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Ground State Destabilization in Uracil DNA Deglycosylase (UDG): Let\\u2019s Not Forget \\u201cTautomeric Strain\\u201d in Substrates
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- QM and QM/MM computations reveal that some enzymes, like the uracil DNA deglycosylase, may achieve g...
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Judy Wu;Ranjita Das;...
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A Simplified Protocol for the ortho-Deuteration of Acidic Aromatic Compounds in D2O
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- Methods to catalytically introduce deuterium in synthetically useful yields ortho to a carboxylic ac...
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Michael Young;Alyssa...
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Nano-Folded Gold Electrocatalysts Enhance the Selectivity of Carbon Dioxide Reduction
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- The local structure and geometry of catalytic interfaces can influence the selectivity of chemical r...
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David Gracias;Kam Sa...
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On the Mechanism of the Nickel-Catalyzed Boron Insertion into the C\\u2212O Bond of Benzofuran
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- The reaction of benzofurans with diboron reagents and Cs2CO3catalyzed by Ni(0) complexes results in ...
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Carles Bo;Ana Mateo-...
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Asymmetric Redox-Neutral Radical Cyclization Catalyzed by Flavin-Dependent \\u2018Ene\\u2019-Reductases
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- Flavin-dependent \\u2018ene\\u2019-reductases (EREDs) are exquisite catalysts for effecting stereose...
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Todd Hyster;Michael ...
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A Unified Electro- and Photocatalytic CO2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes
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- Mechanistic understanding of electro- andphotocatalytic CO2 reduction is crucial to develop strategi...
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Julio Lloret-Fillol;...
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Effect of Tethered, Axial Thioether Coordination on Rhodium(II)-Catalyzed Silyl-Hydrogen Insertion
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- The effect of tethering a thioether to a rhodium paddlewheel complex are evaluated in diazo-mediated...
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Ampofo Darko;William...
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2,2\\u2019-Dipyridylamine as Heterogeneous Organic Molecular Electrocatalyst for Two-Electron Oxygen Reduction Reaction in Acid Media
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- Continuous production of hydrogen peroxide (H2O2) through the two-electron oxygen reduction reaction...
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Xi Yin;Ling Lin;Ulis...
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Photochemical Strain-Release Driven Cyclobutylation of C(sp3)-Centered Radicals
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- Our manuscript describes a photoredox-catalyzed decarboxylative radical addition approach to functio...
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Guillaume Ernouf;Ego...
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Cu-Catalyzed Hydroboration of Benzylidenecyclopropanes: Reaction Optimization, (Hetero)Aryl Scope, and Origins of Pathway Selectivity
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- The copper-catalyzed hydroboration of benzylidenecyclopropanes, conveniently accessed in one step fr...
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- 作 者：
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Keary Engle;Jose Med...
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