精细化工

绿色化学、光电催化二氧化碳转化（人工光合成）

光电催化;环碳酸酯;环氧化合物;二氧化碳;掺杂;二氧化碳还原;人工光合成;偶联反应;二氧化钛;共沉淀法

Carbon Dioxide;Photoelectrocatalysis;Co2 Reduction;Coupling Reaction;Epoxides;Epoxide;Cyclic Carbonate;Ionic Liquids;Heterojunction;Cycloaddition

1. Youzhi Cao et al., Photoelectrothermocatalytic reduction of CO2 to glycol via Cu2S/MoS2-Vs octahedral heterostructure with synergistic mechanism, Journal of Colloid and Interface Science 666 (2024) 141–150. https://doi.org/10.1016/j.jcis. 2024.03.172
2. Chunyan Liu, et al., Photoelectrothermocatalytic reduction of CO2 to glycol via CdIn2S4-N/C hollow heterostructure mimicking plant cell, Chemical Engineering Journal 485 (2024) 149707. https://doi.org/10.1016/j.cej.2024.149707
3. Wenrui Wan, et al., Triazine-COF@Silicon nanowire mimicking plant leaf to enhance photoelectrocatalytic CO2 reduction to C2+ chemicals, Green Energy & Environment, XXX (2024) XXXXX. https://doi.org/10.1016/j.gee.2024.04.007
4. Wanchao Kang, et al., Unraveling sequential oxidation kinetics and determining roles of multi-cobalt active sites on Co3O4 catalyst for water oxidation, J. Am. Chem. Soc. 2023, 145, 3470−3477. https://doi.org/10.1021/jacs.2c11508
5. Youzhi Cao, et al., Photoelectrochemical reduction of CO2 catalyzed by a 3D core–shell NiMoO4@ZnO heterojunction with bicentre at the (111) plane and thermal electron assistance Journal of Material Chemistry A, 2023, 11, 4230–4237. https://doi.org/10.1039/d2ta09055d
6. Yan Wei, et al. Photoelectrocatalytic reduction of CO2 catalyzed by TiO2/TiN nanotube heterojunction: Nitrogen assisted active hydrogen mechanism, Chinese Journal of Catalysis,47(2023)243–253. https://doi.org/10.1016/S1872‐2067(23) 64395‐5
7. Chunyan Liu, et al., Different behaviors on the external and inner surface of hollow CdS/VS-MoS2 heterojunctions in photoelectrocatalytic CO2 reduction via SH-assisted mechanism, Applied Catalysis B: Environmental 325 (2023) 122394. https://doi.org/ 10.1016/j.apcatb.2023.122394
8. Wenrui Wan, et al., p-n heterojunctions of Si@WO3 mimicking thylakoid for photoelectrocatalytic CO2 reduction to C2+ products — Morphology control, Chemical Engineering Journal 454 (2023) 140122. https://doi.org/10.1016/ j.cej.2022.140122
9. Yong Liu, et al. Bipolar charge collecting structure enables overall water splitting on ferroelectric photocatalysts, Nature Communications 13 (2022) 4245. https://doi.org/10.1038/s41467-022-32002-y
10. Jiangping Ma, et al., Identifying and Removing the Interfacial States in Metal Oxide−Semiconductor Schottky Si Photoanodes for the Highest Fill Factor, J. Am. Chem. Soc. 144 (2022) 17540−17548. https://doi.org/10.1021/jacs.2c06748
11. Jinyuan Wang, et al., New heterojunctions of CN/TiO2 with different band structure as highly efficient catalysts for artificial photosynthesis, Applied Catalysis B: Environmental 285 (2021) 119781. https://doi.org/10.1016/j.apcatb.2020.119781
12. 于晓刚 等，磷掺杂提升三氧化钨导带用于高效二氧化碳还原，科学通报，66(7) (2021) 825 ~ 832. doi: 10.1360/TB-2020-0937
13. Bing Wang, et al., Cu@porphyrin-COFs nanorods for efficiently photoelectrocatalytic reduction of CO2, Chemical Engineering Journal 396 (2020) 125255. https://doi.org/10.1016/j.cej.2020.125255
14. Jinyuan Wang, et al., Photoelectrocatalytic Reduction of CO2 to Paraffin Using p-n Heterojunctions, iScience, 2020, 23, 100768. https://doi.org/10.1016/j.isci. 2019.100768
15. Jixian Wang, et al., In situ grown heterojunction of Bi2WO6/BiOCl for efficient photoelectrocatalytic CO2 reduction, Journal of Catalysis 377 (2019) 209–217. https://doi.org/10.1016/j.jcat.2019.06.007
