新材料,储能

（1） 二次(锂/钠/钾/锌)离子电池
（2）固态电池
（3）原位透射电镜与谱学表征

1. “Advances in the rational design of flexible Zn-Air batteries: Recent developments and future perspectives”, Prog. Mater. Sci., 2026, 159, 101657
2. “Stress-Adaptive Conductive Network and Ion-Segregated Polymeric-Inorganic Interphases Enable Durable Room-Temperature Silicon-Based Solid-State Batteries”, Nat. Commun., 2026, In press.
3. “Single-Atom Engineering for Synergistic Nucleation and Interfacial Regulation Enabling Durable Anode-Free Sodium Metal Batteries”, Adv. Mater., 2026, 38,e13154
4. “Synergistic structural and defect engineering in MoS2 featuring ultra-expanded interlayers for fast-chargeable and long-durable sodium-ion batteries”, Adv. Mater., 2026, 38,e17606
5. “Flash Joule Heating-Induced Spinel-Phase Surface in Ni-Rich Layered Oxide Positive Electrodes to Stabilise Lattice Oxygen”, Nat. Commun., 2026, 17, 4008.
6. “Multi-Level Design and Irreversible Ion Exchange Involved Sodium-Storage Mechanism of Zero-Strain K2Ti6O13 Toward Sodium-Ion Capacitors”, Adv. Energy Mater., 2026, e70969
7. “Multiscale Kinetics-Enhanced and Interphase-Stabilized Hierarchical Architecture Design Enables Fast-Charging and Longevous Sodium-Ion Batteries”, Adv. Energy Mater., 2026, e71059
8. “Competitive Occupation Induced Grain Boundary Enrichment Enables Crack-Free Layered Cathode Materials for Sodium-Ion Batteries”, ACS Energy Lett., 2026, In press.
9. “Comprehensive crystallographic engineering for high-efficiency and durable zinc metal anodes”, Prog. Mater. Sci., 2025, 152, 101453
10. “Biomimetic Sandwich-Structured Tubular Ion Pump Arrays for Lithium Metal Batteries”, J. Am. Chem. Soc., 2025, 147, 25883−25895.
11. “Mechanically robust bismuth embedded carbon microspheres for ultra-fast charging and ultra-stable sodium ion batteries”, J. Am. Chem. Soc., 2025, 147, 3047−3061
12. “Converting layered LiCoO2 into disordered rocksalt coating material to enhance interfacial stability of high-voltage cathode”, Angew. Chem. Int. Ed., 2025, 64, e202512300
13. “High-Performance Silicon Anodes Enabled by Multifunctional Ultrafine Silica Nanoparticle-Embedded Carbon Coatings for Lithium-Ion Batteries”, Adv. Energy Mater., 2025, 15, 2500189
14. “Sandwich-Structured Lithiophilic Layer with Mixed Ionic−Electronic Conductivity for Lithium Metal Batteries”, ACS Energy Lett., 2025, 10, 5972−5981
15. “Regulating Interfacial Chemistry to Boost Ionic Transport and Interface Stability of Composite Solid-State Electrolytes for High-Performance Solid-State Lithium Metal Batteries”, Adv. Funct. Mater., 2025, 35, 2422147
16. “Biomimetics-Driven Design of Micron-Sized SiO Composites for High-Performance Lithium-Ion Batteries”, Adv. Funct. Mater., 2025, 35, 2422743
17. “Unlocking the multidimensional application and optimization mechanism of MOFs materials in aqueous zinc ion batteries”, J. Energy. Chem., 2025, 111, 249-273
18. “Single-Crystallization of O3-Type Layered Oxide Cathode for Na-Ion Battery,” Chem. Mater., 2025, 37, 5874–5883
19. “Wide-temperature solid polymer electrolytes: Li+ coordination structure, ionic transport and interphases,” Mater. Horiz., 2025, 12, 3201-3233
20. “Facile and scalable synthesis of bismuth oxyhalide nanosheets anodes for fast and durable sodium-ion storage”, Sci. China Mater., 2025, 68, 868 – 878
21. “Effective binding sufficiently-small SiO2 nanoparticles within carbon nanosheets framework enables a high-performing and durable anode for lithium-ion batteries”, Journal of Materiomics, 2025, 11, 101053
22. “High-entropy Doping Promising Ultrahigh-Ni Co-Free Single-crystalline Cathode toward Commercializable High-energy Lithium-ion Batteries”, Sci. Adv., 2024, 10, eado4472.
