Chemoselective, Scalable Nickel-Electrocatalytic O-Arylation of Alcohols

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The formation of aryl-alkyl ether bonds through cross coupling of alcohols with aryl halides represe...
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作 者:
phil baran;Hai-Jun Z...
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A Six-Coordinate High-Spin FeIV=O Species of Cucurbit[5]uril: A Highly Potent Catalyst for C-H Hydroxylation of Methane, If synthesised

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DFT and ab initio DLPNO-CCSD(T) calculations predict a stable S =2 six-coordinate FeIV=O species wit...
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Gopalan Rajaraman;Ra...
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1- and 2-Azetines via Visible Light-Mediated [2+2]-Cycloadditions of Alkynes and Oximes

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Azetines, four-membered unsaturated nitrogen-containing heterocycles, hold great potential for drug ...
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Corinna Schindler;Em...
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Catalytic Activation via \\u03c0 \\u2013Backbonding in Halogen Bonds?

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The role of halogen bonding (XB) in chemical catalysis has largely involved using XB donors as Lewis...
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作 者:
Pierre Kennepohl;And...
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From Photoredox Catalysis to the Direct Excitation of\\nEthynylBenziodoXolones: Accessing Alkynylated Quaternary\\nCarbons from Alcohols via Oxalates

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EthynylBenziodoXolones (EBXs) are commonly used as radical traps in photocatalytic alkynylations. He...
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作 者:
Jerome Waser;Stephan...
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3D-printed hierarchical pillar array electrodes for high performance semi-artificial photosynthesis

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The re-wiring of photosynthetic bio-machineries to electrodes is a forward-looking semi-artificial r...
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作 者:
Jenny Zhang;Xiaolong...
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Cavity Catalysis: Modifying Linear Free-energy Relationship under Cooperative Vibrational Strong Coupling

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Recent understanding of light-matter strong coupling brought a new niche in molecular-level control ...
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作 者:
Jino GEORGE;Jyoti La...
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Modulating Electric Field Distribution by Alkali Cations for CO2 Electroreduction in Strongly Acidic Medium

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The reaction of carbon dioxide with hydroxide to form carbonate in near neutral or alkaline medium s...
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作 者:
Xile Hu;Jun Gu;Shuo ...
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Manganese-Catalyzed Dehydrogenative Silylation of Alkenes Following Two Paral-lel Pathways

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We report on an additive-free Mn(I)-catalyzed dehydrogenative silylation of terminal alkenes. The mo...
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作 者:
Karl Kirchner;Stefan...
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Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization\\u2013Hydroboration of Unactivated Alkenes

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A tungsten-catalyzed hydroboration of unactivated alkenes at distal C(sp3)\\u2013H bonds aided by na...
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作 者:
Keary Engle;Tanner J...
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