Is maximising current density always the optimum strategy in electrolyser design for electrochemical CO2 conversion to chemicals?

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Electrochemical conversion of CO2 to chemicals and fuels can potentially play a role in reducing CO2...
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作 者:
Mengran Li;Sahil Gar...
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Iron(IV) Complexes with Tetraazaadamantane-based Ligands: Synthesis, Structure, Application in Dioxygen Activation and Labeling of Biomolecules

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4,6,10-Trihydroxy-1,4,6,10-tetraazaadamantane (TAAD) has been shown to form a stable Fe(IV) complex ...
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Alexey Sukhorukov;Iv...
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Hydrodeoxygenation of Guaiacol Over Orthorhombic Molybdenum Carbide: A DFT and Microkinetic Study

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The hydrodeoxygenation of guaiacol is modelled over a (100) \\u03b2-Mo2C surface using density funct...
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Kushagra Agrawal;Alb...
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Electrophilic Sulfur Reagent Design Enables Catalytic syn-Carbosulfenylation of Unactivated Alkenes

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A multi-component approach to structurally complex organosulfur products is described via the nickel...
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作 者:
Keary Engle;Zi-Qi Li...
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Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity

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Covalent organic frameworks (COFs) offer vast structural and chemical diversity enabling a wide and ...
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作 者:
Sebastian T. Emmerli...
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A Binuclear Cobalt Complex for Molecular CO2 Electrocatalysis

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A pyrazole\\u2013based ligand substituted with terpyridine groups at the 3 and 5positions has been s...
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作 者:
Orestes Rivada Wheel...
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Organocatalytic Discrimination of Non-Directing Aryl and Heteroaryl Groups: Enantioselective Synthesis of Bioactive Indole-Containing Triarylmethanes

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Despite the enormous developments of asymmetric catalysis, the basis for asymmetric induction is lar...
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作 者:
Jianwei Sun;Qiaolin ...
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Using pH dependence to understand mechanisms in electrochemical CO reduction

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Electrochemical conversion of CO(2) into hydrocarbons and oxygenates is envisioned as a promising pa...
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作 者:
Georg Kastlunger;Nit...
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Transferrable Selectivity Profiles Enable Prediction in Synergistic Catalyst Space

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Organometallic intermediates participate in many multi-catalytic enantioselective transformations di...
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作 者:
Jolene Reid;Yutao Ku...
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Synergistic Br\\u00f8nsted/Lewis Acid Catalyzed Aromatic Alkylation with Unactivated Tertiary Alcohols or Di-tert-Butylperoxide to Synthesize Quaternary Carbon Centers

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Dual Br\\u00f8nsted/Lewis acid catalysis involving environmentally benign, readily accessible protic...
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作 者:
Aaron Pan;Maja Chojn...
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