A Simple Nickel Catalyst Enables Broad E-Selective Alkyne Semihydrogenation

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A simple and commercially available nickel catalyst for E-selective alkyne semihydrogenation is pres...
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作 者:
Johannes F. Teichert...
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Air Oxidation of Sulfur Mustard Gas Simulant Using a Pyrene-Based Metal-Organic Framework Photocatalyst

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We demonstrate a microporous metal-organic framework NU-400 based on a 2,7-disubstituted pyrene link...
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作 者:
Ghada Ayoub;Mihails ...
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A Mechanically Planar Chiral Rotaxane Ligand for Enantioselective Catalysis

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Rotaxanes are interlocked molecules in which amolecular ring is trapped on a dumbbell-shaped axle d...
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作 者:
Stephen Goldup;Andre...
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Arylboronic Acid-Catalyzed C-Allylation of Unprotected Oximes

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Unprotected keto- and aldoximes are readily C-allylated with allyl diisopropyl boronate in the prese...
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作 者:
Laszlo Kurti;Juha Si...
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Catalytic Fluorination of Boron Compounds at a Bismuth Redox Platform

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The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mi...
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作 者:
Josep Cornella;Oriol...
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Integrating Allyl Electrophiles into Nickel-Catalyzed Conjunctive Cross-Coupling

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Allylation and conjunctive cross-coupling represent two useful, yet largely distinct, reactivity par...
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作 者:
Keary Engle;Van Tran...
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Aromaticity Driven Electrocatalytic Water Oxidation by a Phosphorus-Nitrogen PN3-Pincer Cobalt Complex

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Water oxidation is the primary step in bothnatural and artificial photosynthesis to convert solar en...
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作 者:
Kuo-Wei Huang;Pradip...
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Using Alcohols As Simple H2-Equivalents for Copper-Catalysed Transfer Hydrogenations

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Catalytic transfer hydrogenations are among the most practical synthetic methods for the selective r...
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作 者:
Johannes F. Teichert...
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Intermolecular sp3-C\\u2013H Amination for the Synthesis of Saturated Azacycles

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The preparation of substituted azetidines and larger-ring,nitrogen-containing saturated heterocycles...
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作 者:
Nicholas Chiappini;K...
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Fluoride Migration Catalysis Enables Simple, Stereoselective, and Iterative Glycosylation

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Challenges in the assembly of glycosidic bonds pose a bottleneck in enabling the remarkable promise ...
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作 者:
John Montgomery;Giri...
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