Ground-State Electron Transfer as an Initiation Mechanism for Asymmetric Hydroalkylations in Radical Biocatalysis
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Stereoselective bond-forming reactions are essential tools in modern organic synthesis. However, cat...
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Todd K. Hyster;Haige...
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Surface Electronic State Mediates Proton Transfer at Metal Nanoscale Interface for Catalytic Hydride Reduction of \\u2212NO2 to \\u2212NH2
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Concerted electron and proton transfer is a key step for the reversible conversion of molecular hydr...
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作 者：
Kun Zhang;Bingqian S...
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Photoredox Catalysis Using Heterogenized Iridium Complexes
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Heterogenized photoredox catalysts provide a path to generating chemicals in an environmentally frie...
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Kelly L. Materna;Lei...
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pH-Independent Heat Capacity Changes during Phosphorolysis Catalyzed by the Pyrimidine Nucleoside Phosphorylase from Geobacillus thermoglucosidasius
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Enzyme-catalyzed reactions sometimes display curvature in their Eyring plots in the absence of denat...
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Felix Kaspar;Darian ...
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Phase Coexistence and Structural Dynamics of Redox Metal Catalysts Revealed by Operando TEM
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Metal catalysts play an important role in industrial redox reactions. Although extensively studied,t...
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Xing Huang;Travis Jo...
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Co-Catalyzed E-(\\u03b2)-Selective Hydrogermylation of Terminal Alkynes
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We demonstrated unprecedentedly that Co complexes can catalyze hydrogermylation of alkynes. Subseque...
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Neal Mankad;Maxim Ra...
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Nickel-Catalyzed 1,2-Diarylation of Alkenyl Ketones: A Comparative Study of Carbonyl-Directed Reaction Systems
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A conjunctive cross-coupling reaction of alkenyl ketones, aryl iodides, and arylboronic esters under...
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Keary Engle;Roman Kl...
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Rational Prediction of Distal Activity-Enhancing Mutations in Tryptophan Synthase
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Allostery is a central mechanism for the regulation of multi-enzyme complexes. The mechanistic basis...
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Sílvia Osuna;Miguel ...
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Seven Steps to Reliable Cyclic Voltammetry Measurements for the Determination of Double Layer Capacitance
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Discoveryof electrocatalytic materials for high-performance energy conversion andstorage application...
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Marcel Risch;Dulce M...
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Metallized Ni(OH)2\\u00b7NiO/FeOOH on Ni foam as Highly Effective Water Oxidation Catalyst Prepared by Surface Treatment: Oxidation-Corrosion Equilibrium
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The surface treatment methodhas a great influence on the structure and properties of applied materia...
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作 者：
Huawei Zhou;Fei Wang...
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