Mechanism of the Arene-Limited Nondirected C\\u2013H Activation of Arenes with Palladium

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Recently palladium catalysts have been discovered that enable the directing group-free C\\u2013H act...
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作 者:
Manuel van Gemmeren;...
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Tracking Structure and Composition Changes in Oxide Derived Cu-Sn Catalysts During CO2 Electroreduction Using X-Ray Spectroscopy

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In the field of electrochemical CO2conversion, the development of earth-abundant catalysts which are...
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作 者:
Matthew Mayer;Laura\...
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Origin of Enantioselectivity Reversal in Lewis Acid-Catalysed Michael Additions Relying on the Same Chiral Source

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Enantiodivergence is an important concept in asymmetric catalysis that enables access to both enanti...
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作 者:
Corinna Schindler;Pa...
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Metallic Porous Electrodes Enable Efficient Bicarbonate Electrolysis

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We demonstrate here that a porous free-standing silver foam cathode in an electrolytic flow electrol...
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作 者:
Zishuai Zhang;Eric W...
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Unified Mechanistic Understanding of CO2 Reduction to CO on Transition Metal and Single Atom Catalysts

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CO is the simplest product from CO2electroreduction (CO2R), but the identity and nature of its ratel...
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作 者:
Sudarshan Vijay;Wen ...
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Asymmetric Synthesis of Homoallylic Alcohols Featuring Vicinal Tetrasubstituted Carbon Centers via Dual Pd/Photoredox Catalysis

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Dual palladium/photoredox-catalysis provides aneffective method for the asymmetric synthesis of vici...
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作 者:
Bart Limburg;Sijing ...
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Highly Site-Selective Direct C\\u2212H Bond Functionalization of Unactivated Arenes with Propargyl \\u03b1\\u2011Aryl-\\u03b1-diazoacetates via Scandium Catalysis

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Highly chemo- and regio-selective C\\u2013H bond functionalization of unactivated arenes with propar...
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Prof. Dr. Ramakrishn...
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Isodesmic C\\u2013H Functionalization: Carboxyl-Assisted Remote meta- and ortho-C\\u2013H Iodination of Arenes via Shuttle Catalysis

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Isodesmic C\\u2013Hfunctionalization reactions are extremely rare. Hereinwe report the first Pd(II)-...
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作 者:
Gang Li;Shangda Li;C...
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Spirocyclizative Remote Arylcarboxylation of Non-Activated Arenes with CO2 via Visible-Light-Induced Reductive Dearomatization

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Visible-light-induced reductive dearomatization ofnon-activated arenes is a very challenging transfo...
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作 者:
Gang Li;yuzhen gao;H...
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Ligand-to-Copper Charge Transfer: A General Catalytic Approach to Aromatic Decarboxylative Functionalization

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Aryl carboxylic acids are valuable, stable, and abundant functional handles in organic synthesis. Hi...
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作 者:
Tiffany Q. Chen;P. S...
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