The Peculiar Case of the Hyperthermostable Pyrimidine Nucleoside Phosphorylase from Thermus Thermophilus
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The poor solubility of many nucleoside and nucleobases in aqueous solution demands harsh reaction co...
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Felix Kaspar;Peter N...
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Host-Guest Interactions on Electrode Surfaces for Immobilization of Molecular Catalysts
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The strategy of anchoring molecular catalysts on electrode surfaces combines the high selectivity an...
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David Tilley;Laurent...
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Efficacy Analysis of Compartmentalization for Ambient CH4 Activation Mediated by RhII Metalloradical in Nanowire Array Electrode
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Compartmentalization is a viable approach of ensuring the turnover of a solution cascade reaction wi...
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Chong Liu;Benjamin N...
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Circumventing Scaling Relations in Oxygen Electrochemistry using Metal-Organic Frameworks
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It has been well-established that unfavorable scaling relationships between *OOH, *OH, and *O are re...
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Ambarish Kulkarni;Ty...
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Synthesis of Axially Chiral 2,2\\u2019-Bisphosphobiarenes via a Nickel-Catalyzed Asymmetric Ullmann Coupling: General Access to Privileged Chiral Ligands without Optical Resolution
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We report an asymmetric Ullmann-type homocoupling of ortho-(iodo)arylphosphine oxides and ortho-(iod...
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Donald Watson;Ziqing...
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Bimetallic Cooperativity with a 2-Phosphinoimidazole-Derived Pd(II) Dimer Enables Naphthalene Synthesis via dimeric Pd(III) Catalysis
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Wereportthesynthesisof bimetallic Pd(I)andPd(II)complexesscaffoldedonbidentate2-phosphinoimidazoleli...
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David Michaelis;Chlo...
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DNAzymes for Amine and Peptide Lysine Acylation
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DNAzymes were previously identified by in vitro selection for a variety of chemical reactions, inclu...
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Scott Silverman;Tian...
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Analyzing Mechanisms in Co(I) Redox Catalysis Using a Pattern Recognition Platform
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Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages...
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Matthew Sigman;Tianh...
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H2 Formation Holds the Key to Opening the Fe Coordination Sites of Nitrogenase FeMo-cofactor for Dinitrogen Activation
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Thepresent quantum-mechanical and molecular-mechanics study reveals the crucialroles of H2 formation...
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作 者：
Jun Li;Yong Li;Wan-L...
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N-Heterocyclic Carbene/Magnesium Co-catalyzed Radical Relay Assembly of Aliphatic Keto-nitriles
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An N-heterocyclic carbene andmagnesium co-catalyzed three-component alkylacylation of alkenes with c...
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作 者：
Ding Du;Lei Chen;Shi...
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