Tetrameric Aryl Palladium Bromide Intermediates Leading to Facile Transmetalation in Suzuki\\u2013Miyaura Cross-Couplings with Pd@MIL-101-NH2(Cr)

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The composition and structure of catalytic intermediates in the context of the Suzuki\\u2013Miyaura ...
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作 者:
Belén Martín-Matute;...
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Enhanced electrocatalysts fabricated via quenched ultrafast sintering: physicochemical properties and water oxidation applications

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The synthesis of transition metal oxides is typically time- and energy-consuming. Recently, fast sin...
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作 者:
Antonino Curcio;Matt...
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An In Vivo Biocatalytic Cascade Featuring an Artificial Enzyme Catalyzed New-to-Nature Reaction

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Artificial enzymes utilizing the genetically encoded non-proteinogenic amino acid p-aminophenylalani...
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作 者:
Gerard Roelfes;Linda...
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Direct Synthesis and Applications of Solid Silylzinc Reagents

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The increased synthetic utility of organosilanes motivates researchers to develop a milder and more ...
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作 者:
Ramesh Rasappan;Reva...
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Efficient Electrochemical Reduction of CO2 to Formate in Methanol Solutions by Mn Functionalized Electrodes in the Presence of Amines

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Carbon cloth electrode modified by covalently attaching a manganese organometallic catalyst is used ...
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作 者:
Julien Leclaire;Fran...
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Highly Functional Group Tolerant, (E)-Selective Transfer Semihydrogenation of Alkynes Catalysed by Iridium Complex Bearing Unsymmetrical Ferrocene-Based Phosphine Ligand

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Herein, we present (E)-selective transfer semihydrogenation of alkynes based on in situ generated ir...
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作 者:
Rafa? Kusy;Marcin Li...
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Ir-Catalyzed Chemodivergent Allenylic Alkylation of Vinyl Az-ides: Highly Enantioselective Synthesis of \\u03b1-Allenylic Amides and Ketones

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Enantioselective allenylic alkylation reactions of unstabilized enolates have never been reported. W...
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作 者:
Santanu Mukherjee;Ad...
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Interrogation of the Selectivity and Electrokinetics of CO2 Reduction by AgSn Films in the Presence of Protic Organic [DBU\\u2013H]+ Cations as judged by Impedance Spectroscopy and Distribution of Relaxation Times Analysis

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The use of renewable electricity to synthesize high energy and high value chemicals via reduction of...
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作 者:
Joel Rosenthal;Thabi...
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Substrate multiplexed protein engineering facilitates promiscuous biocatalytic synthesis

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Enzymes with high activity are readily produced through protein engineering, but intentionally and e...
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作 者:
Andrew Buller;Allwin...
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Direct SN2 or SN2X Manifold \\u2013 Mechanistic Study of Ion-Pair Catalyzed Carbon(sp3)-Carbon(sp3) Bond Formation

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Density functional theory (DFT) is used in this work to predict the mechanism for constructing conge...
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作 者:
Richmond Lee;Chi Bon...
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