Revisiting Glycerol Esterification with Acetic Acid over Amberlyst-35 via Statistically Designed Experiments: Overcoming Transport Limitations

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Turnover rates for glycerol esterification with acetic acid over Amberlyst-35 were measured under di...
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作 者:
Víctor Gabriel Baldo...
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Aldehydes and Ketones Influence Reactivity and Selectivity in Nickel-Catalyzed Suzuki-Miyaura Reactions

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We show that the energetically-favorable coordination of aldehydes and ketones \\u2013 but not ester...
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David Nelson;Alasdai...
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Merging Chemoenzymatic and Radical-Based Retrosynthetic Logic For Rapid and Modular Synthesis of Oxidized Meroterpenoids

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We report a modular approach to access a range of oxidized meroterpenoids using a novel hybrid synth...
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作 者:
Hans Renata;Jian Li;...
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Iridium-Catalyzed Silylation of C-H bonds in Unactivated Arenes: A Sterically-Encumbered Phenanthroline Ligand Accelerates Catalysis Enabling New Reactivity

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We report a new system for the silylation of aryl C-Hbonds. The combination of [Ir(cod)(OMe)]2 and 2...
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作 者:
Caleb Karmel;Zhewei ...
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Computational Screening of Roles of Defects and Metal Substitution on Reactivity of Different Single- vs Double-Node Metal\\u2013Organic Frameworks for Sarin Decomposition

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Understanding how different factors affect the electronic prop-erties of metal-organic frameworks (M...
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作 者:
MohammadReza MomeniT...
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The Geometry of the Catalytic Active Site in [FeFe]-Hydrogenases is Determined by Hydrogen Bonding and Proton Transfer

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The H2 conversion and CO inhibition reactivity of nine [FeFe]-hydrogenase constructs with semi-artif...
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作 者:
Sven T. Stripp;Jifu ...
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Electro-Inductive Effect: Using an Electrode as a Functional Group to Control the Reactivity of Molecules with Voltage

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A new general method of controlling the chemical reactivity of molecules is proposed. Instead of tun...
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作 者:
Mu-Hyun Baik;Joon He...
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Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

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To mitigate globalproblems related to energy and global warming, it is helpful to develop anammonia ...
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作 者:
Katsutoshi Nagaoka;K...
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Mild Temperature Copper-Catalyzed Amination of Aryl Halides with Aqueous Ammonia in the Presence of Pyridyldiketone Ligands

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Ambidentate ligand pyridyldiketones were used in combination with copper to catalyze amination of ar...
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作 者:
Florian Monnier;Rach...
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Tenacious Mass Transfer Limitations Drive Catalytic Selectivity during Electrochemical Carbon Dioxide Reduction

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This study evaluated the performance of thecommonly used strong buffer electrolytes, i.e. phosphate ...
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作 者:
Recep Kas;Kailun Yan...
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