Electronically Asynchronous Transition States for C-N Bond Formation by Electrophilic [Co\\u1d35\\u1d35\\u1d35(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle

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The oxidation state of the redox non-innocent TAML (Tetra-Amido Macrocyclic Ligand) scaffold was rec...
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Bas de Bruin;Nicolaa...
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Reversing Reactivity: Stereoselective Desulfurative \\u03b2-O-Glycosylation of Anomeric Thiosugars with Carboxylic Acids Under Copper or Cobalt Catalysis

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We have discovered a new mode of reactivity of 1-thiosugars in the presence of Cu(II) or Co(II) for ...
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作 者:
Samir Messaoudi;Nedj...
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The Role of Atomic Carbon in Directing Electrochemical CO(2) Reduction to Multicarbon Products

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Electrochemical reduction ofcarbon-dioxide/carbon-monoxide (CO(2)R) to fuels and chemicalspresents a...
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Hongjie Peng;Michael...
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From Electricity to Fuels: Descriptors for C1 Selectivity in Electrochemical CO2 Reduction

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Electrochemical reduction of carbon dioxide (CO2)over transition metals follows a complex reaction n...
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Hongjie Peng;Michael...
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Design and Development of 3D Printed Catalytically-Active Stirrers for Chemical Synthesis

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In this present study, we describe the novel design, preparation andevaluation of catalyst-impregnat...
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Stephen Hilton;Matth...
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Cupin Variants as Macromolecular Ligand Library for Stereoselective Michael Addition of Nitroalkanes

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Cupin superfamily proteins (TM1459) work as a macromolecular ligand framework with a double-stranded...
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作 者:
Nobutaka Fujieda;Mih...
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Synthesis and Electrocatalytic HER Studies of Carbene-Ligated Cu3-xP Nanocrystals

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N-heterocycliccarbenes (NHCs) are an important class of ligands capable of making strongcarbon-metal...
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Richard Brutchey;Bry...
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Site-selective enzymatic C\\u2012H amidation for synthesis of diverse lactams

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Please note that this work has been retracted by the authors.After publication of the Report \\u201c...
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作 者:
Zhijun Jia;Inha Cho;...
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Interfacial Photoelectrochemical Synthesis of Organic Molecules: Solar-Induced Electrochemical Organic Transformations

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Conventional organic synthesis for many oxidation and reduction reactions rely on harsh conditions, ...
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作 者:
Nisar Ahmed;Tomas Ha...
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Imine as a Linchpin Approach for Distal C(sp2)\\u2013H Functionalization

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Despitethe widespread applications of C\\u2013H functionalization, controlling siteselectivity remai...
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作 者:
Debabrata Maiti;Sukd...
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