精细化工

金属有机化学。近年来主要对三齿配位钳形金属化合物的设计、合成、光致发光和催化性能及其相关应用进行了研究，同时也开展了一些导向基包括手性导向基辅助的、过渡金属催化C-H键官能团化反应研究。

1. Ya-Ping Pan, Nan Li, Jing-Jing Yang, Zhi-Wu Zhu,Jun-Fang Gong*, Mao-Ping Song. “Facile synthesis of NC(sp3)O pincer palladium complexes and their use as efficient catalysts for Suzuki-Miyaura reaction of aryl bromides in aqueous medium.”J. Organomet. Chem.2021,932, 121645.
2. Yang Li,Jun-Fang Gong*, Mao-Ping Song*. “Palladium-catalyzed δ-selective reductive Heck reaction of alkenyl carbonyl compounds with aryl iodides and bromides.”Org. Chem. Front.2020,7(16), 2216-2223.
3. Wen-Jing Zhu,Jun-Fang Gong*, Mao-Ping Song*.“Synthesis of Chiral Bis(3-indolyl)methanes Bearing aTrifluoromethylated All-Carbon Quaternary Stereocenter via Nickel-Catalyzed Asymmetric Friedel−Crafts Alkylation Reaction.”J. Org. Chem.2020,85(15), 9525-9537.
4. Nan Li, Wen-Jing Zhu, Juan-Juan Huang, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Iridium(III) Complexes withBis(imidazolinyl)phenyl Ligands: Synthesis and Application inEnantioselective C-H Functionalization of Indoles with α-Aryl-α-diazoacetates.”Organometallics2020,39(12), 2222-2234.
5. Cong Wang, Nan Li, Wen-Jing Zhu,Jun-Fang Gong*, Mao-Ping Song*.“Asymmetric Michael Addition of 2-Acetyl Azaarenes to β-CF3-β-(3-indolyl)nitroalkenes Catalyzed by a Cobalt(II)/(imidazoline-oxazoline) Complex.”J. Org. Chem.2019,84(1), 191-203.
6. Invited review:Jin-Kui Liu,Jun-Fang Gong*, Mao-Ping Song*.“Chiral palladium pincer complexes for asymmetric catalytic reactions.”Org. Biomol. Chem.2019,17(25),6069-6098.(封面文章)
7. Jun-Ru Guo,Jun-Fang Gong*, Mao-Ping Song*.“Nickel(II)-catalyzed C(sp2)–H sulfuration/annulation with elemental sulfur: selectiveaccess to benzoisothiazolones.”Org. Biomol. Chem.2019,17(20),5029-5037.
8. Cong Wang, Yang Li, Beibei Lu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “(Phosphinito)aryl benzimidazole PCN pincer palladium(II) complexes: Synthesis, characterization and catalytic activity in C-H arylation of azoles with aryl iodides.”Polyhedron2018,143,184-192.
9. Shuang-Liang Liu, Yang Li, Jun-Ru Guo, Guang-Chao Yang, Xue-Hong Li,Jun-Fang Gong*, Mao-Ping Song*. “An Approach to 3-(Indol-2-yl)succinimide Derivatives by Manganese-Catalyzed C-H Activation.”Org. Lett.2017,19(15),4042-4045.
10. Shuang-Liang Liu, Xue-Hong Li, Shu-Sheng Zhang, Sheng-Kai Hou, Guang-Chao Yang,Jun-Fang Gong*, Mao-Ping Song*. “Nickel-Catalyzed Sulfonylation of C(sp2)-H Bonds with Sodium Sulfinates.”Adv. Synth. Catal.2017,359(13), 2241-2246.
11. Xin-Qi Hao, Cong Wang, Shuang-Liang Liu, Xiao Wang, Li Wang,Jun-Fang Gong*, Mao-Ping Song*. “Cobalt(II)/(imidazoline-oxazoline)-catalyzed enantioselective Michael addition of 2-acetyl azaarenes to β-CF3-β-disubstituted nitroalkenes.”Org. Chem. Front.2017,4(2), 308-312.
