[Co(TPP)]\\u2013Catalyzed Carbene Transfer from Acceptor\\u2013Acceptor Iodonium Ylides via N-enolate Carbene Radicals

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Abstract: Square-planar cobalt(II)-systems have emerged as powerful carbene transfer catalysts for t...
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作 者:
Roel F.J. Epping;Mee...
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Activation by oxidation and ligand exchange in a molecular manganese vanadium oxide water oxidation catalyst

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Despite their technological importance, reaction mechanisms of most water oxidation catalysts (WOCs)...
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作 者:
Ludwig Schwiedrzik;G...
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Radical alpha-Trifluoromethoxylation of Ketones by Means of Organic Photoredox Catalysis

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The first light-driven method for the alpha-trifluoromethoxylation of ketones is reported. Enol carb...
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Luca Dell'Amico;Thib...
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A Localized Enantioselective Catalytic Site on Short DNA Sequences and their Amphiphiles

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A DNA-based artificial metalloenzyme (ArM) consisting of copper (II) complex of 4,4\\u2019-dimethyl-...
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Efrosini Kokkoli;Jun...
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Understanding the Local Chemical Environment of Bioelectrocatalysis

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This work applies electrochemical and computational techniques to explore the local environment of f...
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作 者:
Erwin Reisner;Esther...
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Homogeneous hydrogenation of saturated bicarbonate slurry to formates using multiphase catalysis

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Formic acid and formate salts are key intermediates along the pathways for CO2 utilization and hydro...
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作 者:
Evgeny Pidko;Christo...
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Modular Enantioselective Synthesis of cis-Cyclopropanes through Redox-Active Carbene Transfer and Stereoselective Photo-Decarboxylation

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Chiral cis-cyclopropanes are strained rigid analogs of alkyl chains, whose study and application is ...
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作 者:
Abraham Mendoza;Matt...
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Kinetic Effects of Temperature on Fe-N-C Catalysts for 2e- and 4e-Oxygen Reduction Reactions

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Hydrogen peroxide (H2O2) formed via the two-electron oxygen reduction reaction (2e-ORR) on Fe-N-C ca...
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作 者:
Xi Yin;Jie Yang;Junf...
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Electrochromism or Water Splitting in Neutral Aqueous Solutions by a Metallo-Organic Assembly

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We describe two different functionalities of one metallo-organic film assembled on the surface of a ...
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作 者:
Milko van der Boom;N...
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Nitrene Photochemistry of Manganese N-Haloamides

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Here we report the synthesis and nitrene transfer photochemistry of Mn(III) N-haloamide complexes. P...
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作 者:
David Powers;Gerard ...
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