精细化工

(1) 新型金属硫族纳米团簇的设计合成和表面官能化；
(2) 金属硫族簇基开放骨架和基于金属硫族簇基MOFs材料的设计合成；
(3) 具有半导体特性类分子筛骨架材料的设计合成和光电性能调控；
(4) 基于微孔半导体主客体材料的构建及其能量转移和光电子转移机制研究；
(5) 离散型金属硫族纳米团簇的荧光和电化学发光性能研究；
(6) 多元金属硫族簇基电催化剂的制备及其电催化、光催化性能研究；
(7) 含惰性键有机分子和无机小分子的光活化与高效转化；

Extreme Learning Machine;Traction Control Unit;Fault Diagnosis;Differential Evolution Algorithm

Semiconductor clusters enable high-efficiency extraction of hot electrons from gold nanorods for photocatalytic organic conversions, Liu, J.-X.++; Ma. H.++; Yuan, S.-F.*, Zhang, J.-N.; Liang, J.-G.; Zhou, R.; Li, D.-S.; Chen, W. B.; Li, M.-D.; Wu, T.* Sci. China Chem., 2025, https://doi.org/10.1007/s11426-024-2506-8. [++These authors contributed equally to this work]

Significantly enhanced NIR emission of solid-state clusters based on Cu4Pt2 triggered with volatile organic compounds, Hu, X. N.++; Zhong, X.-H.++; Zhong, R.-R.; Zhang, L.-M.; Hao, D.-B.; Xu, Q.; Wei, H.-Z.; Zhou, R.; Wei, J. Y.; Liu, K.-G.; Yuan, S.-F.*; Li, D.-S.; Wu, T.* Nanoscale, 2025, 17, 5829-5837. [++These authors contributed equally to this work]

Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production, Chen, W. X.; Qiao, X.-Q.*; Hui, G.; Su, B. J.; Hou, D. F.; Wang, M. D.; Wu, X. Q.; Wu, T.*; Li, D.-S.*J. Energy Chem., 2025, 100, 710-720.

Skillful promotion of charge separation via defect-mediated built-in electric field and LSPR effect for enhanced photocatalytic activity, Guo, H.++; Chen, W. X.++; Qiao, X.-Q.*; Li, C.; Sun, B. J.; Hou, D. F.; Wang, M. D.; Wu, X. Q.; Wu, T.*; Chi, R. A.; Li, D.-S.* Nano Energy, 2025, 135, 110672. [++These authors contributed equally to this work]

Semiconductor-cluster-loaded ionic covalent organic nanosheets with enhanced photocatalytic reduction reactivity of nitroarenes, Zhang, J.-N.++; Liu, J.-X.++; Ma. H.; Luo, X.; Han, C.-K.; Zhou, R.; Yuan, S.-F.*, Wu, T.* J. Mater. Chem. A, 2024, 12, 14398. [++These authors contributed equally to this work]

Highly intense NIR emissive Cu4Pt2 bimetallic clusters featuring Pt(I)-Cu4-Pt(I) sandwich kernel, Zhong, R.-R.++; Xie, M.++; Luan, C.-Z.; Zhang, L.-M.; Hao, D.-B.; Yuan, S.-F.*, Wu, T.* Chem. Sci., 2024, 15, 7552. [++These authors contributed equally to this work]

Atomic- and molecular-level modulation of Mn2+-related emission using atomically-precise metal chalcogenide semiconductor nanoclusters, Wang, Z. Q.; Liu, J.-X.; Ma, H.; Xu, Y.-L.; Zhou, R.; Li, D.-S.; Yuan, S.-F*.; Wu, T.* Coord. Chem. Rev., 2024, 510, 215844. [++These authors contributed equally to this work]

N-heterocyclic carbene-stabilized Cu9 Clusters with Combined Thermally Activated Delayed Fluorescence and Phosphorescence, Zhang, L.-M.; Xie, M.; Wei, H. Z.; Yuan, S.-F.*; Wu, T.* Inorg. Chem. Front., 2024, 11, 2498-2507. [++These authors contributed equally to this work]

Molecular Insight into Intrinsic-Trap-Mediated Emission from Atomically Precise Copper-based Chalcogenide Models, Xu, Y.-L.++; Ding, Y. Y.++; Zhang, L.-M.; Ma, H.; Liu, J.-X.; Zhang, J. X.; Zhou, R.; Li, D.-S.; Yuan, S.-F.*; Wu, T.* Inorg. Chem. Front., 2024, 11, 409−416. [++These authors contributed equally to this work]

