Enantioselective Coupling of Nitroesters and Alkynes

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By using Rh-H catalysis, we couple \\u03b1-nitroesters and alkynes to prepare \\u03b1-amino acid sur...
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作 者:
Vy M. Dong;Ryan Davi...
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Nucleophilic Attack on Nitrogen in Tetrazines by Silyl-Enol Ethers

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The nucleophilic addition to nitrogen in 3-monosubstituted s-tetrazines under mild conditions is rep...
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作 者:
Karl Gademann;Simon ...
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Fast Carbon Isotope Exchange of Carboxylic Acids Enabled by Organic Photoredox Catalysis

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Carbazole/cyanobenzene photocatalysts promote the direct isotopic carboxylate exchange ofC(sp3)-acid...
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作 者:
Rylan Lundgren;Duany...
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Temperature and Solvent Effects on H2 Splitting and Hydricity: Ramifications on CO2 Hydrogenation by a Rhenium Pincer Catalyst

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The catalytic hydrogenation of carbon dioxide holds immense promise for applications in sustainable ...
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作 者:
Alexander Miller;Jen...
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Chemoselective Union of Olefins, Organohalides and Redox-Active Esters Enables Regioselective Alkene Dialkylation

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Multicomponent catalytic processes that can generate multiple C(sp3)-C(sp3) bonds in a single step u...
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作 者:
Ming Joo Koh;Tao Yan...
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A CO2-Catalyzed Transamidation Reaction

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Amide bond formation reactions are often mediated by reactive substratesin the presence of over-stoi...
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作 者:
JIWOONG LEE;Yang Yan...
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Shuttle Arylation by Rh(I) Catalyzed Reversible Carbon\\u2013Carbon Bond Activation of Unstrained Alcohols

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The advent of transfer hydrogenation and borrowing hydrogen reactions paved the way to manipulate si...
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作 者:
Bill Morandi;Marius ...
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A DFT Study on the Electrocatalytic Reduction of CO2 to CO by a Molecular Chromium Complex

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A variety of molecular transitionmetal-based electrocatalysts for the reduction of carbon dioxide (C...
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作 者:
Charles Machan;Juan ...
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A Pharmacophore-Based Approach to Demonstrating the Scope of Alcohol Dehydrogenases

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Barriers to the ready adoption ofbiocatalysis into asymmetric synthesis for early stage medicinal ch...
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作 者:
Holly Reeve;Katrina ...
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Visible Light-Mediated Oxidative Debenzylation

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Protecting groups are key in the synthesis of complex molecules such as carbohydrates to distinguish...
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Bartholom?us Pieber;...
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