Using Data Science to Guide Aryl Bromide Substrate Scope Analysis in a Ni/Photoredox-Catalyzed Cross-Coupling with Acetals as Alcohol-Derived Radical Sources

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Ni/photoredox catalysis has emerged as a powerful platform for C(sp2)\\u2013C(sp3) bond formation. I...
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作 者:
Abigail Doyle;Stavro...
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Electrosynthesis of Green Urea by co-reduction of N2 and CO2 Using Dual Active Sites of Copper Phthalocyanine Nanotube

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Green synthesis of urea under ambient conditions by electrochemical co-reduction of N2 and CO2 gases...
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作 者:
Uttam Ghorai;Jit Mu...
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Dipole Moment and Charge Reorganization in Photoredox Catalysts

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We report evidence of excited-state ion pair reorganisation in a cationic iridium (III) photoredox c...
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作 者:
Justin Earley;Anna Z...
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Preparation of Recyclable and Versatile Porous Poly-Arylthioethers by Reversible Pd-Catalysed C\\u2013S/C\\u2013S Metathesis

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Porous organic polymers have shown a number of promising properties; however, their application is u...
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作 者:
Bill Morandi;Miguel ...
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Carbonylative Cross-Electrophile Coupling Between Aryl Bromides and Aryl Triflates Enabled by Palladium and Rhodium Cooperative Catalysis

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Ketones are among the most useful functional groups in organic synthesis. Here, we report the first ...
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作 者:
S?ren Kramer;Zhong L...
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Structural insight into an atomic layer deposition (ALD) grown Al2O3 layer on Ni/SiO2: impact on catalytic activity and stability in dry reforming of methane

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The development of stable Ni-based dry reforming of methane (DRM) catalysts is a key challenge owing...
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作 者:
Paula Abdala;Kim Sun...
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MD Simulations and QM/MM Calculations Reveal the Key Mechanistic Ele-ments which are Responsible for the Efficient C-H Amination Reaction Per-formed by a Bioengineered P450 Enzyme

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An enzyme which is capable of catalyzing C-H amination reactions, is considered to be a dream tool f...
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作 者:
Kshatresh Dubey;Saso...
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Intermolecular 2+2 Imine-Olefin Photocycloadditions Enabled by Cu(I)-Alkene MLCT

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2+2 Photocycloadditions are idealized, convergent approaches to the construction of 4-membered heter...
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作 者:
Valerie Schmidt;Dani...
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Local Electric Fields Dictate Function: The Different Product Selectivity Observed for Fatty Acids Oxidation by Two Deceptively Very Similar P450-Peroxygenases OleT and BSbeta

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Cytochrome P450 peroxygenases use hydrogen peroxide to hydroxylate long-chain fatty acids by bypassi...
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作 者:
Kshatresh Dubey;Shal...
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The synthesis of chiral branched allylamines through dual photoredox/nickel catalysis

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Allylamines are versatile building blocks in the synthesis of various naturally occurring products a...
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作 者:
Sebastian Stecko;Mat...
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