Rerouting an Organocatalytic Reaction by Intercepting its Reactive Intermediates

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Reactive intermediates are key to halting and promoting chemical transformations, however due to the...
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作 者:
anat milo;Santosh C....
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Mechanisms for Flavin Mediated Oxidation: Hydride or Hydrogen-Atom Transfer?

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Flavins are versatile biological cofactors which catalyze proton-coupled electron transfers (PCET) w...
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作 者:
Guilherme M. Arantes...
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Oxygenate Reactions over PdCu and PdAg Catalysts: Distinguishing Electronic and Geometric Effects on Reactivity and Selectivity

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We investigate PdCu and PdAg catalysts in the context of oxygenate upgrading for biofuels. To this e...
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作 者:
Konstantinos A Goula...
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Breaking Simple Scaling Relations Through Metal-Oxide Interactions: Understanding Room Temperature Activation of Methane on M-CeO2 (M= Pt, Ni or Co) Interfaces

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The clean activation of methane at low temperatures remains an eminent challenge and a field of comp...
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作 者:
Pablo Lustemberg;Fen...
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Tunable Eg Orbital Occupancy in Heusler Compounds for Oxygen Evolution Reaction

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Heusler compounds have great potential in electrocatalysis due to theirmechanical robustness, metall...
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作 者:
Guowei Li;Mingquan Y...
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Mass Transport in Catalytic Pores of GDE-Based CO2 Electroreduction Systems

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Gas diffusion electrode (GDE)-based setups have shown promising performance for CO2 electrocatalysis...
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作 者:
Divya Bohra;Jehanzeb...
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Selecting Double Bond Positions with a Single Cation- Responsive Iridium Olefin Isomerization Catalyst

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The catalytic transposition of double bonds holds promise as an ideal route to alkenes with value as...
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作 者:
Alexander Miller;And...
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An Efficient Discovery of Active, Selective and Stable Catalysts for Electrochemical H2O2 Synthesis Through Active Motif Screening

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Electrochemical reduction of O2 provides a clean and decentralized pathway to produce H2O2 compared ...
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作 者:
Seoin Back;Jonggeol ...
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DEET Degradation by Titanium Dioxide\\u2013Zeolite Nanocomposites: Effects of Aggregation State, Water Chemistry, and Natural Organic Matter

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Immobilizationof titanium dioxide nanoparticles (TiO2 NPs) facilitates their removaland reuse in wat...
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作 者:
Stacey M. Louie;Tche...
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Coverage-Dependent Formic Acid Oxidation Reaction Kinetics Determined by Oscillating Potentials

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We report a methodology based on applying oscillating potentials to various electrocatalytically act...
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作 者:
Ning Yan;Max J. Huel...
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