23. “Self-assembled hydrated copper coordination compounds as ionic conductors for room temperature solid-state batteries” , Nat. Commun., 2024, 15, 1056
24. “The Origin, Characterization, and Precise Design and Regulation of Diverse Hard Carbon Structures for Targeted Applications in Lithium/Sodium/Potassium Ion Batteries”, Electrochem. Energy Rev., 2024, 7, 34.
25. “Mechanistic Understanding of the Underlying Energy Storage Mechanism of α-MnO2-based Pseudo-Supercapacitors”, Adv. Mater., 2024, 36, 2408476
26. “Simultaneous Catalytic Acceleration of White Phosphorus Polymerization and Red Phosphorus Potassiation for High ‐Performance Potassium-Ion Batteries”, Adv. Mater., 2024, 36, 2306512
27. “Achieving High-Capacity Cathode Presodiation Agent via Triggering Anionic Oxidation Activity in Sodium Oxide”, Adv. Mater., 2024, 36, 2407720
28. “Engineering Covalent Organic Frameworks toward Advanced Zinc–based Batteries”, Adv. Mater., 2024, 36, 2313152
29. “Tailoring Desolvation Strategies for Aqueous Zinc-Ion Batteries”, Energy Environ. Sci., 2024, 17, 4819-4846.
30. “Hard carbon with an opened pore structure for enhanced sodium storage performance”, Energy Environ. Sci., 2024,17, 8189-8197.
31. “Resolving the Origins of Superior Cycling Performance of Antimony Anode in Sodium-ion Batteries: A Comparison with Lithium-ion Batteries”, Angew. Chem. Int. Ed., 2024, 63, e202320183
32. “Electrostatic Shielding Engineering for Stable Zn Metal Anodes”, Adv. Energy. Mater., 2024, 15, 2403958
33. “Long-Durable Potassium Ion Batteries Enabled by Medium-Entropy Lattice Engineering on Prussian Blue Analogues Cathodes”, Adv. Energy. Mater., 2024, 15, 2405007
34. “Electrochemical processes and reactions in rechargeable battery materials revealed via in situ transmission electron microscopy”, Adv. Energy. Mater., 2024, 14, 2303165
35. “Enhanced Fast-Charging and Longevity in Sodium-Ion Batteries through Nitrogen-Doped Carbon Frameworks Encasing Flower-Like Bismuth Microspheres”, Adv. Energy. Mater., 2024, 14, 2400132
36. “Three birds with one stone: multifunctional separators based on SnSe nanosheets enable high-performance Li-, Na- and K-sulfur batteries”, Adv. Energy. Mater., 2024, 14, 2303551
37. “Multiscale Micro-Nano Hierarchical Porous Germanium with Self-Adaptive Stress Dispersion for Highly Robust Lithium-Ion Batteries Anode”, Adv. Energy. Mater., 2024, 14, 2303876
38. “Machine Learning-Assisted Property Prediction of Solid-State Electrolyte”, Adv. Energy. Mater., 2024, 14, 2304480
39. “Fluorine doping modulating pore structure and adsorption capability of carbon matrix boosting potassium storage performance of red phosphorus anode”, Adv. Funct. Mater., 2024, 34, 2409090
40. “Unlocking the Origins of Highly Reversible Lithium Storage and Stable Cycling in a Spinel High-Entropy Oxide Anode for Lithium-Ion Batteries”, Adv. Funct. Mater., 2024, 34, 2307923
41. “Three birds with one arrow: Multifunctional single-atom catalysts enableefficient lithium-sulfur batteries”, Energy Storage Mater., 2024, 66, 103240
