The Role of Homoaromaticity in the Tropylium-Catalyzed Carboxylic Acid O-H Insertion with Diazoesters

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The tropylium catalyzed carboxylic acid O-H insertion with diazoesters providing \\u03b1-hydroxy est...
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作 者:
Venkataraman Ganesh;...
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Enzyme-Independent Interaction of Pyridoxal-5\\u2019-Phosphate with Cysteine

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Pyridoxal-5\\u2032-phosphate (PLP), commonly known as Vitamin B6, is a versatile co-factor that assi...
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作 者:
Vijay Krishna;Prajak...
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An Efficient Synthesis of the Bicyclic Darunavir Side Chain Using Chemoenzymatic Catalysis

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Herein, we describe a chemoenzymatic synthesis of the bicyclic fragment of Darunavir. A ketoreductas...
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Paul Riehl;Todd Hys...
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Divergent Synthesis of Indolenine and Indoline Ring Systems by Palladium-Catalyzed Asymmetric Dearomatization of Indoles

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Dearomatized indole derivatives bearing a C3- or C2-stereocenter exist ubiquitously in natural produ...
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作 者:
Lei Jiao;Dong Gao
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The Ir\\u2013OOOO\\u2013Ir Transition State and the Mechanism of the Oxygen Evolution Reaction on IrO2(110)

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Carefully assessing the energetics along the pathway of the oxygen evolution reaction (OER), our com...
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Tobias Binninger;Mar...
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Not that innocent \\u2013 ammonium ions boost homogeneous light-driven hydrogen evolution

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We report that the homogeneous light-driven hydrogen evolution reaction (HER) can be significantly e...
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作 者:
Carsten Streb;Magdal...
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The Importance of Chemical Activation and the Effect of Low Operation Voltage on the Performance of Pt-alloy Fuel Cell Electrocatalysts

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Pt-alloy (Pt-M) nanoparticles (NPs) with less expensive 3d transition metals (M = Ni, Cu, Co) suppor...
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作 者:
Matija Gatalo;Alejan...
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Organocatalytic Enantioselective Synthesis of Bicy-clo[2.2.2]octenones via Oxaziridinium Catalysed ortho-Hydroxylative Phenol Dearomatization

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Hydroxylative dearomatization reactions of phenols (HPD) offer an efficient way to assemble complex,...
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作 者:
Benjamin Buckley;Tom...
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Arylboronic Acids Catalyzed Upgrade of Glucosamines for Deoxyfructosazine and Insights on Reaction Mechanism

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Chitin is the most abundant N-containing polysaccharides in nature and D-glucosamine is one of most ...
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作 者:
Liuqun Gu;Meifeng Wa...
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Imidazole Promoted Efficient Anomerization of \\u03b2-D-Glucose Pentaacetate in Solid State and Reaction Mechanism

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Anomerization of glycosides was rarely performed under basic condition. Here an imidazole promoted a...
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作 者:
Liuqun Gu;Meifeng Wa...
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