Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand
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We report that the silylation of five-membered ring heteroarenes occurs with high sterically derived...
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Caleb Karmel;Camille...
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Decarbonylative Olefination of Aldehydes to Alkenes
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New atom-economical alternatives to Wittig chemistryare needed construct olefins from carbonyl compl...
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Adelina Voutchkova-K...
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The Evolution Pathway from Iron Compounds to Fe1(II)-N4 Sites Through Gas-Phase Iron During Pyrolysis
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Pyrolysis is indispensable for synthesizing highly active Fe-N-C catalysts for the oxygen reduction ...
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Jingkun Li;Li Jiao;E...
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Chemoenzymatic ortho-quinone methide formation
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Generation of reactive intermediates and interception of these fleeting species in a cascade is a co...
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Alison Narayan;Tyler...
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Rh(III)-Catalyzed Direct Access to 2,3-Substituted \\u03b2-N-Glycosyl Indoles Through C-H Activation/annulation Coupling of \\u03b2-N-Aryl Glycosides with Substituted Internal Alkynes
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An efficient and selective C-H activation/annulation of readily available \\u03b2-N-aryl glycosides ...
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Samir Messaoudi;Oliv...
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Facile Electron Transfer to CO2 during Adsorption at the Metal | Solution Interface
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We estimate the rate of electron transfer to CO2 at the Au (211)|water interface during adsorption i...
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Michal Bajdich;Josep...
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High-Performance Iron-Based ORR Catalysts Synthesized via Chemical Vapor Deposition
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A Fe-N-C catalyst was synthesized via chemical vapor deposition (CVD) of gas phase FeCl3 onto a meta...
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Qingying Jia;Li Jiao...
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Nitrene Transfer Catalyzed by a Non-Heme Iron Enzyme and Enhanced by Non-Native Small-Molecule Cofactors
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Transition-metal catalysis is a powerful tool for the construction of chemical bonds. Here we show t...
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Frances H. Arnold;Na...
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Directed Evolution of an Fe\\u1d35\\u1d35-Dependent Halogenase for Asymmetric C(sp\\u00b3)-H Chlorination
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By using structure-guided directed evolution, the substrate scope of the FeII and a\\u2011ketoglutar...
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Sabrina Hoebenreich;...
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Application of Amino Transaminases in a Disperse System for the Biotransformation of Hydrophobic Substrates
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The challenging bioamination of hydrophobic substrates has been attained through the employment of a...
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作 者：
Davide Tessaro;Andre...
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