精细化工

1）含硫挥发性有机物催化去除及资源化利用
2）丙烷二氧化碳氧化脱氢
3）二氧化碳加氢甲烷化

Methyl Mercaptan;Aerobic Oxidation;Deactivation Mechanism;Sulfur-containing Vocs;Dry Reforming;Support Effects;Metal-support Interactions;Cr-based Catalysts;Tempo-peg(4000)-nhc-cu(ii) Complex;Amphiphilic Catalyst

[1]Zijun Huang,Xiaohua Cao*, Huaiyu Xu, Miao Lin, Dedong He, Dingkai Chen, Jichang Lu*, Yongming Luo*,Revealing low-temperature reaction mechanism of cobalt-doped CeO2catalyst for catalytic removal of methyl mercaptan,Journal of Rare Earths, 2025,1002-0721.
[2]Huaiyu Xu ,Xiaohua Cao*, Xiude Peng , Miao Lin , Dedong He , Jichang Lu , Dingkai Chen , Yongming Luo*，Catalytic autoxidation of methyl mercaptan at room temperature over three-dimensionally ordered macroporous Cu2Ce8O catalyst,Separation and Purification Technology, 2025, 367, 132891.
[3]Xiude Peng,Xiaohua Cao*, Huaiyu Xu, Ruibin Xiong, Dedong He, Dingkai Chen, Yongming Luo*, Modulation of acidic–basic and metal–carrier interactions in CO2-assisted propane dehydrogenation over Ga2Lax/ZSM-5 catalysts,New Journal of Chemistry, 2025, 49, 8867-8876.
[4]Zixuan Wang,Xiaohua Cao*, Zijun Huang, Dedong He, Wenwei Wu*, Yongming Luo*, Enhanced sulfur-resistance in Fe-based catalysts with secondary crystallization for the removal of odorous S-VOCs (CH3SH),Catalysis Today,2024, 439, 114810.
[5]Yuqiu Zhu, Yulai Lin, Jiaming Dong, Jun Liang, Dedong He, Tianhao Ai*,Xiaohua Cao*, Yongming Luo*, Precisely constructing Ce-loaded sulfur resistant catalyst for efficient methane dry reforming,Surfaces and Interfaces, 2024, 50, 104517.
[6]Xiaohua Cao, Tianhao Ai, Zhizhi Xu, Jichang Lu*, Dingkai Chen, Dedong He, Jiangping Liu, Rui Tian, Yutong Zhao, Yongming Luo*, Insights into the different catalytic behavior between Ce and Cr modified MCM-41 catalysts: Cr2S3as new active species for CH3SH decomposition,Separation and Purification Technology, 2023, 307, 122742.
[7]Xiaohua Cao, Jichang Lu*, Xiangqian Zheng, Dedong He, Wenjie Zhu, Yutong Zhao, Wenjun Zhang, Rui Tian, Yongming Luo*, Regulation of the reaction pathway to design the high sulfur/coke-tolerant Ce-based catalysts for decomposing sulfur-containing VOCs,Chemical Engineering Journal, 2022, 429, 132473.
[8]Bihui He, ZhiZhi Xu,Xiaohua Cao*, Jichang Lu*, Jian Fang, Yubei Li, Siyou Feng, Yongming Luo, The influence of lanthanum (La) promoter on Mo/Al2O3for the catalytic synthesis of methyl mercaptan (CH3SH) from COS/H2/H2S,Fuel Processing Technology, 2022, 238, 107488.
[9]Xiaohua Cao, Jichang Lu*, Yutong Zhao, Rui Tian, Wenjun Zhang, Dedong He, Yongming Luo*, Promotional Effects of Rare-Earth Praseodymium (Pr) Modification over MCM-41 for Methyl Mercaptan Catalytic Decomposition,Processes,2021, 9, 400.
[10]Xiaohua Cao, Dedong He, Jichang Lu, Yutong Zhao, Yi Mei, Caiyun Han*, Yongming Luo*, The negative effect of P addition of La/HZSM-5 on the catalytic performance in methyl mercaptan abatement,Applied Surface Science, 2019, 494, 1083-1090.
[11]Zijun Huang,Xiaohua Cao, Hao Wang, Dingkai Chen, Xianming Chen, Dedong He, Shuquan Huang*, Yongming Luo*,Ni-doped Co/SPP zeolite catalyst with optimized metal oxide-support interaction for propane dehydrogenation to propylene,Chemical Engineering Journal,2025,511, 162074.
[12]Zijun Huang, Yubing Li*, Yongming Luo*, Dingkai Chen,Xiaohua Cao, Hao Wang, Shuquan Huang, Dedong He*, Boosting propane dehydrogenation performance by engineering of cobalt positions in MFI zeolite,Chemical Engineering Journal,2025,506,160153.
[13]Zijun Huang,Dedong He*,Jichang Lu,Lanfang Han,Kongzhai Li,Dingkai Chen,Xiaohua Cao,Tan Li,Yongming Luo*，Modifying the Charge-Density of Tetrahedral Cobalt(II) Centers through Carbon-Layer Modulation Promotes C-H Activation in the Propane Dehydrogenation Reaction (PDH)，Angewandte Chemie international Edition，2024，1433-7851.
[14]Dedong He, Shaojie Wu,Xiaohua Cao, Dingkai Chen*, Lei Zhang, Yu Zhang, Yongming Luo*, Dynamic trap of Ni atelevated temperature for yielding high-efficiency methane dry reforming catalyst，Applied Catalysis B: Environment and Energy，2024，346，123728.
[15]Dedong He, Yimin Zhang,* Tan Li, Dingkai Chen, Hao Wang, Lei Zhang, Jiangping Liu,Xiaohua Cao, Jichang Lu,* and Yongming Luo*，Designing Ultra-Stable and Surface-Exposed NiNanoparticles with Dually Confined Microenvironment for High-Temperature Methane Dry Reforming，Advanced Functional Materials，2024，12895.
[16]Rui Tian, Jichang Lu*, Zhizhi Xu, Wenjun Zhang, Jiangping Liu, Langlang Wang, Yibing Xie, Yutong Zhao,Xiaohua Cao, and Yongming Luo*. Unraveling the Synergistic Reaction and the Deactivation Mechanism for the Catalytic Degradation of Double Components of Sulfur-Containing VOCs over ZSM-5-Based Materials，Environmental Science Technology, 2023, 57, 3, 1443–1455.
[17]Jiangping Liu, Hong Su, Yanan Hu*, Chenhao Gong, Jichang Lu, Dedong He, Wenjie Zhu, Dingkai Chen,Xiaohua Cao, Jun Li, Sasho Gligorovski, Yongming Luo*, Highly efficient degradation of sulfur-containing volatile organic compounds by amorphous MnO2at room temperature: Implications for controlling odor pollutants,Applied Catalysis B: Environmental, 2023, 334, 122877.
[18]Yutong Zhao, Dingkai Chen, Jiangping Liu, Dedong He,Xiaohua Cao, Caiyun Han, Jichang Lu*, Yongming Luo*. Tuning the metal-support interaction on chromium-based catalysts for catalytically eliminate methyl mercaptan: Anchored active chromium species through surface hydroxyl groups,Chemical Engineering Journal, 2020, 389, 124384.

