Photochemically-Mediated Nickel-Catalyzed Synthesis of N-(Hetero)aryl Sulfamides

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A general method for the N-arylation of sulfamides with aryl bromides is described. The protocol lev...
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作 者:
Jennifer Roizen;R. T...
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Computationally-Guided Investigation of Dual Amine/pi Lewis Acid Catalysts for Direct Additions of Aldehydes and Ketones to Unactivated Alkenes and Alkynes

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Dual amine/pi Lewis acid catalyst systems have been reported for intramolecular direct additions of ...
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作 者:
Chris Dockendorff;Er...
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Conditional Copper-Catalyzed Azide Alkyne Cycloaddition by Catalyst Encapsulation

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Supramolecular encapsulation is known to alter chemical properties of guest molecules. Here we apply...
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作 者:
Rienk Eelkema;Tobias...
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Palladium Catalyzed Stereoselective Arylation of Biocatalytically Derived Cyclic 1,3-Dienes: Chirality Transfer via a Heck-Type Mechanism

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Microbial arene oxidation of benzoic acid with Ralstonia eutropha B9 provides a chiral highly functi...
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Nina Kann;Andrew J. ...
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A Structurally Robust Chiral Borate Ion: Molecular Design, Synthesis, and Asymmetric Catalysis

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Catalysis by chiral weakly-coordinating anions (WCAs) remains underdeveloped due to the lack of a mo...
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作 者:
Takashi Ooi;Daisuke ...
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Carboxylated Chitosan Nanocrystals: Novel Synthetic Route and Application as Superior Support for Gold-Catalyzed Reactions

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Chitin nanocrystals (ChNCs) wereprepared by partial cleavage of glycosidic bonds in chitin with conc...
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作 者:
Audrey Moores;Tony J...
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Tuning Mechanism through Buffer Dependence of Hydrogen Evolution Catalyzed by a Cobalt Mini-enzyme

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Cobalt-mimochrome VI*a (CoMC6*a) is a synthetic mini-protein that catalyzes aqueous proton reduction...
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作 者:
Kara Bren;Jennifer L...
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Spectroscopic investigations under whole cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase

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Hydrogenases are among the fastest H2 evolving catalysts known to date and have been extensively stu...
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作 者:
Sven T. Stripp;Lívia...
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Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

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A mechanism for Rh(I)-catalyzed asymmetricSuzuki-Miyaura coupling with racemic allyl halides is prop...
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作 者:
Lucy van Dijk;Ruchut...
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Cobalt/Lewis Acid Catalysis for Hydrocarbofunctionalization of Alkynes via Cooperative C\\u2013H Activation

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A catalytic system comprised of a cobalt-diphosphine complex and a Lewis acid (LA) such as AlMe3 has...
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作 者:
Naohiko Yoshikai;Cha...
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