Controlling Non-Native B12 Reactivity and Catalysis in the Transcription Factor CarH

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Vitamin B12 derivatives catalyze a wide range of organic transformations, but B12-dependent enzymes ...
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作 者:
Jared Lewis;Xinhang ...
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Tandem electrocatalytic N2 fixation via concerted proton-electron transfer

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New electrochemical ammonia (NH3) synthesis technologies are of interest as a complementary route to...
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作 者:
Jonas Peters;Pablo G...
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An Expedited Phenotypic Approach Towards Organic Reaction Generality

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Reaction generality is crucial in determining the overall impact and usefulness of organic synthetic...
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作 者:
Cesar N. Prieto Kull...
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Mechanochemical solid state synthesis of a bifunctional copper(I)/N-heterocyclic carbene complex and its catalytic activity in hydrogenative transformations

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A sophisticated bifunctional catalyst bearing a copper(I)/N-heterocyclic carbene and a guanidine org...
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Teichert Johannes;Bi...
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Base dependent 1,3-dithioacetals rearrangement over sulfoxidation under visible-light photocatalysis to access disulfide-linked-dithioesters

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Base dependent oxidative rearrangement of dithiolanes and dithianes to access disulfide-linked-dithi...
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Dr. Ramakrishna G. B...
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Activating [FeFe] hydrogenase mimic for hydrogen evolution under visible light

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Inspired by the active center of the natural [FeFe] hydrogenases, we designed a compact and precious...
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Maria W?chtler;Phili...
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Structural Basis for the Friedel-Crafts Alkylation in Cylindrocyclophane Biosynthesis

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The Lewis acid-catalyzed Friedel-Crafts alkylation of an aromatic ring with an alkyl halide is exten...
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作 者:
Zheng Xiang;Hua-Qi W...
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Rationally Tailoring Catalysts for the CO Oxidation Reaction by Using DFT Calculations

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Rational design of catalysts by tailoring specific surface sites with different elements could resul...
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作 者:
Henrik Kristoffersen...
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In silico investigation of ligand-regulated palladium-catalysed formic acid dehydrative decomposition under acidic conditions

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In silico investigation of ligand-regulated palladium-catalysed formic acid dehydrative decompositio...
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作 者:
Chaoren Shen;Kaiwu D...
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Tunable and Recyclable Polyesters from CO2 and Butadiene

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Carbon dioxide is inexpensive and abundant, and its prevalence as waste makes it attractive as a sus...
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作 者:
Ian Tonks;Rachel Rap...
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