[1]曹小华,徐怀钰,罗永明,陆继长,何德东,陈定凯,彭秀德,黄树全,王皓，一种钴改性球形氧化铈催化剂在催化分解甲硫醇中的应用（发明专利，2024年10月31日受理，专利号：2024115377146）。
[2]罗永明,曹小华,彭秀德,徐怀钰,陆继长,何德东,陈定凯,黄树全,王皓，一种无金属催化剂在煤气化过程中催化分解甲硫醇的应用（发明专利，2024年10月31日受理，专利号：202411538291X）。
[3]何德东,李嘉诚,曹小华,陈定凯,一种聚硅酸铁锆絮凝剂在去除污水中的磷酸盐和氟中的用途（发明专利，2025年01月22日受理，专利号：2025100980192）。

[1]国家自然科学基金青年基金项目，构建非对称氧空位催化剂应用于室温下甲硫醇催化自氧化脱除机理研究（批准号：22306081），2024.01-2026.12，30万，在研，主持；
[2]云南省基础研究专项青年基金项目，淬火诱导合成Co-Ce双金属单原子催化剂应用于含硫物种的脱除机理研究（批准号：202401AU070136）2024.06-2027.05，5万，在研，主持；
[3]昆明理工大学高层次人才引进经费，80万，2022.09—2030.09，在研，主持；
[4]国家自然科学基金重点项目，褐煤气化过程中含硫挥发性有机物的排放特征与控制机理研究（批准号：42030712），2021.01—2025.12，296万，在研，参与（排名第二）；
[5]云南省重大科技专项计划，天然橡胶行业典型污染防治与资源化关键核心技术研究与应用（批准号：202202AG050004），2023.01—2025.01，2000万，在研，参与子课题（排名第三）；
[6]国家自然科学基金地区基金项目，液化石油气中含硫挥发性有机物定向转化耦合低碳烷烃脱氢制烯烃的应用基础研究（批准号：21966018），2020.01—2023.12，40万，结题，参与（排名第四）。

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