Chance Emergence of Catalytic Activity and Promiscuity in a Self-Replicator

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This study reveal a mechanism by which self-replicating molecules can autonomously acquire the abili...
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作 者:
Sijbren Otto;Jim Ott...
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Emergence of Light-Driven Protometabolism upon Recruitment of a Photocatalytic Cofactor by a Self-Replicator

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This work shows how a designed co-factor can be recruited and activated by a self-replicator to do p...
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Sijbren Otto;Guiller...
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Enantioselective alpha-Arylation of Benzamides via Synergistic Nickel and Metallaphotoredox Catalysis

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A new method to access alpha-arylated benzamides has been enabled by metallaphotoredox catalysis. Th...
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John Montgomery;Alex...
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A Dual Catalytic Platform for Enabling sp3 \\u03b1 C\\u2013H Arylation & Alkylation of Benzamides

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A dual catalytic sp3 a C\\u2013H arylation & alkylation of benzamides withorganic halides is describ...
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作 者:
Ruben Martin;Hongfei...
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Chiral Tetrahydropyridines via FeCl3-Catalyzed Carbonyl-Olefin Metathesis

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Herein, we describe the application of Lewis acid-catalyzedcarbonyl-olefin metathesis towards the sy...
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作 者:
Corinna Schindler;Ka...
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Catalytic Asymmetric Radical-Polar Crossover Hydroalkoxylation

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Asymmetric intramolecular hydrofunctionalization of tertiary allylic alcohols is described. This met...
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作 者:
Sergey Pronin;Christ...
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Sequential Immobilization of Ansa-Hafnocene Complexes for Propene Polymerization

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We report the immobilization of the ultrarigid ansa-hafnocene complexes [Me2Si(Ind*)2HfCl2] (Ind* = ...
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作 者:
Marius Arz;Tim Kratk...
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A Molecular-Level Mechanism of the Biological N2 Fixation

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We present a detailed molecular-level mechanism for the biological fixation of atmospheric nitrogen ...
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作 者:
Vanessa Jane Bukas;J...
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Heterolytic Hydrogen Activation: Understanding Support Effects in Water-Gas Shift, Hydrodeoxygenation, and CO Oxidation Catalysis

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Identifying the role of oxide supports in transition metal catalysis is critical toward our understa...
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作 者:
Nicholas Nelson;Jáno...
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Electrochemical CO2 Reduction on Nanostructured Metal Electrodes: Fact or Defect?

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Electrochemical CO2reduction has received an increased amount of interest in the last decade as a pr...
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作 者:
Recep Kas;Kailun Yan...
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