16. Yapeng Dong, et al., Photoelectrocatalytic CO2 reduction based on metalloporphyrin-modified TiO2 photocathode, Chinese Journal of Catalysis 40 (2019) 1222–1230. doi: S1872-2067(19)63375-9
17. Jinyuan Wang, et al., New crown ether complex cation ionic liquids with N-heterocycle anions: preparation and application in CO2 fixation, Org. Chem. Front., 5 (2018) 741–748. DOI: 10.1039/c7qo00829e
18. Yanjie Xu, et al., Highly efficient photoelectrocatalytic reduction of CO2 on the Ti3C2/g-C3N4 heterojunction with rich Ti3+ and pyri-N species, J. Mater. Chem. A, 2018, 6, 15213–15220. DOI: 10.1039/c8ta03315c
19. Bo Han, et al., The photoelectrocatalytic CO2 reduction on TiO2@ZnO heterojunction by tuning the conduction band potential, Electrochimica Acta 2018, 285, 23–29. https://doi.org/10.1016/j.electacta.2018.07.216
20. Yanjie Xu, et al., In-situ grown nanocrystal TiO2 on 2D Ti3C2 nanosheets for artificial photosynthesis of chemical fuels, Nano Energy 51 (2018) 442–450. https://doi.org/10.1016/j.nanoen.2018.06.086
21. Xiying Fu, et al., Chiral basket‐handle porphyrin‐Co complexes for the catalyzed
asymmetric cycloaddition of CO2 to epoxides, Chinese Journal of Catalysis 39 (2018) 997–1003. DOI:10.1016/S1872‐2067(18)63023‐2
22. Jixian Wang, et al., Photoelectrocatalytic Reduction of CO2 to Chemicals via ZnO@Nickel Foam: Controlling C–C Coupling by Ligand or Morphology, Topics in Catalysis (2018) 61:1563–1573 https://doi.org/10.1007/s11244-018-1018-y
23. Xueying Wang, et al., Metal-free iodine(III)-promoted synthesis of 2,5-diaryloxazoles, Org. Biomol. Chem., 2018, 16, 3104–3108. DOI: 10.1039/c8ob00401c
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25. Yanjie Xu, et al., Photoelectrocatalytic reduction of CO2 to methanol over the multi-functionalized TiO2 photocathodes, Applied Catalysis B: Environmental 205 (2017) 254–261. http://dx.doi.org/10.1016/j.apcatb.2016.12.039
26. Xiaofeng Zhang, et al. Substituted and Anchoring Groups Improve the Efficiency
of Dye-Sensitized Solar Cells, ChemistrySelect 2 (2017) 4084 – 4091. https://doi.org/10.1002/slct.201700494
27. Da-gang Zhou, et al., Mechanism of selective C–H cyanation of 2-phenylpyridine with benzyl nitrile catalyzed by CuBr: a DFT investigation Org. Chem. Front., 4 (2017) 377 – 385. DOI: 10.1039/c6qo00652c
28. Si Chen et al., Palladium-Catalyzed Isocyanide Insertion with Allylic Esters: Synthesis of N-(But-2-enoyl)-N-(tert-butyl)benzamide Derivatives via Intramolecular Acyl Transfer Termination, Adv. Synth. Catal. 359 (2017) 3538 – 3544. DOI: 10.1002/adsc.201700765
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improved photoelectrocatalytic reduction of CO2 to methanol, Journal of Catalysis 349 (2017) 1–7. http://dx.doi.org/10.1016/j.jcat.2017.01.013
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33. Zhen Wenlong, et al. The role of a metallic copper interlayer during visible photocatalytic hydrogen generation over a Cu/Cu2O/Cu/TiO2 catalyst, Catal. Sci. Technol., 7 (2017) 5028–5037. DOI: 10.1039/c7cy01432e

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1. 异质结微结构调控及光电催化CO2制备化学品，lzujbky-2021-sp55，兰州大学战略发展专项项目-“双碳”计划专项， 2022.1.1-2023.12.31， 30万元
2. 掺杂半导体异质结微结构调控及光电催化二氧化碳还原为高碳醇, 21JR7RA466, 甘肃省科技计划项目, 2021.11-2023.10, 6万元
3. 光电催化CO2制备高碳醇及合成气放大试验，2021620005001561，横向课题， 2021.1-2022.12，90万元
4. 高效二氧化碳消纳技术研究，2018620001001365，横向课题，2019.1-2021.12，20万元
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