天然气化工,新材料,石油炼制,石油化工,精细化工,生物医药

1、含噻二唑的功能分子的合成与表征。
2、D-A环丙烷的反应方法学研究

Molecular Wires;Molecular Electronics;Bioinformatics;Convergent Synthesis;Self Assembled Monolayer;Biomedical Research;Oligo(phenylene Ethynylene) (ope);Atomic Force Microscopy;Absorption Spectra;Null

Molecular Wires;Electron Transport;Dendrimers;Carboxylic Acids;Synthesis;Molecular Electronics;Single-molecule Junction;Cycloaddition;Regioselectivity;Triphenylamine

1. Enantioselective Formal Synthesis of (+)-Cycloclavine and Total Synthesis of (+)-5-epi-Cycloclavine, W. Wang, Y. Mi, X. P. Cao*, Z. F. Shi*, Org. Lett. 2019, 21, 6603-6607.
2. Modulation of piezochromic fluorescence behavior by subtle structural change, T. Man, N.-S. Xu, Z.-H. Yu, Y. Huo, Y. Yuan, Z.-F. Shi*, X.-P. Cao, L. Wang*, H.-L. Zhang*, Dyes and Pigments 2019, 166, 301-306.
3. Access to Sulfides through Free Radical Reaction of Vinyl Halides with Thiols, Z.-F. Shi*, L.-N. Xu, J. Chen, H.-X. Luo, J. Zhang, X.-P. Cao*, Asian J. Org. Chem. 2019, 8, 161-170.
4. Organocatalytic Enantioselective Tandem Michael Addition and Cyclization Reaction of Trisubstituted 2-Nitro-1,3-enynes with Cyclic 1,3-Diketones, Z.-M. Xing, L.-L. Song, F.-X. Li, N.-S. Xu, L.-F. Wang, Z.-F. Shi*, X.-P. Cao, Adv. Synth. Catal. 2017, 359, 1892-1900.
5. Dendron-Enhanced Emission from 1,4-Bis[2,2-bis(4-alkoxyphenyl)vinyl]benzene Derivatives, Z.-F. Shi*, P. An, W. Wen, Z.-M. Xing, X.-P. Cao*, H.-L. Zhang, Asian J. Org. Chem. 2016, 5, 786-791.
6. Facile Preparation of α-Cyano-α,ω-Diaryloligovinylenes: A New Class of Color-Tunable Solid Emitters, P. An, N.-S. Xu, H.-L. Zhang, X.-P. Cao*, Z.-F. Shi*, W. Wen, Chem. Asian J. 2015, 10, 1959-1966.
7. Construction of Fused- and Spiro-oxa-[n.2.1] Skeletons by a Tandem Epoxide Rearrangement/intramolecular [3+2] Cycloaddition of Cyclopropanes with Carbonyls, L.-F. Wang, Z.-F. Shi*, X.-P. Cao*, B.-S. Li, P. An, Chem. Commun. 2014, 50, 8061-8064.
8. A Phosphine-Catalyzed Regioselective [3+2] Cycloaddition of Ethyl 5,5-Diarylpenta-2,3,4-trienoate with Aromatic Aldehydes and α,β-Unsaturated Carbonyl Compounds, L.-F. Wang, X.-P. Cao*, Z.-F. Shi*, P. An, H.-F. Chow, Adv. Synth. Catal. 2014, 356, 3383-3390.
9. Pentacenobis(thiadiazole)dione, an n-Type Semiconductor for Field-Effect Transistors, Z.-F. Shi, H. T. Black, A. Dadvand, D. F. Perepichka*, J. Org. Chem. 2014, 79, 5858-5860.

1、发明专利，一种双三唑并五苯醌类化合物及其制备方法，ZL201710219181.0。
2、发明专利，一种具有有机场效应晶体管性质的材料及其制备方法，ZL201310525961.X。

1、国家自然科学基金 面上项目，2016年1月1日至2019年12月31日，主持。

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