精细化工

绿色催化反应过程与工艺，(1)从源头上解决化工过程安全的催化反应技术与工艺；(2)化工过程强化及工程放大技术。

[1] Shanshan Zhao, Zhengxiang Ma, Xiaoshu Ding, Qiusheng Yang, Yanji Wang, Xinqiang Zhao, Dongsheng Zhang*. Vinyl Silane Modified Silica-Grafted Sulfonic Acid Based Polymeric Ionic Liquids for Efficient Catalytic Hydrolysis of Cyclohexanone Oxime[J]. Industrial Engineering Chemistry Research, 2022, 61, 50, 18588-18600.
[2]  Shanshan Zhao, Zhengxiang Ma, Peng Cheng, Yanji Wang, Xinqiang Zhao, Qiusheng Yang, Junqi Zhang, Dongsheng Zhang*. Mesoporous acidic polymeric ionic liquids as novel solid acids for catalytic hydrolysis of ketoxime reactions[J]. RSC Advances, 2022, 12(51): 33276-33283.
[3] Jiali Zheng, Zhihui Li, Dongsheng Zhang*, Qiusheng Yang, Xinqiang Zhao, Baoquan Zhang, Yanji Wang, Thermal decomposition behavior, thermal stability and thermalexplosion risk evaluation of a novel green hydroxylamine ionic liquid salt, Journal of Molecular Liquids, 2022, 348: 118407.
[4] Shuangyu Wang, Jiaqi Liu, Peng Cheng, Zhihui Li, Dongsheng Zhang,*Qiusheng Yang, Xinqiang Zhao, Yanji Wang, Application of an immobilized ionic liquid for the preparation of hydroxylamine via hydrolysis of cyclohexanone oxime, Zeitschrift Fur Anorganische Und Allgemeine Chemie. 2021, 647, 742-750.
[5] Xiaoliang Ren, Shufang Wang, Xiaoshu Ding, Dongsheng Zhang*, Yanji Wan, Preparation and catalytic performance of active metal sintered membrane reactor anchored with Pt atoms. RSC Advances, 2021, 11, 2848-2853.
[6] Aina Yang, Tong Wang, Zhihui Li, Yuanyuan Xu, Liya Gao, Dongsheng Zhang*, Shufang Wang, Xinqiang Zhao, Yanji Wang*. One-step synthesis of cyclohexylamine from benzene, hydroxylamine and hydrogen over vanadium and ruthenium catalysts. Research on Chemical Intermediates, 2018, 44(1): 339-354.
[7] Zhihui Li, Xudong Qi, Liya Gao, Yuanyuan Xu, Dongsheng Zhang*, Shufang Wang, Xinqiang Zhao, Yanji Wang*. Application of hydroxylamine ionic liquid salts in hydroxylation of benzene to phenol with ammonium molybdate-copper chloride-ionic liquid system. Chemistry Letters, 2017, 46(3): 289-292.
[8] Yuanyuan Xu, Qiusheng Yang, Zhihui Li, Liya Gao, Dongsheng Zhang*, Shufang Wang, Xinqiang Zhao, Yanji Wang*. Ammoximation of cyclohexanone to cyclohexanone oxime using ammonium chloride as nitrogen source. Chemical Engineering Science, 2016, 152: 717-723.
[9] Zhihui Li, Qiusheng Yang, Xudong Qi, Yuanyuan Xu, Dongsheng Zhang*, Yanji Wang*, Xinqiang Zhao. A novel hydroxylamine ionic liquid salt resulting from the stabilization of NH2OH by a SO3H-functionalized ionic liquid. Chemical Communications, 2015, 51(10): 1930-1932.
[10] Yuanyuan Xu, Zhihui Li, Liya Gao, Dongsheng Zhang*, Xinqiang Zhao, Shufang Wang, Yanji Wang*. An integrated process for the synthesis of solid hydroxylamine salt with ammonia and hydrogen peroxide as raw materials. Industrial and Engineering Chemistry Research, 2015, 54 (3): 1068-1073.

[1] 张东升, 赵山山, 王双瑜, 等. 一种交联酸性聚合离子液体催化环己酮肟制备羟胺的方法: CN114477112A[P], 2022-05-13.
[2] 张东升, 赵山山, 卢遥, 等. 一种乙烯基改性二氧化硅接枝酸性聚合离子液体催化环己酮肟水解制备羟胺的方法: CN115092897A[P], 2022-09-23.
[3] 张东升, 王晓曼, 王延吉, 等. 一种由环己酮肟水解制备羟胺的方法: CN107265420A [P], 2017-10-20.

1. 国家自然科学基金项目（21878069），纳米多孔SiO2限域酸功能化离子液体催化酮肟水解制备羟胺的基础研究，主持；
2. 国家自然科学基金项目（21646015），基于功能化离子液体羟胺盐的己内酰胺直接合成反应过程研究，主持；
3. 国家自然科学基金项目（21106029），酸性离子液体中甲苯直接羟基化合成甲基苯酚的反应过程研究，主持；
4. 天津市自然科学基金项目（12JCQNJC03000），酸性离子液中芳烃直接羟基化合成相应酚类化合物的反应，主持；
5. 河北省自然科学基金项目（B2016202335），借助功能化羟胺盐构建由酮一步合成内酰胺类化合物的反应过程，主持；
6. 河北省自然科学基金项目（B2012202043），酸性离子液体中甲苯与羟胺盐一步合成甲基苯酚的反应工艺研究，主持；
7. 河北省高等教育教学改革研究项目（2020GJJG026），以提升学生工程实践及创新能力的化工工艺专业教学体系改革研究，主持；
8. 教育部产学合作协同育人项目（220605588225547），基于VR/AR技术的合成氨虚拟仿真实训基地建设，主持；

技术咨询