42. “Manipulating charge-transfer kinetics and flow-domain LiF-rich interphase to enable high-performance microsized silicon-silver-carbon composite anode for solid-statebatteries”, Energy Environ. Sci., 2023,16, 5395-5408
43. “Enabling highly-efficient and stable potassium-ion storage by exposing atomic-dispersed super-coordinated antimony O2Sb1N4 sites on N-doped carbon nanosheets”, Energy Environ. Sci., 2023,16, 2153-2166
44. “Deciphering Structural Origins of Highly Reversible Lithium Storage in High Entropy Oxides with In Situ Transmission Electron Microscopy”, Adv. Mater., 2023, 35, 2205751
45. “Surface and lattice engineered ruthenium superstructures towards high-performance bifunctional hydrogen catalysis,” Energy Environ. Sci., 2023, 16, 157–166
46. “Fast and Long-Lasting Potassium-Ion Storage Enabled by Rationally Engineering Strain-Relaxation Bi/Bi 2O3 Nanodots Embedded in Carbon Sheets”, Adv. Funct. Mater., 2023, 33, 2307205
47. “In Situ Atomic-Scale Deciphering of Multiple Dynamic Phase Transformations and Reversible Sodium Storage in Ternary Metal Sulfide Anode”, ACS Nano, 2023, 17, 12483–12498
48. “A General Route for Encapsulating Monodispersed Transition Metal Phosphides into Carbon Multi-Chambers toward High-Efficient Lithium-Ion Storage with Underlying Mechanism Exploration,”Adv. Funct. Mater., 2023, 33, 2212100
49. “Challenges and opportunities towards silicon-based all-solid-state batteries”, Energy Storage Mater., 2023, 61, 102875
50. “Efficient implementation of kilogram-scale, high-capacity and long-life Si-C/TiO2 anodes,” Energy Storage Mater., 2023, 56, 319–330
51. “Machine Learning ‑ Assisted Low ‑ Dimensional Electrocatalysts Design for Hydrogen Evolution Reaction”, Nano-Micro Lett., 2023, 15, 227
52. “In situ atomic-scale observation of size-dependent (de)potassiation and reversible phase transformation in tetragonal FeSe anodes”, InfoMat., 2023, 5, e12364.
53. “Ultra-thick, dense dual-encapsulated Sb anode architecture with conductively elastic networks promises potassium-ion batteries with high areal and volumetric capacities”, eScience, 2023, 3, 100177
54. “Deciphering the potassium storage phase conversion mechanism of phosphorus by combined solid-state NMR spectroscopy and density functional theory calculations,” J. Energy Chem., 2023, 79, 45–53
55. “Advances in the structure design of substrate materials for zinc anode of aqueous zinc ion batteries”, Green Energy & Environment, 2023, 8, 1531-1552
56. “Building better solid-state batteries with silicon-based anodes”, Interdisciplinary Materials, 2023, 2, 635-663
57. “Phase Engineering of a Ruthenium Nanostructure toward High-Performance Bifunctional Hydrogen Catalysis,” ACS Nano, 2022, 16, 14885–14894
58. “Unraveling Atomic-Scale Origins of Selective Ionic Transport Pathways and Sodium-Ion Storage Mechanism in Bi2S3 Anodes”, Small Methods, 2022, 6, 2200995
59. “In Situ Transmission Electron Microscopy for Understanding Materials and Interfaces Challenges in All-Solid-State Lithium Batteries,” eTransportation, 2022, 14, 100203
