, C.; Xie, X.*; Qu, S.*; Zhang, N.*, Isolated Cu Sites in CdS Hollow Nanocubes with Doping-Location-Dependent Performance for Photocatalytic CO2 Reduction. ACS Catal. 2024, 14, 1468-1479. DOI: https://doi.org/10.1021/acscatal.3c05412 (ESI 高被引论文)
[32] Li, J.*; Chen, Z.; Qu, S.*, DFT study of rhodium-catalyzed transformation of silacyclobutane with alkyne or H2O: Si–Cl bond reductive elimination vs. alkyne insertion, Org. Chem. Front. 2024, 11, 3663–3674. DOI: https://doi.org/10.1039/D4QO00440J
[31] Lei, T.; Huang, Q.-N.; Wu, F; Xiao, Y.; Zhou, J.-L; Xu, T.-T; Wu, W.-B.; Qu, S.*; Feng., J.-J.* "C(sp2)–H cyclobutylation of hydroxyarenes enabled by silver-p-acid catalysis: diastereocontrolled synthesis of 1,3-difunctionalized cyclobutanes" Chem. Sci. 2023, 14, 9696. DOI: https://doi.org/10.1039/D3SC03258B
[30] Li, J.; Tang, D.; Zhang, Y.; Su, Xiao.; Yu, P.*; Qu, S.* "DFT study of Ni-catalyzed intramolecular asymmetric anti-hydrometalative cyclization of alkynone: mechanism and origins of selectivity" Org. Chem. Front. 2023, 10, 4263. DOI: https://doi.org/10.1039/D3QO00701D
[29] Tong, W.-Y.; Su, X.; Sun, Peng.; Xu, Shao.; Qu, S.*; Wang, Xiao.* "Understanding the Reaction Mechanism of Ni-Catalyzed Regio- and Enantioselective Hydroalkylation of Enamines: Chemoselectivity of (Bi-oxazoline)NiH" J. Org. Chem. 2023, 88, 15404. DOI: https://doi.org/10.1021/acs.joc.3c01939
[28] Dong, C.-S.#; Tong, W.-Y.#; Ye, P.; Cheng, N.; Qu, S.*; Zhang, B.* "Phenanthroline-Catalyzed anti-Selective Hydrosulfonylation of Un-activated Alkynes with Sulfonyl Chlorides" ACS Catal. 2023, 13, 6983. DOI: https://doi.org/10.1021/acscatal.3c01529
[27] Li, S.#; Tong, W.-Y.#; Zhou, Q.; Yu, X.; Shi, J.-L.; Li, S.-X.; Qu, S.*; Wang, J.* "Palladium-Catalyzed Oxidative Coupling of Dibenzosiloles with α-Diazo Esters: Formal Replacement of the Silyl Group with Carbenes" Organometallics. 2023, 42, 660. DOI: https://doi.org/10.1021/acs.organomet.3c00015 (封面论文)
[26] Li, J.; Luo, J.; Tong, W.; Tang, D.; Zhang, J.; Zhang, Z.; Qu, S.* "Mechanistic Study of Nickel-Catalyzed Intramolecular [4+2] Cycloaddition of Cyclobutanone with Allene: Origin of Selectivity and Ligand Effect" Org. Chem. Front. 2023, 10, 1672. DOI: https://doi.org/10.1039/D2QO01849G
[25] Jin, H.*; Tong, W.-Y.; Zhang, J.; Rudolph, M.; Rominger, F.; Shen, X.; Qu, S.*; Hashmi, A. S. K.* "Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity" Nature Communications. 2022, 13, 1672. DOI: https://doi.org/10.1038/s41467-022-29326-0
[24] Wang, X.; Tong, W.-Y.; Huang, B.; Cao, S.; Li, Y.; Jiao, J.; Huang, H.; Yi, Q.; Qu, S.*; Wang, X.* "Convergent Synthesis of 1,4-Dicarbonyl Z-Alkenes through Three-Component Coupling of Alkynes, α-Diazo Sulfonium Triflate, and Water" J. Am. Chem. Soc. 2022, 144, 4952-4965. DOI: https://doi.org/10.1021/jacs.1c12874
[23] Yao, X-Q.#; Tong, W.-Y.#; Kang, W.; Qu, S.*; Wang, J.* "Azacycle-Directed Formal Aromatic C(sp2)–H Insertion with Cr(0) Fischer Carbene Complex via Oxidative Hydrogen Migration" Organometallics. 2021, 40, 3526. DOI: https://doi.org/10.1021/acs.organomet.1c00352 (封面论文)
