精细化工

烯酰胺类化合物的区域及立体选择性碳-氢官能化转化，廉价过渡金属催化的碳-碳成键反应，光催化的环境友好型自由基反应等领域的

1. Guo, J.-Y.; Zhang, Z.-Y.; Guan, T.; Mao, L.-W.; Ban, Q.; Zhao, K.*; Loh, T.-P.* Photoredox-Catalyzed Stereoselective Alkylation of Enamides with N-Hydroxyphthalimide Esters via Decarboxylative Cross-Coupling Reactions. Chem. Sci. 2019, 10, 8792−8798. (影响因子 9.825; SCI一区)
2. Zhao, K.; Shen, L.; Shen, Z.-L.*; Loh, T.-P.* Transition Metal-Catalyzed Cross-Coupling Reactions Using Organoindium Reagents. Chem. Soc. Rev. 2017, 46, 586−602. (封面论文，影响因子 54.564; SCI一区)
3. Guan, T.; Guo, J.-Y.; Zhang, Q.-H.; Xu, X.-W.; Yu, X.-Y.; Zhang, Y.; Zhao, K.* Photoredox-Catalyzed Regio- & Stereoselective C(sp2)–H Cyanoalkylation of Enamides with Cycloketone Oximes via Selective C–C Bond Cleavage/Radical Addition Cascade. Green Chem. 2022, 24, 6524−6530. (影响因子 11.034; SCI一区)
4. Tao, J.-Y.; Wang, Y.-X.; Zhang, Q.-H.; Ni, K.; Zhu, T.-H.; Zhao, K.* Transition-Metal-Free Regioselective and Stereoselective C(sp2)-C(sp3) Coupling of Enamides with Ethers or Alkanes via Photoredox-Catalyzed Cross-Dehydrogenative Coupling Reactions. Green Chem. 2022, 24, 4004−4011. (影响因子 11.034; SCI一区)
5. Zhao, K.*; Zhang, X.-C.; Tao, J-Y.; Wu, X.-D.; Wu, J.-X.; Li, W.-M.; Zhu, T.-H.*; Loh, T.-P.* Regio- and Stereoselective C(sp2)–H Acylation of Enamides with Aldehydes via Transition-Metal Free Photoredox Catalysis. Green Chem. 2020, 22, 5497−5503. (影响因子 11.034; SCI一区)
6. Zhao, Q.; Zhang, Q.; Wu, X.; Wang, L.; Shen, K.; Hua, Y.; Gao, C.; Zhang, Y.; Peng, M.; Zhao, K.* Visible-light-induced ring-opening cross-coupling of cycloalcohols with vinylazaarenes and enones via β-C-C scission enabled by proton-coupled electron transfer. Chin. Chem. Lett. 2024, doi: 10.1016/j.cclet.2024.110167 (影响因子 9.40; SCI一区)
7. Qin, Z.-B.; Ni, K.; Wang, L.; Wu, X.-D.; Zhang, Y.; Zhao, K.* Photoredox-catalyzed metal-free regio- & stereoselective C(sp2)‒H amination of enamides with N-aminopyridium salts. Chin. J. Chem. 2024, 42, 2235−2242. (影响因子 5.40; SCI一区)
8. Zhao, K.*; Zhang, Z.-Y.; Cui, X.-L.; Wang, Y.-X.; Wu, X.-D.; Li, W.-M.; Wu, J.-X.; Zhao, L.-L.*; Guo, J.-Y.*; Loh, T.-P.* Visible-Light-Induced Regio- and Stereoselective C(sp2)−H Trifluoroethylation of Enamides with 2,2,2-Trifluoroethyl Iodide. Org. Lett. 2020, 22, 9029−9035. (影响因子 6.091; SCI一区)
9. Guo, J.-Y.; Guan, T.; Tao, J.-Y.; Zhao, K.*; Loh, T.-P.* Stereoselective C(sp2)–H Alkylation of Enamides with Unactivated Aliphatic Carboxylic Acids via Decarboxylative Cross-Coupling Reactions. Org. Lett. 2019, 21, 8395−8399. (影响因子 6.555; SCI一区)
10. Zhu, T.-H.; Zhang, Z.-Y.; Tao, J.-Y.; Zhao, K.*; Loh, T.-P.* Regioselective and Stereoselective Difluoromethylation of Enamides with Difluoromethyltriphenyl-phosphonium Bromide via Photoredox Catalysis. Org. Lett. 2019, 21, 6155−6159. (影响因子 6.555; SCI一区)
11. Zhang, Y.-H.; Zhang, W.-W.; Zhang, Z.-Y.; Zhao, K.*; Loh, T.-P.* Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones. Org. Lett. 2019, 21, 5101−5105. (影响因子 6.555; SCI一区)
12. Tao, J.-Y.; Zhang, Q.-H.; Zhu, T.-H.; Xu, X.-W.; Ni, K.; Zhao, Q.; Qin, Z.-B.; Zhang, Y.; Zhao, L.; Zhao, K.* Visible-Light-Initiated Regio and Stereoselective C(sp2)–H Phosphorylation of Enamides under Transition-Metal-Free Conditions. Org. Chem. Front. 2022, 9, 6540−6546. (影响因子 5.456; SCI一区)
13. Zhao, K.*; Guo, J.-Y.*; Guan, T.; Wang, Y.-X.; Tao, J.-Y.; Zhang, Y.; Zhang, Q.-H.; Ni, K.; Loh, T.-P.* Photoinitiated Stereoselective Direct C(sp2)–H Perfluoroalkylation and Difluoroacetylation of Enamides. Org. Chem. Front. 2021, 8, 4086−4094. (影响因子 5.456; SCI一区)
14. Zhu, T.-H.; Zhang, X.-C.; Zhao, K.*, Loh, T.-P.* Cu(OTf)2-Mediated C(sp2)–H Arylsulfonylation of Enamides via the Insertion of Sulfur Dioxide. Org. Chem. Front. 2019, 6, 94−98. (影响因子 5.456; SCI一区)
15. Zhu, T.-H.; Zhang, X.-C.; Zhao, K.*, Loh, T.-P.* Direct C(sp2)−H Arylsulfonylation of Enamides via iridium(III)-Catalyzed Insertion of Sulfur Dioxide with Aryldiazonium Tetrafluoroborates. Adv. Syn. & Catal. 2019, 361, 3593−3598. (影响因子 5.837; SCI一区)
16. Zhao, K.; Loh, T.-P.*, Asymmetric Conjugate Addition of Grignard Reagents to 3-silyl Unsaturated Esters for the Facile Preparation of Enantioenriched β-Silylcarbonyl Compounds and Allylic Silanes, Chem. Eur. J. 2014, 20, 16764−16772. (影响因子 5.731; SCI二区)