60. “Unveiling the Dynamic Oxidative Etching Mechanisms of Nanostructured Metals/Metallic Oxides in Liquid Media Through In Situ Transmission Electron Microscopy”, Adv. Funct. Mater.， 2022, 32, 202204976
61. “Synergistic Engineering of Heterointerface and Architecture in New-Type ZnS/Sn Heterostructures In Situ Encapsulated in Nitrogen-Doped Carbon Toward High-Efficient Lithium Ion Storage”, Adv. Funct. Mater., 2022, 32, 2205635
62. “Enabling robust structural and interfacial stability of micron-Si anode toward high-performance liquid and solid-state lithium-ion batteries”, Energy Storage Mater., 2022, 52, 547–561
63. “Electrolyte additive engineering for aqueous Zn ion batteries”, Energy Storage Mater., 2022, 51, 733-755
64. “A Review on 3D Zinc Anodes for Zinc Ion Batteries”, Small Methods, 2022, 2200597
65. “Boosting the potassium-ion storage performance enabled by engineering of hierarchical MoSSe nanosheets modified with carbon on porous carbon sphere”, Science Bulletin, 2022, 67, 933-945
66. “Polymer-/ceramic-based dielectric composites for energy storage and conversion”, Energy & Environmental Mater., 2022, 5, 486–514
67. “Understanding the growth mechanisms of metal-based core–shell nanostructures revealed by in situ liquid cell transmission electron microscopy”, J. Energy Chem., 2022, 71, 370-383
68. “B-doped and La4NiLiO8-coated Ni-rich cathode with enhanced structural and interfacial stability for lithium-ion batteries”, J. Energy Chem., 2022, 71, 588-594
69. “Atomic mechanisms of hexagonal close-packed Ni nanocrystallization revealed by in situ liquid cell transmission electron microscopy”, Nano Research, 2022, 15, 6772–6778
70. “Shining light on transition metal tungstate-based nanomaterials for electrochemical applications: Structures, progress, and perspectives”, Nano Research, 2022, 15, 6924–6960
71. “Scalable Synthesis of Pore-Rich Si/C@C Core−Shell-Structured Microspheres for Practical Long-Life Lithium-Ion Battery Anodes”, ACS Appl. Mater. Interfaces, 2022,14, 10308–10318
72. “Lithiophilic N-doped carbon bowls induced Li deposition in layered graphene film for advanced lithium metal batteries”, Nano Research, 2022, 15, 352–360
73. “Research Progresses on Structural Optimization and Interfacial Modification of Silicon Monoxide Anode for Lithium-Ion Battery”, Acta Phys. -Chim. Sin., 2022, 38, 2103052.
74. “Harnessing the Volume Expansion of MoS3 Anode by Structure Engineering to Achieve High Performance Beyond Lithium-Based Rechargeable Batteries”, Adv. Mater., 2021,33, 2106232
75. “An Efficient Strategy toward Multichambered Carbon Nanoboxes with Multiple Spatial Confinement for Advanced Sodium–Sulfur Batteries,” ACS Nano, 2021, 15, 20607–20618
76. “Understanding all solid-state lithium batteries through in situ transmission electron microscopy”, Mater. Today, 2021, 42, 137-161
77. “Fast and Durable Potassium Storage Enabled by Constructing Stress-Dispersed Co3Se4 Nanocrystallites Anchored on Graphene Sheets”, ACS Nano, 2021, 15, 10107–10118
78. “Design principles and direct applications of cobalt-based metal organic frameworks for electrochemical energy storage”, Coord. Chem. Rev., 2021, 438, 213872.