Interface Microenvironment Mediates Emission of Semiconductor Nanocluster via Surface-Dopant-Involved Direct Charge Transfer, Wang, Z. Q.++; Ma, H.++; Zhang, J. X.++; Lan, Y. J.++; Liu, J.-X.; Yuan, S.-F.; Zhou, X.-P.; Li, X. H.; Qin, C. C; Li, D.-S.; Wu, T.* Chem. Sci. 2023, 14, 10308−10317. [++These authors contributed equally to this work]

Atomic-Level Insights into Manganese-Environment-Related Photophysical Properties of II-III-VI Quantum Dots Using Well-Defined Nanofragments, Zhang, J. X.++; Wang, J.++; Li, J.++; Debnath, T.++; Zhou, R.; Wang, Z. Q.; Xu, L. H.; Wang, X.; Qin, C. C.*; Xu, D. G.*; Yang, S. R.; Li, M. D.; Li, D.-S.; Wu, T.* J. Phys. Chem. C. 2023, 127, 15951−15961. [++These authors contributed equally to this work]

Atomically Precise Metal Chalcogenide Supertetrahedral Clusters: Frameworks to Molecules, and Structure to Function, Zhang, J. X.; Feng, P.*; Bu, X.; Wu, T.* Nat. Sci. Rev., 2022, 9, nwab076.

Ultrastable Anti-Acid “Shield” in Layered Silver Coordination Polymers, Sun, P. P. ++; Xie, M. ++; Zhang, L.-M.; Liu, J.-X.; Wu, J.; Li, D.-S.; Yuan, S.-F.*; Wu, T.*; Li, D.* Angew. Chem. Int. Ed. 2022, 61, e202209971. [++These authors contributed equally to this work]

A Chalcogenide-cluster-based Semiconducting Nanotube Array with Oriented Photoconductive Behavior, Tang, J. Q.++; Wang, X.++; Zhang, J. X.++; Wang, J.; Yin, W. J.; Li, D.-S.; Wu, T.* Nat. Commun. 2021, 12, 4275. [++These authors contributed equally to this work]

一种铜-铂多核团簇及其制备方法与应用，袁尚富、钟瑞茹、王春凤、周瑞、吴涛、李丹，授权专利号：ZL 2023 1 0092150.9
一种光催化芳香硝基化合物为氧化偶氮苯类化合物的方法，袁尚富、马浩、周瑞、吴涛、李丹，授权专利号：ZL 2024 1 0533960.8

国家自然科学基金重大研究计划集成项目，92461309，基于环三核单元的异类型团簇组装体的构筑、结构与功能研究，2025.01–2027.12，318 万元（直接经费），参与，执行中。
生物活性分子与成药性优化全国重点实验室自主课题，20240202，团簇基复合光催化剂创制与含惰性官能团药物分子的衍生化，2024.06–2026.05，50 万元，主持，执行中。
国家自然科学基金重大研究计划重点项目，92261205，原子精确硫族半导体分子团簇中热电子动力学及其光催化应用研究，2023.01–2026.12，370 万元（直接经费），主持，执行中。
国家自然科学基金面上项目，22071165，锰基半导体纳米团簇的构筑及其荧光调控机制与器件化研究，2021.01–2024.12，63 万元（直接经费），主持，已结题。
国家自然科学基金面上项目，21875150，多元金属硫族簇基电催化剂的制备及其电催化还原反应性能研究，2019.01–2022.12，65 万元（直接经费），主持，已结题。
国家自然科学基金面上项目，21671142，基于金属硫族半导体分子筛主客体复合材料的构建以及主体参与的能量和电子转移机制研究，2017.01–2020.12，65 万元（直接经费），主持，已结题。
国家自然科学基金面上项目，21271135，新型半导体“量子点”材料：金属硫族超四面体簇的离散化和表面功能化，2013.01–2016.12，80 万元，主持，已结题。
江苏省科学技术厅杰出青年基金项目，BK20160006，金属硫族纳米团簇及其超结构的构建与功能化研究，2016.07–2019.06, 100 万元，主持，已结题。

技术咨询