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Synthesis of All-carbon Disubstituted Bicyclo[1.1.1]pentanes by Iron-Catalyzed Kumada CrossCoupling
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- 1,3-Disubstituted bicyclo[1.1.1]pentanes (BCPs) are important motifs in drug design as surrogates fo...
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Edward Anderson;Jere...
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Nucleophilic (Radio)Fluorination of Redox-Active Esters via Radical-Polar Crossover Enabled by Photoredox Catalysis
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- We report a redox-neutral method for nucleophilic fluorination of N-hydroxyphthalimide esters using ...
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Abigail Doyle;Eric W...
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Divergent Synthesis of Complex ent-Kauranes, ent-Atisanes and ent-Trachylobanes via a Hybrid Oxidative Approach
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- Nine complex diterpenes were synthesized using a hybrid oxidative approach that combines chemical an...
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Hans Renata;Xiao Zha...
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Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers
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- ABSTRACT: Although the catalytic carboxylation of unactivated alkyl electrophiles has reached remark...
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Ruben Martin;Rosie S...
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Surface Chemistry Modulates CO2 Reduction Reaction Intermediates on Silver Nanoparticle Electrocatalysts
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- Electrocatalytic reduction of carbon dioxide (CO2R) to fuels and chemicals is a pressing scientifica...
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Nikolay Kornienko;To...
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A Pyridinic Fe-N4 Macrocycle Effectively Models the Active Sites in Fe/N-Doped Carbon Electrocatalysts
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- Iron- and nitrogen-doped carbon (Fe-N-C) materials are leading candidates to replace platinum in fue...
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Yogesh Surendranath;...
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Rational Enzyme Design Without Structural Knowledge: A Sequence-Based Approach for Efficient Generation of Glycosylation Catalysts
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- We present an enzyme engineeringapproach based solely on amino-acids sequence to convert glycoside h...
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David Teze;Zhao, Jia...
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Mechanism of the Iridium-Catalyzed Silylation of Aromatic C\\u2013H Bonds
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- Theiridium-catalyzed silylation of aromatic C\\u2013H bonds has become a syntheticallyvaluable react...
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Caleb Karmel;John Ha...
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Dipole Field Interactions Determine the CO2 Reduction Activity of 2D FeNC Single Atom Catalysts
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- Electrochemical CO2 Reduction (CO2R) can potentially allow for the sustainable production of valuabl...
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- 作 者：
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Sudarshan Vijay;Jose...
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Enantioselective C(sp3)\\u2013C(sp3) Cross-Coupling of Non-activated Alkyl Electrophiles via Nickel Hydride Catalysis
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- Cross-coupling of two alkyl fragments is anefficient method to produce organic molecules rich in sp3...
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- 作 者：
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Xile Hu;Srikrishna B...
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