精细化工

[1]新型配体的设计、合成及应用。
[2]不对称催化。
[3]金属催化的C-N键形成反应。

D.-Q. Wu, Z.-Y. Guan, Y. Peng, J. Sun, C. Zhong, Q.-H. Deng*. Iron(II) Chloride-Catalyzed Nitrene Transfer Reaction for Dearomative Amination of β-Naphthols with Aryl Azides. Adv. Synth. Catal., 2018, Ahead of Print.
W. Zhou, Y. L. Mei, B. Li, Z. Y. Guan, Q.-H. Deng*. Synthesis of beta-Alkyl 2-Hydroxychalcones by Rhodium-Catalyzed Coupling of N-Phenoxyacetamides and Nonterminal Propargyl Alcohols. Org. Lett. 2018, 20, 5808-5812.
Z.-R. Li, D.-Q. Wu, J. Sun, J. Shen, Q.-H. Deng*. Metal-Free Azidoarylation of Vinylcyclopropanes for the Synthesis of N3-Containing Dihydronaphthalenes. Asian J. Org. Chem. 2018, 7, 432-438.
Q. Ye, M. Jiang*, Q.-H. Deng*, J.-T. Liu. Copper-catalyzed Intramolecular Carbotrifluoromethylation of Ene-Imines for the Construction of 3-(2,2,2-Trifluoro)ethylated 4-Amino-Chromans. Adv. Synth. Catal. 2018, 360, 1402-1406.
Q. Liu, Q. Chen, X. Leng, Q.-H. Deng*, L. Deng*. Hafnium(II) Complexes with Cyclic (Alkyl)(amino)carbene Ligation.Organometallics2018, accepted.
Z.-R. Li, X.-X. Bao, J. Sun, J. Shen, D.-Q. Wu, Y.-K. Liu, Q.-H. Deng*, F. Liu*.Iron-catalyzed trifluoromethylation of vinylcyclopropanes: facile synthesis of CF3– containing dihydronaphthalene derivatives. Org. Chem. Front. 2016, 3, 934.
T. Bleith#, Q.-H. Deng#, H. Wadepohl, L. H. Gade*. Radical Changes in Lewis Acid Catalysis: Matching Metal and Substrate. Angew. Chem. Int. Ed.2016, 55, 7852.( # Co-first Authors)
Q.-H. Deng, R. L. Melen, L. H. Gade*.Anionic Chiral Tridentate N-Donor Pincer Ligands in Asymmetric Catalysis. Acc. Chem. Res. 2014, 47, 3162.
Q.-H. Deng, Rettenmeier, C., H. Wadepohl, L. H. Gade*.Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations. Chem. Eur. J.2014, 20, 93. (Highlighted by “Synfacts2014, 398.”)
Q.-H. Deng, T. Bleith, H. Wadepohl, L. H. Gade*. Enantioselective Iron-Catalyzed Azidation of β-Ketoesters and Oxindoles. J. Am. Chem. Soc.2013, 135, 5356.
Q.-H. Deng, H. Wadepohl, L. H. Gade*. Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters. J. Am. Chem. Soc.2012, 134, 10769. (Highlighted by “Synfacts2012, 979.”)
Q.-H. Deng, H. Wadepohl, L. H. Gade*. Highly Enantioselective Copper-Catalyzed Alkylation ofβ-Ketoesters and Subsequent Cyclization to Spirolactones/Bi-spirolactones. J. Am. Chem. Soc.2012,134, 2946. (Highlighted by “Synfacts2012, 512.”)
Q.-H. Deng, H. Wadepohl, L. H. Gade*. The Synthesis of a New Class of Chiral Pincer Ligands and Their Applications in Enantioselective Catalytic Fluorinations and the Nozaki-Hiyama-Kishi Reaction. Chem. Eur. J.2011, 17, 14922.

[1]新型手性钳形协同配体的合成及其在不对称催化中的应用研究，2015-2017。
[2]新型配体设计及其金属有机化学，上海高校特聘教授岗位计划，2015- 2019。
[3]新型手性协同配体的设计及其在仿生催化中的应用研究，上海市人才发展资金，2016-2018。
[4]手性钳形协同配体在不对称氢转移反应中的应用和机理研究，2016-2019。
[5]新型协同配体在不对称催化中的应用研究， 2017- 2019。
[6]基于二吡咯亚甲基骨架的NNNN型手性光敏配体的合成及其在不对称光致氧气氧化反应中的应用研究，国家自然科学基金面上项目，2018-2021。