Phosphine/Photoredox Catalyzed anti-Markovnikov Hydroamination of Olefins with Primary Sulfonamides via a-Scission from Phosphoranyl Radicals

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New strategies to access radicals from common feedstock chemicals hold the potential to broadly impa...
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作 者:
Abigail Doyle;Alex C...
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Conductivity mechanism in ionic 2D carbon nitrides: from hydrated ion motion to enhanced photocatalysis

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Carbon nitrides are among the most studied materials for photocatalysis, however, limitations arise ...
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作 者:
Filip Podjaski;Julia...
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Polydopamine coated CdSe@CdS dot-in-rod heterostructures with Rhodium-based catalysts for stable photocatalytic NAD+ reduction

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We report on a photocatalytic system consisting of CdSe@CdS nanorods, coated with a polydopamine (PD...
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作 者:
Tanja Weil;Marcel B...
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Reversal of Regioselectivity in Reactions of Donor-Acceptor Cyclopropanes with Eelectrophilic Olefins

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Cyclopropanes bearing donor and acceptor groups at the opposite ends of the C-C bond should react wi...
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作 者:
Dorota Gryko;Joanna ...
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Photoredox Catalyzed Site-Selective Generation of Carbanions from C(sp3)-H bonds in Amines

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The selective activation of sp3 carbon-hydrogen bonds in presence of multiple C\\u00ac-H bonds is ch...
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作 者:
Burkhard Koenig;Kath...
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First d0 Metal-Catalyzed Alkyl\\u2013Alkyl Cross Coupling Enabled by a Redox-Active Ligand

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Alkyl\\u2013alkyl cross coupling through well-defined mechanisms that allow for controlled oxidative...
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作 者:
Courtney Roberts;Rom...
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Hydrogen evolution reaction on Co-Ni core-shell nanoclusters in different sizes: A DFT investigation from geometric structures to electronic structures

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Nanoclusters have broad prospects in the application of hydrogen evolution reaction (HER) electrocat...
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作 者:
Hengyue Xu
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Additive-free selective methylation of amines with formic acid over a Pd/In2O3 catalyst

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Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and alipha...
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作 者:
Caroline Genre;Idir ...
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Adsorbed Cobalt Porphyrins Act like Metal Surfaces in Electrocatalysis

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Carbon electrodes chemically modified with molecular active sites are potent catalysts for key energ...
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作 者:
Corey J. Kaminsky;So...
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Asymmetric synthesis of heterocyclic chloroamines and aziridines by enantioselective protonation of catalytically generated enamines

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We report a method for the synthesis of chiral vicinal chlo-roamines via asymmetric protonation of c...
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作 者:
Allan Watson;Liam Mc...
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