Photocatalytic Deoxygenation of N\\u2013O Bonds with Rhenium Complexes: From the Reduction of Nitrous Oxide to Pyridine N-Oxides

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The accumulation of nitrogen oxides in the environment calls for new pathways to interconvert the va...
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作 者:
Emmanuel Nicolas;Mar...
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Mechanistic Investigations of an \\u03b1-Aminoarylation Photoredox Reaction

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We present time-dependent percent and quantum yield measurements of a photoredox-catalyzed coupling ...
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作 者:
John SWIERK;Bernard ...
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Ni/Photoredox-Catalyzed Enantioselective Cross-Electrophile Coupling of Styrene Oxides with Aryl Iodides

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A Ni/photoredox-catalyzed enantioselective reductive coupling of styrene oxides and aryl iodides is ...
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作 者:
Abigail Doyle;Sii Ho...
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Synergistic Catalysis of Tandem Michael Addition/Enantioselective Protonation Reactions by an Artificial Enzyme

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Enantioselective protonation is conceptually one of the most attractive methods to generate an \\u03...
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作 者:
Zhi Zhou;Gerard Roel...
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Nickel-Catalyzed Thiolation of Aryl Nitriles

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A nickel-catalyzed thiolation of aryl nitriles has been developed to access functionalized aryl thio...
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作 者:
Bill Morandi;Tristan...
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Radical Trifluoroacetylation of Alkenes Triggered by a Visible-Light-Promoted C\\u2212O Bond Fragmentation of Trifluoroacetic Anhydride

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Trifluoromethyl ketones are not only found in drug like substances, butare also considered as key sy...
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作 者:
Dmitry Katayev;Kun Z...
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Revisiting the Concept of Photocatalysis: An Analysis from the Chemical Potentials

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A renewed criterion ofphotochemical free energy is proposed by introducing the concept of absorbedph...
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作 者:
Yubin Chen;Jiazhe Wu...
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Stereospecific, Ligand-Free Synthesis of All-Carbon Quaternary Stereocenters from Tertiary Benzylic Carboxylates

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Nickel-catalyzed, stereospecific cross-couplings via activation of secondary C\\u2013O bonds has bee...
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作 者:
Mary Watson;Jianyu X...
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Diversification of 4\\u02b9-Methylated Nucleosides by Nucleoside Phosphorylases

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The growing demand for 4'-modified nucleoside analogs in medicinal and biological chemistry is contr...
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作 者:
Felix Kaspar;Margari...
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On the Mechanism of Electrochemical Generation and Decomposition of Phthalimide N-oxyl (PINO)

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Phthalimide N-oxyl (PINO)is a potent hydrogen atom transfer (HAT) catalyst that can be generatedelec...
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作 者:
Corey Stephenson;Che...
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