12. Shuang-Liang Liu, Xue-Hong Li, Tan-Hao Shi, Guang-Chao Yang, Hai-Li Wang,Jun-Fang Gong*, Mao-Ping Song*.“Copper-Promoted Thiolation of C(sp2)–H Bonds Using a 2-Amino Alkylbenzimidazole Directing Group.”Eur. J. Org. Chem.2017,2017(16), 2280-2289.
13. Xin-Qi Hao, Juan-Juan Huang, Tao Wang, Jing Lv,Jun-Fang Gong*, Mao-Ping Song*.“PCN Pincer Palladium(II) Complex Catalyzed Enantioselective Hydrophosphination of Enones: Synthesis of Pyridine-Functionalized Chiral Phosphine Oxides as NCsp3O Pincer Preligands.”J. Org. Chem.2014,79(20), 9512-9530.
14. Xin-Qi Hao, Yong-Wei Zhao, Jing-Jing Yang, Jun-Long Niu,Jun-Fang Gong*, Mao-Ping Song*. “Enantioselective Hydrophosphination of Enones with Diphenylphosphine Catalyzed by Bis(imidazoline) NCN Pincer Palladium(II) Complexes.”Organometallics2014,33(7), 1801-1811.
15. Zhao Wang, Zheming Sun,Xin-Qi Hao, Jun-Long Niu, Donghui Wei, Tao Tu,Jun-Fang Gong*, Mao-Ping Song*.“Neutral and Cationic NCN Pincer Platinum(II) Complexes with 1,3-Bis(benzimidazol-2'-yl)benzene Ligands: Synthesis, Structures, and Their Photophysical Properties.”Organometallics2014,33(7), 1563-1573.
16. Tao Wang, Xin-Qi Hao, Juan-Juan Huang, Kai Wang,Jun-Fang Gong*, Mao-Ping Song*. “Chiral CNN Pincer Palladium(II) Complexes with 2-Aryl-6-(Oxazolinyl)pyridine Ligands: Synthesis, Characterization, and Application to Enantioselective Allylation of Isatins and Suzuki-Miyaura Coupling Reaction.”Organometallics2014,33(1), 194-205.
17. Tao Wang, Xin-Qi Hao, Juan-Juan Huang, Jun-Long Niu,Jun-Fang Gong*, Mao-Ping Song*. “Chiral Bis(imidazolinyl)phenyl NCN Pincer Rhodium(III) Catalysts for Enantioselective Allylation of Aldehydes and Carbonyl-Ene Reactionof Trifluoropyruvates.”J. Org. Chem.2013,78(17), 8712-8721.
18. Tao Wang, Jun-Long Niu, Shuang-Liang Liu, Juan-Juan Huang,Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Rhodium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Enantioselective Catalytic Alkynylation of Trifluoropyruvates with Terminal Alkynes.”Adv. Synth. Catal.2013,355(5), 927-937. (Highlighted bySynfacts2013, 9(6), 0636)
19. 研究专题：郝新奇,牛俊龙,赵雪梅,龚军芳*,宋毛平*. “第VIII族钳形金属催化剂的研究进展.”有机化学2013,33(4), 663-674.
20. Xin-Qi Hao, Yan-Xiao Xu, Ming-Jun Yang, Li Wang, Jun-Long Niu,Jun-Fang Gong*, Mao-Ping Song*. “A Cationic NCN Pincer Platinum(II) Aquo Complex with a Bis(imidazolinyl) phenyl Ligand: Studies toward its Synthesis and Asymmetric Friedel−Crafts Alkylation of Indoles with Nitroalkenes.”Organometallics2012,31(3), 835-846.
21. Ming-Jun Yang, Yan-Jing Liu,Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes with Aryl-Based Aminophosphine-Imidazoline Ligands: Synthesis via Aryl C-H Activation, and Asymmetric Addition of Diarylphosphines to Enones.”Organometallics2011,30(14), 3793-3803.
22. Invited Perspective:Jun-Long Niu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Symmetrical and unsymmetrical pincer complexes with group 10 metals: Synthesis via aryl C–H activation and some catalytic applications.”DaltonTrans.2011,40(19), 5135-5150.
