Observations and Theories of Quantum Effects in Proton Transfer Electrode Processes

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Quantum tunneling effects play an important role in a variety of chemical reactions considerably aff...
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作 者:
Ken Sakaushi;Andrey ...
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Tetranuclear Copper and Mononuclear Nickel Complex of the Schiff Base of (3Z)-3-Hydrazonobutan-2-One Oxime with Different Aromatic Carbonyl Compounds: Synthesis, Single Crystal X-Ray Structure, Catecholase Activity, Phenoxazinone Synthase Activity, Catalytic Study for the Homocoupling of Benzyl Amines

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Synthesisand characterisation of one trinuclear copper complex, ([Cu3L3O]ClO4)(1) and one nickel com...
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作 者:
Swaraj Sengupta;Saha...
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Solvent Effect on Dipeptide Bond Formation: Glycine as a Case Study

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Peptide bond formation is a crucial chemical process that dominates most biological mechanisms and i...
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Zied Hosni;Sofiene A...
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Site-Selective C-H Halogenation using Flavin-Dependent Halogenases Identified via Family-Wide Activity Profiling

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Herein, we describe the use of a high-throughput mass spectrometry-based screen to evaluate a broad ...
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Jared C. Lewis;Brian...
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Protein Flexibility Catalyzes a Cell Signaling Reaction of the Ras-GAP Complex

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Many enzyme molecules exhibit characteristic global and slow dynamics which furnish them with allost...
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Shigehiko Hayashi;Ke...
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Bioinformatics-Guided Discovery of Citrulline 4-Hydroxylase from GE81112 Biosynthesis and Rational Engineering of Its Substrate Specificity

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We functionally characterize a nonheme dioxygenase from GE81112 biosynthesis and identify it as a ci...
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作 者:
Hans Renata;Christia...
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Molecular Engineering of \\u03b2-Substituted Oxoporphyrinogens for Hydrogen-Bond Donor Catalysis

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Anew class of bifunctional hydrogen-bond donor organocatalyst usingoxoporphyrinogens with increased ...
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作 者:
Daniel Payne;Mandeep...
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Novel Hierarchical Copper-Based Metal-Organic Frameworks for Improved Catalytic Performance

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Introducingadditional meso- or macroporosity into traditionally microporous metal-organicframeworks ...
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Huan Doan;Srinivasan...
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Implications of the Fractional Charge of Hydroxide at the Electrochemical Interface

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Rational design of materials that efficiently convert electrical energy into chemicalbonds will ulti...
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Joseph Gauthier;Lean...
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Light-Driven Depolymerization of Native Lignin Enabled by Proton- Coupled Electron Transfer

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Here we report a catalytic, light-driven method for the redox-neutral depolymerization of native lig...
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作 者:
Robert Knowles;Suong...
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