[22] Ji, Y-X.#; Li, J.#; Li, C-M.; Qu, S.*; Zhang, B*. "Manganese-Catalyzed N−F Bond Activation for Hydroamination and Carboamination of Alkenes" Org. Lett. 2021, 23, 207-212. DOI: https://doi.org/10.1021/acs.orglett.0c03916(ESI 高被引论文)
[21] Cheng, H.-G.; Yang, Z.; Chen, R.; Cao, L.; Wei, Q.; Tong, W.-Y.; Wang, Q.; Wu, C.; Qu, S.*; Zhou, Q.*, "A Concise Total Synthesis of (–)-Berkelic Acid" Angew. Chem. Int. Ed. 2020, 60, 5141. DOI: https://doi.org/10.1002/anie.202014660
[20] Liu, R.-Z.; Li, J.; Sun, J.; Liu, X.-G.; Qu, S.*; Li, P.*; Zhang, B*. "Generation and Reactivity of Amidyl Radicals: Manganese-Mediated Atom-Transfer Reaction" Angew. Chem. Int. Ed. 2020, 59, 4428-4433. DOI: https://doi.org/10.1002/anie.201913042
[19] Li, J.; Qu, S.; Zhao, W*. "Rhodium-Catalyzed Remote C(sp3)−H Borylation of Silyl Enol Ethers" Angew. Chem. Int. Ed. 2020, 59, 2360-2364. DOI: https://doi.org/10.1002/ange.201913281
[18] Lu, C.; Zhang, C.; Wang, P.; Zhao, Y.; Yang, Y.; Wang, Y.; Yuan, H.; Qu, S.; Zhang, X.; Song, G.; Pu, K., "Light-free Generation of Singlet Oxygen through Manganese-Thiophene Nanosystems for pH-Responsive Chemiluminescence Imaging and Tumor Therapy" Chem. 2020, 6, 2314-2334. DOI: https://doi.org/10.1016/j.chempr.2020.06.024
---------2018年之前----------
[17] Qu, S.*; Cramer, C. J. "Mechanistic Study of Cp*CoIII/RhIII-catalyzed Directed C-H Functionalization with Diazo Compounds" J. Org. Chem. 2017, 82, 1195-1204. DOI: 10.1021/acs.joc.6b02962 (ESI 高被引论文)
[16] Ono, T.; Qu, S.; Johnson, M.; Cramer, C. J.*; Llobet, A*. "Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects" ACS Catal. 2017. DOI: 10.1021/acscatal.7b00603 (共同一作)
[15] Qu, S.; Dang, Y.; Song, C.; Wen, M.; Huang, K.-W.; Wang, Z.-X*. "Catalytic Mechanisms of Direct Pyrrole Synthesis via Dehydrogenative Coupling Mediated by PNP-Ir or PNN-Ru Pincer Complexes: Crucial Role of Proton-transfer Shuttles in the PNP-Ir system" J. Am. Chem. Soc. 2014, 136, 4974-4991. DOI: 10.1021/ja411568a
[14] Ye, F.; Qu, S.; Zhou, L.; Peng, C.; Wang, C.; Cheng, J.; Hossain, M. L.; Liu, Y.; Zhang, Y.; Wang, Z.-X.*; Wang, J*. "Palladium-Catalyzed C–H Functionalization of Acyldiazomethane and Tandem Cross-Coupling Reactions" J. Am. Chem. Soc. 2015, 137, 4435-4444. DOI: 10.1021/ja513275c (共同一作)
[13] Xia, Y. ; Qu, S.; Xiao, Q. ; Wang, Z.-X.*; Qu, P.; Chen, L.; Liu, Z.; Tian, L.; Huang, Z.; Zhang, Y.; Wang, J*. "Palladium-Catalyzed Carbene Migratory Insertion Using Conjugated Ene-Yne-Ketones as Carbene Precursors" J. Am. Chem. Soc. 2013, 135, 13502-13511. DOI: 10.1021/ja4058844 (共同一作)
[12] Qu, S.; Dang, Y.; Song, C.; Guo, J.; Wang, Z-X*. "Depolymerization of Oxidized Lignin Catalyzed by Formic Acid Exploits an Unconventional Elimination Mechanism Involving 3c–4e Bonding: A DFT Mechanistic Study" ACS Catal. 2015, 5, 6386-6396. DOI: 10.1021/acscatal.5b01095
[11] Qu, S.; Dai, H.; Dang, Y.; Song, C.; Wang, Z.-X.*; Guan, H. "Computational Mechanistic Study of Fe-Catalyzed Hydrogenation of Esters to Alcohols: Improving Catalysis by Accelerating Pre-catalyst Activation with a Lewis Base" ACS Catal. 2014, 4, 4377-4388. DOI: 10.1021/cs501089h