23. Tao Wang, Xin-Qi Hao, Xiao-Xue Zhang,Jun-Fang Gong*, Mao-Ping Song*. “Synthesis, structure and catalytic properties of CNN pincer palladium(II) and ruthenium(II) complexes with N-substituted-2-aminomethyl-6-phenyl pyridines.”DaltonTrans.2011,40(35), 8964-8976. (封面文章)
24. Dan-Dan Shao, Jun-Long Niu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Neutral and cationic chiral NCN pincer nickel(II) complexes with 1,3-bis(2'-imidazolinyl) benzenes: synthesis and characterization.”DaltonTrans.2011,40(35), 9012-9019.
25. Ben-Shang Zhang, Wei Wang, Dan-Dan Shao, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C-H Activation, Crystal Structures and Catalytic Studies.”Organometallics2010,29(11), 2579-2587.
26. Jun-Long Niu, Qing-Tao Chen, Xin-Qi Hao, Qing-Xiang Zhao,Jun-Fang Gong*, Mao-Ping Song*. “Diphenylprolinol-derived Symmetrical and Unsymmetrical Chiral Pincer Palladium(II) and Nickel(II) Complexes: Synthesis via One-Pot Phosphorylation/metalation Reaction and C-H Activation.”Organometallics2010,29(9), 2148-2156.
27. Li-Yuan Wu, Xin-Qi Hao, Yan-Xiao Xu, Min-Qiang Jia, Ya-Nan Wang,Jun-Fang Gong*, Mao-Ping Song*. “Chiral NCN Pincer Pt(II) and Pd(II) Complexes with 1,3-Bis(2'-imidazolinyl)benzene: Synthesis via Direct Metalation, Characterization, and Catalytic Activity in the Friedel-Crafts Alkylation Reaction.”Organometallics2009,28(12), 3369-3380.
28. Jun-Fang Gong, Yan-Hui Zhang, Mao-Ping Song*, Chen Xu. “New PCN and PCP Pincer Palladium(II) Complexes: Convenient Synthesis via Facile One-pot Phosphorylation/Palladation Reaction and Structural Characterization.”Organometallics2007,26(25), 6487-6492.
29. An-Ting Hou, Yan-Jing Liu, Xin-Qi Hao,Jun-Fang Gong*, Mao-Ping Song*. “Synthesis and Characterization of new (pyrazolyl)aryl phosphinite PCN pincer palladium(II) complexes.”J. Organomet. Chem.2011,696(15-16), 2857-2862.
30. Xin-Qi Hao, Ya-Nan Wang, Jun-Rui Liu, Kun-Lun Wang,Jun-Fang Gong*, Mao-Ping Song*. “Unsymmetrical, oxazolinyl-containing achiral and chiral NCN pincer ligand precursors and their complexes with palladium(II).”J. Organomet. Chem.2010,695(1), 82-89.
31. Ben-Shang Zhang, Chao Wang,Jun-Fang Gong*, Mao-Ping Song*. “Facile synthesis of achiral and chiral PCN pincer palladium(II) complexes and their application in the Suzuki and copper-free Sonogashira cross-coupling reactions.”J. Organomet. Chem.2009,694(16), 2555-2561.
32. Xin-Qi Hao,Jun-Fang Gong*, Chen-Xia Du, Li-Yuan Wu, Yang-Jie Wu, Mao-Ping Song*. “Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands.”Tetrahedron Lett.2006,47(29), 5033-5036.

1. 2015.01-2018.12国家自然科学基金面上项目“手性钳形铱化合物的合成、负载化及其催化不对称卡宾插入反应(21472176)
2. 2010.01-2012.12国家自然科学基金面上项目“混合给体钳形镍化合物的合成、结构及其在催化反应中的应用” (20972141)
3. 2012.01-2014.12河南省高校科技创新人才支持计划资助项目“手性钳形钯化合物催化剂的合成与应用研究” (2012HASTIT003)
4. 2010.01-2012.12河南省科技攻关重大项目“非对称三齿配位钯化合物的催化性能研究” (102101210200)
5. 2010.01-2012.12河南省高等学校青年骨干教师资助计划“含氮杂环卡宾的钯和镍化合物的合成与催化性能研究” (2010GGJS-015)