79. “Designing and Understanding the Superior Potassium Storage Performance of Nitrogen/Phosphorus Co-Doped Hollow Porous Bowl-Like Carbon Anodes”, Adv. Funct. Mater., 2021, 31, 2007158
80. “Stable Hollow-Structured Silicon Suboxide-Based Anodes toward High-Performance Lithium-Ion Batteries”, Adv. Funct. Mater., 2021, 31, 2101796
81. “A Self-Healing Volume Variation Three-Dimensional Continuous Bulk Porous Bismuth for Ultrafast Sodium Storage”, Adv. Funct. Mater., 2021, 31, 2011264
82. “Confining invasion directions of Li+ to achieve efficient Si anode material for lithium-ion batteries”, Energy Storage Mater., 2021, 42, 231-239
83. “N-doped porous carbon nanofibers sheathed pumpkin-like Si/C composites as free-standing anodes for lithium-ion batteries”, J Energy Chem, 2021, 54, 727-735
84. “LiPO2F2 electrolyte additive for high-performance Li-rich cathode material”, J Energy Chem, 2021, 60, 564-571
85. “Rational design of three-dimensional branched NiCo-P@CoNiMo-P core/shell nanowire heterostructures for high-performance hybrid supercapacitor”, J Energy Chem, 2021, 61, 489-496
86. “Leaf-inspired design of mesoporous Sb2S3/N-doped Ti3C2Tx composite towards fast sodium storage”, Sci. China Chem., 2021, 64, 964–973
87. “Boosting lithium storage performance of Si nanoparticles via thin carbon and nitrogen/phosphorus co-doped two-dimensional carbon sheet dual encapsulation”, Rare Metals, 2021, 40, 1347–1356.
88. “Application of in-situ characterization techniques in all-solid-state lithium batteries”, Acta Phys. Sin., 2021, 70, 198102
89. “Influencing Factors and Promotion Strategies of the First-cycle Coulombic Efficiency of Silicon Suboxide Anodes in Lithium-ion Batteries”, Chem. J. Chinese Universities, 2021, 42, 2342-2358.
90. “Research Progress of Anode Materials for Zinc-Based Aqueous Battery in a Neutral or Weak Acid System”, Progress in Chemistry, 2021, 11, 1983-2001
91. “Research progress in understanding of lithium storage behavior and reaction mechanism of electrode materials through in situ transmission electron microscopy”, Energy Storage Science and Technology, 2021, 10，1219-1236
中文文章：
1. 张佳明，施博扬，林炜琦，夏佳浩，何 桐，怡 勇，李 永*，张桥保*，“超高能量密度锂金属电池电解液研究进展”，储能科学与技术，2026, doi：10.19799/j.cnki.2095-4239.2025.0975.
2. 张桥保, 龚正良*, 杨勇*，“硫化物固态电解质材料界面及其表征的研究进展”，物理学报，2020, 69(22): 228803. doi: 10.7498/aps.69.20201581 (入选物理学报2022年度最有影响论文)
3.陆敬予, 柯承志, 龚正良, 李德平*, 慈立杰*, 张力, 张桥保*，“原位表征技术在全固态锂电池中的应用”，物理学报，2021, 70(19): 198102, doi: 10.7498/aps.70.20210531 (入选物理学报2023年度高被引论文)
4.柯承志, 肖本胜, 李苗, 陆敬予, 何洋, 张力, 张桥保*, “电极材料储锂行为及其机制的原位透射电镜研究进展”， 储能科学与技术, 2021, 10(4): 1219-1236.
5.朱思颖, 李辉阳, 胡忠利, 张桥保*, 赵金保, 张力* “锂离子电池氧化亚硅负极结构优化和界面改性研究进展”，物理化学学报， 2022, 38(6): 2103052.
6.李辉阳, 朱思颖, 李莎, 张桥保*, 赵金保, 张力*，“锂离子电池硅氧化物负极首次库伦效率的影响因素与提升策略”，高等学校化学学报, 2021, 42(8): 2342.
7.王华燕, 陈慧鑫*, 张桥保*, 张力，“生物质碳材料作为钠/钾离子电池负极材料的研究进展”，中国材料进展, 2021, 40(08):596-606. doi:10.7502/j.issn.1674-3962.202106013
书籍：
1. 张桥保，吴贤文，陆敬予，伊廷锋；“电池材料——合成，表征与应用”，北京：化学工业出版社，2022，https://cip.com.cn/Book/Index/49252。获中国石油和化学工业优秀出版物奖•图书奖二等奖。
2. 张桥保，柯小行，唐永福；“能源材料的原位透射电子显微分析”，北京：化学工业出版社，2026，待出版。
3. 张桥保；“固态电池基础科学和产业实践”，北京：化学工业出版社，2026，待出版。