[10] Qu, S.; Dang, Y.; Wen, M.; Wang, Z.-X*. "Mechanism of the Methyltrioxorhenium- Catalyzed Deoxydehydration of Polyols: A New Pathway Revealed" Chem.-Eur. J. 2013, 19, 3827-3832. DOI: 10.1002/chem.201204001
[9] Lu, Y.; Liu, Z.; Guo, J.; Qu, S.; Zhao, R.; Wang, Z.-X*. "A DFT Study Unveils the Secret of How H2 is Activated in the N-formylation of Amines with CO2 and H2 Catalyzed by Ru (II) Pincer Complexes in the Absence of Exogenous Additives" Chem. Commun. 2017, 53, 12148-12151. DOI: 10.1039/C7CC06795J
[8] Guo, J.; Deng, X.; Song, C.; Lu, Y.; Qu, S.; Dang, Y.; Wang, Z.-X*. "Differences Between the Elimination of Early and Late Transition Metals: DFT Mechanistic Insights into the Titanium-Catalyzed Synthesis of Pyrroles from Alkynes and Diazenes" Chem. Sci. 2017, 8, 2413- 2425. DOI: 10.1039/C6SC04456E
[7] Dang, Y.; Qu, S.; Tao, Y.; Deng, X.; Wang, Z.-X*. "Mechanistic Insight into Ketone α-Alkylation with Unactivated Olefins via C–H Activation Promoted by Metal–Organic Cooperative Catalysis (MOCC): Enriching the MOCC Chemistry" J. Am. Chem. Soc. 2015, 137, 6279-6291. DOI: 10.1021/jacs.5b01502
[6] Dang, Y.; Qu, S.; Nelson, J. W.; Pham, H. D.; Wang, Z.-X.*; Wang, X*. "The Mechanism of a Ligand-Promoted C(sp3)–H Activation and Arylation Reaction via Palladium Catalysis: Theoretical Demonstration of a Pd(II)/Pd(IV) Redox Manifold" J. Am. Chem. Soc. 2015, 137, 2006-2014. DOI: 10.1021/ja512374g
[5] Dang, Y.; Qu, S.; Wang, Z.-X. *; Wang, X*. "A Computational Mechanistic Study of an Unprecedented Heck-Type Relay Reaction: Insight into the Origins of Regio- and Enantioselectivities" J. Am. Chem. Soc. 2014, 136, 986-998. DOI: 10.1021/ja410118m
[4] Dang, Y.; Qu, S.; Tao, Y.; Song, C.; Wang, Z.-X*. "Mechanistic Origins of Chemo- and Regioselectivity of Ru(II)-Catalyzed Reactions Involving ortho-Alkenylarylacetylene, Alkyne, and Methanol: The Crucial Role of a Chameleon-like Intermediate" J. Org. Chem. 2014, 79, 9046-9064. DOI: 10.1021/jo501399x
[3] Song, C.; Qu, S.; Tao, Y.; Dang, Y.; Wang, Z.-X*. "DFT Mechanistic Study of RuII-Catalyzed Amide Synthesis from Alcohol and Nitrile Unveils a Different Mechanism for Borrowing Hydrogen" ACS Catal. 2014, 4, 2854-2865. DOI: 10.1021/cs5008156
[2] Chen, T.; Li, H.; Qu, S.; Zheng, B.; He, L.; Lai, Z.; Wang, Z.-X.*; Huang, K.-W*. "Hydrogenation of Esters Catalyzed by Ruthenium PN3-Pincer Complexes Containing an Aminophosphine Arm" Organometallics 2014, 33, 4152-4155. DOI: 10.1021/om500549t
[1] Dang, Y.; Qu, S.; Wang, Z.-X. *; Wang, X*. "Mechanism and Origins of Z Selectivity of the Catalytic Hydroalkoxylation of Alkynes via Rhodium Vinylidene Complexes to Produce Enol Ethers" Organometallics 2013, 32, 2804-2813. DOI: 10.1021/om400227u
二、发明专利:
[9] 利用冶金固废制备的耐高温无机涂料及其制备方法和应用、以及复合结构 (ZL.202510358505.3)。
[8] 水性零VOCs微纳新型环保饰面砂浆及其制备方法与应(ZL.2022115364202)。
[7] 一种硅酸钙盐晶种胶体及其制备方法 (ZL.2022114541252)。
[6] 一种金属冶炼废渣衍生材料及其制备方法与应用 (ZL.2022114541248)。
[5] 一种自流平自密实耐磨地面材料及其制备方法 (ZL.2022114541163)。
[4] 一种低碳井下充填料及其制备方法 (ZL.2022114541233)。
[3] 用于尾砂浓缩与填料制备的一体化智能装置及其应用 (ZL.2022114805301)。
[2] 一种矿尾砂衍生自成型材料及其制备方法 (ZL.2022115572239)。
[1] 一种全尾砂基3D打印增材的制备方法和应用 (ZL.2022115553967)。